CAS 78839-75-5; n-(tert-butoxycarbonyl)-2-bromoaniline

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货号

品牌

产品名称

规格

包装、参考价格

N854734

MACKLIN

N-(叔丁氧羰基)-2-溴苯胺

97%

82元/1g; 256元/5g; 957元/25g; 3776元/100g;

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储存：室温,干燥
状态：黄色液体

531316

Sigma-Aldrich

N-(tert-Butoxycarbonyl)-2-bromoaniline

97%

3053.89元/10 G;

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产品说明

一般描述

N-(tert-Butoxycarbonyl)-2-bromoaniline, also known as tert-butyl-N-(2-bromophenyl)carbamate, is an N-Boc-protected o-bromoaniline.1 It reacts with ethyl perfluorooctanoate in the presence of tert-butyllithium to form the corresponding 1-hydroxy-1H-perfluorooctyl compound.

应用

N-(tert-Butoxycarbonyl)-2-bromoaniline may be used in the synthesis of N-boc-protected o-aryl anilines, which undergoes coupling reaction with bromoacetylenes to form the corresponding arene?ynamides.

包装

10 g in glass bottle

基本信息

线性分子式	BrC₆H₄HNCO₂C(CH₃)₃
分子量	272.14
MDL编号	MFCD01006614
PubChem化学物质编号	24877811
NACRES	NA.22

产品性质

质量水平	100
测定	97%
折射率	n20/D 1.54 (lit.)
bp	110 ℃/0.3 mmHg (lit.)
密度	1.342 g/mL at 25 ℃ (lit.)
SMILES string	CC(C)(C)OC(=O)Nc1ccccc1Br
InChI	1S/C11H14BrNO2/c1-11(2,3)15-10(14)13-9-7-5-4-6-8(9)12/h4-7H,1-3H3,(H,13,14)
InChI key	UQBGKDLSIIHUEZ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	230.0 °F - closed cup
闪点(C)	110 ℃ - closed cup
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

324206

Fluorochem

tert-Butyl (2-bromophenyl)carbamate

95%

572元/1g; 1232元/5g; 2156元/10g; 17336元/100g;

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基本信息

CAS Number	78839-75-5
MDL Number	MFCD01006614
Boiling Point	110 ℃/0.3 mmHg(Lit)

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .