1,2-双[(2R,5R)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸�?I)

产品名称９�/div>

528565-84-6
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
1,2-双[(2R,5R)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸�?I)

产品介绍９�/div>

Technical Notes:

1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalyzed asymmetric hydrogenation.

2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.

3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.

4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.

References:

1. Org. Lett., 2003, 5, 1273.

2. Tetrahedron Lett., 2004, 45, 9277.

3. Angew. Chem. Int. Ed., 2005, 44, 5834.

Strem

推荐产品

Rhodium(III) chloride, anhydrous

无水三氯化铑III)

Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4

四三[?-(+)-N-(对十二烷基苯磺酰)卟啉]二铑

1,2-�?(2R,5R)-2,5-�?的i-丙基)乙烷(环辛二烯)�?I)四氟硼酸�? 1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

苄钯磷杂金刚�? Dibenzylideneacetonepalladium(0) 1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane-8- ethyl Silica (PhosphonicS PAPd2r)

[1,3-�?2,6-二异丙基苯基)-4,5-二氢咪唑-2-亚基]{2-[(二甲基氨�?kN)甲基]苯基-KC}吡啶合钯(II)四氟硼酸, [1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]{2-[(dimethylamino-kN)methyl]phenyl-kC}(pyridine)palladium(II) tetrafluoroborate

Bis(tri-t-butylphosphine)palladium(0)

�?三叔丁基�?化钯

�?2-二环己基膦基-2',4',6'-三异丙基-1,1'-联苯)[2-(2-氨基乙基苯基)]�?II), Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II) methyl-t-butylether adduct

甲磺�?2-二环己基�?3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)(2'-氨基-1,1'-联苯�?2-�?�?II), Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

甲烷磺酸[1,2-�?3,5-�?三氟甲基)苯基膦基)-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯(2'-氨基 -1,1'-联苯-2-�?�?II), Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Dichlorobis(acetonitrile)palladium(II)

�?乙腈)氯化�?II)