CAS 95464-05-4; [1,1'-双(二苯基膦基)二茂铁]二氯化钯(ii) 二氯甲烷加合物; [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane adduct

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产品名称

规格

包装、参考价格

B803385

MACKLIN

[1,1'-双(二-苯基膦基)二茂铁]氯化钯(II),二氯甲烷复合物(1:1)

98%

181元/1g; 668元/5g; 2832元/25g;

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储存：室温
状态：红色到红色-橙色到橙色粉末或晶体

B2064

TCI

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct

>98.0%(T)

790元/1G; 1490元/5G; 5650元/25G;

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基本信息

纯度/分析方法	>98.0%(T)
分子式/分子量	C₃₄H₂₈Cl₂FeP₂Pd・CH₂Cl₂ = 816.64
外观与形状(20℃)	固体
包装和容器	1G-带有塑料内管的玻璃瓶 (查看图片)
PubChem物质ID	87564938
MDL编号	MFCD00015757

技术规格

Appearance	Light yellow to Amber to Dark green powder to crystal
Purity(Argentometric Titration)	min. 98.0 %

物性(参考值)

熔点	268 ℃(dec.)

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

811200

J&K

1,1'-Bis(diphenylphosphino)ferrocene palladium(II)chloride dichloromethane complex

97%

304元/1G; 889元/5G; 3926元/25G;

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基本信息

分子式	C₃₅H₃₀Cl₂FeP₂·PdCl₂
分子量	816.65
熔点	275-280
MDL编码	MFCD00792899

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H332 H351
防范说明	P280 P305+P351+P338
WGK	3
TSCA	否

46-0450

Strem

Dichloro 1,1'-bis(diphenylphosphino)ferrocene palladium (II) dichloromethane

99%

834元/1g; 2692元/5g; 10767元/25g;

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Technical Notes:

1.See 26-0270.

2.Catalyst for the borylation of aryl halides.

3.ß-AIkyI Suzuki-Miyaura cross -coupling reactions with potassium alkyltrifluoroborates.

4.Catalyst for modified Negishi coupling.

5.Synthesis of polyheterocycles by a Pd -catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.

6.Catalyst for Stille allylation.

7.Catalyst for the amination of aryl bromides

References:

1. J. Org. Chem., 2000, 65, 164.

2.J. Org. Chem., 2003, 74, 5534.

3.Org. L ett., 2002, 4, 375.

4.Angew. Chem. Int. Ed., 2003, 42, 47 74.

5.J. Am. Chem. Soc., 2008, 130, 1 6854.

6.J. Org. Chem., 2009, 74, 6867.

C34868

Alfa Aesar

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane adduct

2081元/1g; 6206元/5g; 15670元/25g;

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基本信息

Ref#
34868

MDL
792899

分子式
C35 H30 Cl4 Fe P2 Pd

分子量
816.22

形态
Powder

379670

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane

671.28元/1 G; 2522.45元/5 G; 9042.11元/25 G; 70660.5元/250 G;

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产品说明

应用

钯催化交叉偶联反应应用指南

包装

1, 5, 25, 250 g in glass bottle

分析说明

催化剂，用于芳基卤化物和双(频哪醇合)二硼 (473294) 的硼化反应，以及芳基硼酯衍生物和芳基卤化物偶联生成联芳基化合物的反应。也可用于 CO 插入反应合成内酰胺以及芳基卤化物和醇的分子内偶联反应合成中环芳基醚。

基本信息

经验(实验)分子式	C₃₅H₃₀Cl₄FeP₂Pd
分子量	816.64
MDL编号	MFCD00792899
PubChem化学物质编号	24863679
NACRES	NA.22

产品性质

质量水平	200
reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst
mp	275-280 ℃
SMILES string	[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI	1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h21-14H;1H2;2*1H;;/q;;;;;;+2/p-2
InChI key	CWHRHCATIKFSND-UHFFFAOYSA-L

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H312 + H332 - H315 - H319 - H335
预防措施声明	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

048593

Fluorochem

1,1'-Bis(Diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

98%

484元/1g; 1650元/5g; 8140元/25g;

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基本信息

CAS Number	95464-05-4
MDL Number	MFCD00792899
Melting Point	264-278℃

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H351: Suspected of causing cancer ..
防范说明	P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P233: Keep container tightly closed. P260: Do not breathe P261: Avoid breathing . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P281: Use personal protective equipment as required. P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313: IF exposed or concerned: Get medical advice/ attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.