Technical Notes:
1. Heck olefination of haloarenes .
References:
1.Angew. C hem. Int. Ed., 1995, 34, 1844.
2.J. Am. Chem. Soc., 1999 ,
3.J. Am. Chem. Soc., 1998, 120, 8971.
4.Org. L ett., 2005, 7, 3327.
Strem
氯{[X-Phos][2-(2-氨基乙基苯基]?II)}/[X-Phos]混合?PdP/P摩尔比为1:1), Chloro{[X-Phos][2-(2-aminoethylphenyl]palladium(II)}/[X-Phos] admixture (molar PdP/P = 1:1)
钯碳, Palladium Nanoparticles [PdNP: 2-3 nm (Gelatin)]
1,1'-?二异丙基?二茂铁]二氯? Dichloro[1,1'-bis(di-i-propylphosphino)ferrocene]palladium(II)
Dichloro(di-mu-chloro)bis[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]dipalladium(II)
二氯-[1,3-?二异丙苯?咪唑-2-基]?II)二聚佒/p>
甲烷磺酸[9,9-二甲?4,5-?二苯基膦)呫吨] [2'-氨基-1,1'-联苯]?II)二氯甲烷加合? Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct
?乙酸?二环己基苯基膦钯(II), Di(acetato)dicyclohexylphenylphosphinepalladium (II)
5%钯碳, Palladium
Palladium(II) hexafluoroacetylacetonate
1,1,1,5,5,5-六氟乙酰丙酮?II)
10%钯碳, Palladium
5%Pd/硫酸? Palladium
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