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位置9a href="//www.vuestras.com/strem/">首页> 品牌> Strem> (+)-2,6-双[(4S)-4-(异丙?-2-恶唑?2-基]吡啶

(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine

(+)-2,6-双[(4S)-4-(异丙?-2-恶唑?2-基]吡啶

品牌
Strem
CAS
118949-61-4
货号
07-0307
包装型号
规格纯度
98+%
参考价栻/div>
1709 兂/span>*本价格含增值税贸/span>
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数量
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产品名称9/div>
118949-61-4
(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine
(+)-2,6-双[(4S)-4-(异丙?-2-恶唑?2-基]吡啶
产品介绍9/div>

Technical Notes:

1. Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.

2.Ligand for cross-coupling reactions of iodoalkanes with alkyI zinc halides.

3.L igand for asymmetric 1 , 4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes .

4.L igand for asymmetric allylation of alde hydes with b-carbonyl allylstannanes.

5.L igand used in the enantioselective Negishi reaction of racemic secondary benzylic halides. L igand for osmium catalyzed enantioselective transfer hydrogenation.

References:

1. J. Am. Chem. Soc., 2004, 126, 9928.

2.Angew. Chem. Int. Ed., 2007, 46, 87 90.

3.Angew. Chem. Int. Ed., 2009, 48, 91 1 7.

4.J. Organomet. Chem, 2010, 695, 128.

5. J. Am. Chem. Soc. 2005, 127, 10482. Inorg. Chem.2013, 52, 6193.

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