174813-82-2
RuCl[( R, R)-TsDPEN](mesitylene)
[ N-[(1 R,2 R)-2-(Amino-κ N)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-κ N]chloro [(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium
RuCl[( R, R)-TsDPEN](均三甲苯)
[ N-[(1 R,2 R)-2-(氨基-κ N)-1,2-二苯乙基]-4-甲基苯磺酰胺�?κ N]氯[(1,2,3,4,5,6-η)-1,3,5-三甲苯]-钋�br />

产品介绍９�/div>

产品说明

应用

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

• (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemicN-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
• Chiral nonracemic ��-phenylseleno alcohols from ��-phenylseleno ketones via catalytic ATH reaction.

Takasago Ligands and Complexes for Asymmetric Reactions

包装

500 mg in amber glass bottle

法律信息

� Takasago 合作销�?#65292;仅用于研究目的。WO9720789

基本信息

经验(实验)分子弎�/td>	C30H33ClN2O2RuS
分子野�/td>	622.18
MDL编号	MFCD12545951
PubChem化学物质编号	329762817

产品性质

质量水平	100
测定	90%
mp	241-249 ℂ�/td>
储存温度	2-8ℂ�/td>
SMILES string	Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
InChI	1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
InChI key	XBNBOGZUDCYNOJ-AGEKDOICSA-M

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)