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CAS: 873-77-8
分子式: ClC6H4MgBr
分子量: 215.76
英文名称: 
4-Chlorophenylmagnesium bromide solution
4-chlorophenylmagnesium bromide
推荐供应商
货号品牌产品名称规格包装、参考价格
C805157MACKLIN4-氯苯基溴化镁1.0 M solution in THF, MkSeal98元/100ml;   450元/500ml;   805元/1L;   咨询
储存:2~8 ℃
状态:黄色到暗棕色液体
774448Sigma-Aldrich4-Chlorophenylmagnesium bromide solution1.0 M in 2-methyltetrahydrofuran447.8元/100 ML;   939.5元/4 X 25 ML;   3010.31元/800 ML;   咨询

产品说明

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Find details here.

应用

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

包装

4×25, 100, 800 mL in Sure/Seal™
The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法律信息

Sure/Seal is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式ClC6H4MgBr
分子量215.76
MDL编号MFCD00009926
PubChem化学物质编号329767685
NACRESNA.22

产品性质

质量水平100
环保替代产品特性Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.
浓度1.0 M in 2-methyltetrahydrofuran
密度1.005 g/mL at 25 ℃
环保替代产品分类Aligned
储存温度2-8℃
SMILES stringClc1ccc([Mg]Br)cc1
InChI1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1
InChI keyCDEMHJCJMMOFMB-UHFFFAOYSA-M

安全信息

象形图GHS02GHS05GHS07
警示用语:Danger
危险声明H225 - H302 - H314
预防措施声明P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
补充剂危害EUH014 - EUH019
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)8.6 °F - closed cup
闪点(C)-13.0 ℃ - closed cup
214284Fluorochem4-Chlorophenylmagnesium bromide 0.5 M in Tetrahydrofuran4048元/100ml;   10824元/500ml;   43274元/2.5L;   咨询

基本信息

CAS Number873-77-8
MDL NumberMFCD00009926
Density0.889

安全信息

图形或危害标志
危险性说明 EUH014: Reacts violently with water.
EUH019: May form explosive peroxides.
H225: Highly flammable liquid and vapour.
H261: In contact with water releases flammable gases.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H351: Suspected of causing cancer ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from – No smoking.
P223: Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231 + P232: Handle under inert gas. Protect from moisture.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P335 + P334: Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P402 + P404: Store in a dry place. Store in a closed container.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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