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CAS: 78008-36-3
分子式: C9H14O3
分子量: 170.21
英文名称: 
(R)-1,4-dioxaspiro[4.5]decane-2-carboxaldehyde
推荐供应商
货号品牌产品名称规格包装、参考价格
R848338MACKLIN(R)-1,4-二氧杂螺[4,5]癸烷-2-甲醛98%298元/250mg;   594元/1g;   咨询
储存:2-8°C,惰性气体氛围
状态:无色-略淡黄色澄清液体
D5511TCI(R)-1,4-Dioxaspiro[4.5]decane-2-carboxaldehyde>98.0%(GC)1590元/5G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C9H14O3 = 170.21
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN3540045
MDL编号MFCD03093997

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 98.0 %
Specific rotation [a]20/D+73.0 to +81.0 deg(C=1, CHCl3)
Acid Valuemax. 5.0

物性(参考值)

沸点94 ℃/2 mmHg
闪点109 ℃
比重1.11
比旋光度 [α]D77° (C=1,CHCl3)
折射率1.47
543039Sigma-Aldrich(R)-1,4-Dioxaspiro[4.5]decane-2-carboxaldehyde1544.18元/1 G;   咨询

产品说明

应用

Reactant for:

  • Proline-catalyzed Diels Alder reaction
  • Stereodivergent synthesis of carbahexofuranoses employing a Wittig olefination-Claisen rearrangement protocol
  • Wittig reactions
  • Crotylation reactions
  • Asymmetric synthesis of Goniothalesdiol A via stereocontrolled allylation and base-catalyzed oxy-Michael addition

作为结构单元。

包装

1 g in glass bottle

其他说明

含不定量的聚合物

基本信息

经验(实验)分子式C9H14O3
分子量170.21
MDL编号MFCD03093997
PubChem化学物质编号24878656
NACRESNA.22

产品性质

旋光性[α]/D 60±10° in chloroform
质量水平100
折射率n20/D 1.472 (lit.)
密度1.108 g/mL at 25 ℃ (lit.)
SMILES stringO=C[C@H]1COC2(CCCCC2)O1
InChI1S/C9H14O3/c10-6-8-7-11-9(12-8)4-2-1-3-5-9/h6,8H,1-5,7H2/t8-/m0/s1
InChI keyFFGZPNNLXMQFMO-QMMMGPOBSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
092272Fluorochem(R)-1,4-Dioxaspiro[4.5]decane-2-carbaldehyde95%1716元/1g;   5214元/5g;   8360元/10g;   16742元/25g;   咨询

基本信息

CAS Number78008-36-3
MDL NumberMFCD03093997

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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