(11bR)-2,6-双[3,5-�?三氟甲基)苯基]-8,9,10,11,12,13,14,15-八氢-4-羟基-4-氧化�?二萘并[2-,1-d:1',2'-f][1,3,2]二氧磷杂七环

品牌

Strem

CAS

1011465-24-9

货号

15-1376

包装型号

规格纯度

98%, (99% ee)

参考价栻�/div>

1530 兂�/span>*本价格含增值税贸�/span>

促销

数量

- +

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产品名称９�/div>

1011465-24-9
(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11bR)-2,6-双[3,5-�?三氟甲基)苯基]-8,9,10,11,12,13,14,15-八氢-4-羟基-4-氧化�?二萘并[2-,1-d:1',2'-f][1,3,2]二氧磷杂七环

产品介绍９�/div>

Technical Notes:

1. The preparation of binaphthol monophosphoric acid derivatives.

2.Sigmatropic Rearrangements: Used in the organocatalytic aryl-aryl bond-forming process for the regio- and atroposelective synthesis of 2,2'-diamino-1,1'-binaphthalenes (BINAMs).In the presence of catalytic amounts of axially chiral phosphoric acids, achiral N,N'-binaphthyl hydrazines undergo a facile3,3-

sigmatropic rearrangement to afford enantiomerically enriched BINAM derivatives in good to excellent yield.

References:

1: JP4725757E81038877 u86274745,12000-3-21.

Strem

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