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CAS: 7787-64-6
分子式: BiI3
分子量: 589.69
熔点: 408 °C(lit.)
中文名称: 
碘化铋
英文名称: 
Bismuthine,triiodo-
triiodo-bismuthin
Bismuth iodide
Bismuth(III)iodide
Bismuth(III)iodide,Puratronic
Bismuth(III)iodide,tech
Bismuth(III)iodide,ultra dry
推荐供应商
货号品牌产品名称规格包装、参考价格
B802267MACKLIN碘化铋98%47元/5g;   140元/25g;   540元/100g;   2690元/500g;   13396元/2.5kg;   咨询
储存:室温
状态:灰色粉末和/或块状
B803330MACKLIN碘化铋99.99% metals basis236元/5g;   咨询
储存:室温
状态:灰色粉末和/或块状
B5787TCIBismuth(III) Iodide Anhydrous>98.0%(T)390元/5G;   1065元/25G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量BiI3 = 589.69
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
包装和容器 5G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN3903094
PubChem物质ID354335729
Merck Index (14)1269
MDL编号MFCD00010894

技术规格

AppearanceWhite to Gray to Brown powder to crystal
Purity(Chelometric Titration)min. 98.0 %

物性(参考值)

熔点408 ℃
沸点500 ℃
水溶性不溶

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN3260
类别8
包装类别 III
监管条件代码(*)
164264J&KBismuth(III) iodide98%, 无水的356元/5G;   993元/25G;   咨询

基本信息

分子式BiI3
分子量589.6900
熔点108
沸点500
MDL编码MFCD00010894
Beilstein3903094
Merck14,1269

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P260
P264
P280
P303+P361+P353
P301+P330+P331
P363
P304+P340+P310
P305+P351+P338+P310
993003J&KBismuth(III) iodide99.999%, 微量金属基础481元/2G;   1695元/10G;   咨询

基本信息

分子式BiI3
分子量589.69
熔点408
密度5.78
MDL编码MFCD00010894
Beilstein3903094
Merck14,1269
EINECS 编号232-127-4

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P260
P264
P280
P303+P361+P353
P301+P330+P331
P363
P304+P340+P310
P305+P351+P338+P310
UN号码3260
危险分类8
包装等级III
93-8317StremBismuth(III) iodide(99.999%-Bi) PURATREM1140元/5g;   2565元/25g;   咨询
010656Alfa AesarBismuth(III) iodidePuratronic庐, 99.999% (metals basis)693元/2g;   2444元/10g;   9391元/50g;   咨询

应用
Polycrystalline films of bismuth triiodide are used as beta direct and digital detectors for medical imaging applications. Bismuth(III) iodide is used as an ice nucleant. It is also used in electron microscopy to reveal synapses. Addition of bismuth triiodide has been shown to improve the glass forming ability and thermal stability of Ge-Te-BiI(3) chalcogenide glasses. Solution-processable BiI3 nanosheets have been shown to exhibit the potential to be used as HTLs (Hole Transport Layer) in conventional OPV (organic photovoltaic) devices.

备注
It is stable in air. It is not hygroscopic, but decomposed by water.

基本信息

MDL
MFCD00010894

EINECS
232-127-4

分子式
BiI3

分子量
589.69

熔点
408°

沸点
ca 500°

密度
5.778

灵敏度
Hygroscopic. Light Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Lump/Powder

溶解性
Insoluble in water. Highly soluble in ethanol, benzene, toluene and xylene, hydrochloric acid and in hydriodic acid.

Merck
14,1269

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
34
Causes burns.

安全等级
3-20-26-36/37/39-45-60
Keep in a cool place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

035681Alfa AesarBismuth(III) iodideultra dry, 99.998% (metals basis)1148元/1g;   1764元/5g;   6784元/25g;   咨询

基本信息

MDL
MFCD00010894

EINECS
232-127-4

分子式
BiI3

分子量
589.69

熔点
408°

沸点
ca 500°

密度
5.778

形态
-10 Mesh Granules, Ampouled under argon

Merck
14,1269

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

229474Sigma-AldrichBismuth(III) iodide≥99.998% trace metals basis2878.86元/10 G;   咨询

基本信息

经验(实验)分子式BiI3
分子量589.69
EC 号232-127-4
MDL编号MFCD00010894
PubChem化学物质编号24853279
NACRESNA.23

产品性质

质量水平100
测定≥99.998% trace metals basis
形式powder and chunks
reaction suitabilityreagent type: catalyst
core: bismuth
杂质≤15.0  ppm Trace Metal Analysis
mp408 ℃ (lit.)
密度5.78 g/mL at 25 ℃ (lit.)
SMILES stringI[Bi](I)I
InChI1S/Bi.3HI/h;3*1H/q+3;;;/p-3
InChI keyKOECRLKKXSXCPB-UHFFFAOYSA-K

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
危险分类Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
341010Sigma-AldrichBismuth(III) iodide99%1562.58元/25 G;   3864.95元/100 G;   咨询

产品说明

应用

碘化铋(III)或三碘化铋无毒性,因此可作为环保催化剂使用。它可用作以下反应的催化剂:

  • 水中的缩醛和缩酮的化学选择性脱保护反应。
  • 硫脲和胺合成多取代胍的成胍反应。
  • 羰基化合物的巯基化反应。

包装

25, 100 g in glass bottle

基本信息

经验(实验)分子式BiI3
分子量589.69
EC 号232-127-4
MDL编号MFCD00010894
PubChem化学物质编号24860889
NACRESNA.22

产品性质

质量水平100
测定99%
reaction suitabilitycore: bismuth
reagent type: catalyst
mp408 ℃ (lit.)
密度5.78 g/mL at 25 ℃ (lit.)
SMILES stringI[Bi](I)I
InChI1S/Bi.3HI/h;3*1H/q+3;;;/p-3
InChI keyKOECRLKKXSXCPB-UHFFFAOYSA-K

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
危险分类Skin Corr. 1B
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9
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