Technical Notes:
1.Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
2.L igand for palladium-catalyzed asymmetric reduction of allylic esters.
3.L igand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes .
4.L igand for the rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to Isatins.
References９/p>
1.J. Am. Chem. Soc., 1991, 1 13, 9887.
2.Acc. Chem. Res., 2000, 33, 354. (review)
3.J. Am. Chem. Soc., 1994, 1 16, 775.
4.J. Am. Chem. Soc., 2000, 122, 976.
5.Angew. Chem. Int. Ed., 2006, 45, 3353.
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