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CAS: 789-25-3
分子式: C18H16Si
分子量: 260.40
沸点: 152℃(2 t
熔点: 43-46℃
中文名称: 
三苯基硅烷
三苯硅烷
英文名称: 
triphenyl-Silane
Triphenylsilane
triphenyl-silan
Triphenyl-silane
Silane,triphenyl-
Triphenylhydrosilane
Triphenylsilan
用途: 医药中间体
推荐供应商
货号品牌产品名称规格包装、参考价格
T829501MACKLIN三苯基硅烷97%30元/1g;   36元/5g;   136元/25g;   535元/100g;   咨询
储存:2~8°C,密封
状态:白色晶体粉末
折射率:1.618 (20ºC)
T0661TCITriphenylsilane>96.0%(GC)340元/5G;   1125元/25G;   咨询

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C18H16Si = 260.41
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN978182
PubChem物质ID87576535
SDBS (AIST Spectral DB)7872
MDL编号MFCD00003003

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 96.0 %
Melting point45.0 to 47.0 ℃
Solubility in Methanolalmost transparency

物性(参考值)

熔点46 ℃
沸点184 ℃/6 mmHg

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
122416J&KTriphenylsilane97%303元/10G;   1043元/50G;   咨询

基本信息

分子式C18H16Si
分子量260.41
熔点43-45
沸点152
闪点76
MDL编码MFCD00003003
Beilstein978182
EINECS 编号212-333-0

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK1
TSCA
93-1467StremTriphenylsilanemin. 97%543元/10g;   2168元/50g;   咨询
A11605Alfa AesarTriphenylsilane97%565元/10g;   1827元/50g;   咨询

应用
Triphenylsilane acts as a reactant or reagent for catalytic hydrogen deuterium exchange reactions of silanes, to be oxidized by carbon nanotube-gold nanohybrids, for hydrolysis by ruthenium complexes, for hydrosilylation to produce enolsilanes, for synthesis of bromosilanes, for ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives. It is used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes.

备注
Air Sensitive. Incompatible with air and oxidizing agents.

基本信息

MDL
MFCD00003003

EINECS
212-333-0

分子式
(C6H5)3SiH

分子量
260.41

熔点
42-44°

沸点
159-163°/3mm

闪点
76°(169°F)

灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Crystalline powder/lumps

溶解性
Soluble in methanol. Decomposes in water.

Beilstein
978182

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

148504Sigma-AldrichTriphenylsilane97%296.26元/5 G;   1265.28元/25 G;   咨询

产品说明

应用

作为以下反应的反应物或试剂:

  • 用于硅烷的催化氢氘交换反应
  • 碳纳米管-金纳米复合物的氧化
  • 用于钌配合物的水解
  • 用于氢化硅烷化,以产生烯醇硅烷
  • 用于合成溴硅烷
  • 用于甲硅烷基烯烃的臭氧氧化,以合成α-O-甲硅烷基化偶姻衍生物
  • 用于合成氢化甲硅烷基和双(甲硅烷基)双(咪唑啉基)镍配合物

包装

5, 25 g in glass bottle

基本信息

线性分子式(C6H5)3SiH
分子量260.41
Beilstein978182
EC 号212-333-0
MDL编号MFCD00003003
PubChem化学物质编号24848907
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilityreagent type: reductant
bp152 ℃/2 mmHg (lit.)
mp43-45 ℃ (lit.)
SMILES stringc1ccc(cc1)[SiH](c2ccccc2)c3ccccc3
InChI1S/C18H16Si/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
InChI keyAKQNYQDSIDKVJZ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)168.8 °F - closed cup
闪点(C)76 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
228562AmethystTriphenylsilane97%, 用于合成134元/5G;   485元/25G;   1754元/100G;   咨询

基本信息

分子式C18H16Si
分子量260.41
熔点43-45
沸点152
闪点76
MDL编码MFCD00003003
Beilstein978182
EINECS 编号212-333-0

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK1
TSCA
S20600FluorochemTriphenylsilane96%396元/5g;   1056元/25g;   3080元/100g;   咨询

基本信息

CAS Number789-25-3
MDL NumberMFCD00003003
Boiling Point160℃
Melting Point42-44℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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