反应概述９�/span>

酰基叠氮化物在惰性溶剂中加热分解生成异氰酸酯:

异氰酸酯水解则得到胺９�/p>

反应机理９�/strong>

反应实例９�/strong>

实例1９�/p>

实例2９�/p>

参考文献：

[1] T. Curtius, Ber., 1890, 23, 3023; J. Prakt. Chem., 1894, 50(2), 275.

[2] T. Curtius, et al., J. Prakt. Chem., 1923, 105(2), 289; 1930, 125, 63.

[3] Peter A. S. Smith, Org. Reactions, 1946, 3, 337.

[4] P. de Mayo, Molecular Rerrangments, New York, 1963, 1, 474.