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CAS: 89-60-1
分子式: C7H6ClNO2
分子量: 171.58
沸点: 260-262℃
熔点: 7-262℃
中文名称: 
1-氯-4-甲基-2-硝基苯
4-氯-3-硝基甲苯
对氯间硝基甲苯
英文名称: 
1-Chloro-4-methyl-2-nitrobenzene
1-chloro-4-methyl-2-nitro-benzen
4-chloro-3-nitrotoluene
toluene,4-chloro-3-nitro-
1-chloro-4-methyl-2-nitro-benzene
Benzene,1-chloro-4-methyl-2-nitro-
2-Chloro-5-methylnitrobenzene
性质描述: 黄色油状液体。熔点7℃,沸点260℃(99.3kPa),118℃(1.47kPa),相对密度1.297,折光率1.5572。溶于醇,不溶于水。
生产方法: 由对乙酰氨基甲苯经混酸硝化得对乙酰氨基间硝基甲苯。重氮化氯化亚铜置换而得。
用途: 医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C742718MACKLIN4-氯-3-硝基甲苯Standard for GC, ≥99.8%(GC)228元/5g;   展开
储存:室温
状态:液体
C742719MACKLIN4-氯-3-硝基甲苯99%118元/25g;   391元/100g;   1890元/500g;   展开
储存:室温
状态:液体
C806009MACKLIN4-氯-3-硝基甲苯97%84元/25g;   279元/100g;   1350元/500g;   展开
储存:室温
状态:黄色到暗棕色液体
折射率:n20/D 1.558(lit.)
C0232TCI4-Chloro-3-nitrotoluene>97.0%(GC)410元/25G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C7H6ClNO2 = 171.58
外观与形状(20℃)液体
Reaxys-RN511055
PubChem物质ID87565394
SDBS (AIST Spectral DB)3882
MDL编号MFCD00007085

技术规格

AppearanceLight yellow to Yellow to Orange clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点260 ℃
闪点129 ℃
比重1.31

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

运输信息

UN编号UN2433
类别6.1
包装类别 III
监管条件代码(*)
966482J&K4-Chloro-3-nitrotoluene98%193元/25G;   544元/100G;   2413元/500G;   展开

基本信息

分子式C7H6ClNO2
分子量171.58
熔点7
沸点260
闪点129
密度1.297
折光率(n20D)1.5570 - 1.5580
MDL编码MFCD00007085
Beilstein511055
EINECS 编号201-922-8

安全信息

图形或危害标志
提示语Danger
危险说明H301
H311
H331
H315
H319
防范说明P261
P264
P270
P280
P301+P310+P330
P302+P352+P312+P361+P364
P304+P340+P311
P403+P233
P501
UN号码2433
危险分类6.1
包装等级III
WGK3
A11383Alfa Aesar4-Chloro-3-nitrotoluene97+%238元/25g;   1239元/100g;   5390元/500g;   28485元/2500g;   展开

基本信息

MDL
MFCD00007085

EINECS
201-922-8

分子式
C7H6ClNO2

分子量
171.58

熔点
ca 7°

沸点
260-262°

闪点
129°(264°F)

密度
1.295

折射率
1.5580

形态
Liquid

Beilstein
511055

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319-H373-H401-H411
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause damage to organs through prolonged or repeated exposure.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P260-P280-P305+P351+P338-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-33-36/38-51/53
Harmful by inhalation, in contact with skin and if swallowed.Danger of cumulative effects.Irritating to eyes and skin.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
9-23-26-36/37-57
Keep container in a well-ventilated place.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.Use appropriate container to avoid environmental contamination.

欧盟危险品标志

TSCA

213055Sigma-Aldrich4-Chloro-3-nitrotoluenetechnical grade1284.98元/100 G;   展开

产品说明

一般描述

Vibrational spectral analysis of 4-chloro-3-nitrotoluene has been studied using Raman and IR spectroscopy.

应用

4-Chloro-3-nitrotoluene was used in the synthesis of 4-(2-hydroxyethylamino)-3-nitrotoluene.

包装

100 g in glass bottle

基本信息

线性分子式CH3C6H3(NO2)Cl
分子量171.58
EC 号201-922-8
MDL编号MFCD00007085
PubChem化学物质编号24852766
NACRESNA.22

产品性质

等级technical grade
质量水平100
形式liquid
折射率n20/D 1.558 (lit.)
bp260 ℃/745 mmHg (lit.)
mp7 ℃ (lit.)
密度1.297 g/mL at 25 ℃ (lit.)
SMILES stringCc1ccc(Cl)c(c1)[N+]([O-])=O
InChI1S/C7H6ClNO2/c1-5-2-3-6(8)7(4-5)9(10)11/h2-4H,1H3
InChI keyNWESJZZPAJGHRZ-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H315 - H319 - H335 - H411
预防措施声明P273 - P302 + P352 - P305 + P351 + P338
危险分类Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)264.2 °F
闪点(C)129 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
222322Fluorochem1-Chloro-4-methyl-2-nitrobenzene95%220元/10g;   374元/25g;   1034元/100g;   展开

基本信息

CAS Number89-60-1
MDL NumberMFCD00007085
Boiling Point260 ℃
Melting Point7 ℃
Density1.297

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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