CAS 770-12-7; 二氯磷酸苯酯; phenylphosphoryl dichloride

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货号

品牌

产品名称

规格

包装、参考价格

P815684

MACKLIN

二氯化磷酸苯酯

98%

30元/25g; 44元/100g; 149元/500g; 446元/2.5kg;

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储存：2~8°C
状态：无色到浅液体
折射率：n20/D 1.523(lit.)

P0209

TCI

Phenyl Dichlorophosphate

>98.0%(T)

275元/25G; 2190元/500G;

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基本信息

纯度/分析方法	>98.0%(T)
分子式/分子量	C₆H₅Cl₂O₂P = 210.98
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
Reaxys-RN	511863
PubChem物质ID	87574455
SDBS (AIST Spectral DB)	4237
Merck Index (14)	7282
MDL编号	MFCD00002067

技术规格

Appearance	Colorless to Light yellow clear liquid
Purity(Argentometric Titration)	min. 98.0 %

物性(参考值)

沸点	240 ℃
比重	1.42
折射率	1.52

安全信息

图形或危害标志
信号词	危险
危险性说明	H302 : 吞咽有害。 H314 : 造成严重皮肤灼伤和眼损伤。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P270 : 使用本产品时不要进食、饮水或吸烟。 P234 : 只能在原容器中存放。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P390 : 吸收溢出物，防止材料损坏。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

相关法规

RTECS#

TD4393000

运输信息

UN编号	UN3265
类别	8
包装类别	II
监管条件代码(*)

197054

J&K

Phenyl Dichlorophosphate

97%

162元/25G; 460元/100G; 1835元/500G;

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基本信息

分子式	C₆H₅Cl₂O₂P
分子量	210.98
沸点	241-243
闪点	113
密度	1.412
折光率(n20D)	1.5230
MDL编码	MFCD00002067
Beilstein	511863
EINECS 编号	212-220-6

安全信息

图形或危害标志
提示语	Danger
危险说明	H314
防范说明	P280 P305+P351+P338 P310
UN号码	3265
危险分类	8
包装等级	II
WGK	3
RTECS	TD4393000
TSCA	是

A10479

Alfa Aesar

Phenyl Phosphorodichloridate

97%

333元/25g; 886元/100g; 3878元/500g;

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应用
Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.

备注
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, alcohols and strong oxidizing agents.

基本信息

MDL
MFCD00002067

EINECS
212-220-6

分子式
C₆H₅Cl₂O₂P

分子量
210.98

熔点
-1°

沸点
241-243°

闪点
112°(233°F)

密度
1.415

折射率
1.5230

灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Immiscible with water.

Beilstein
511863

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34
Harmful if swallowed.Causes burns.

安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
TD4393000

TSCA
是

C13048

Alfa Aesar

Phenyl Dichlorophosphate

99%

912元/25g; 1607元/100g;

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基本信息

Ref#
13048

MDL
2067

分子式
C6 H5 Cl2 O2 P

分子量
210.98

闪点
>110

密度
1412

安全信息

危险等级
8

包装组
II

P22389

Sigma-Aldrich

Phenyl Dichlorophosphate

≥95%

472.17元/25 G; 1007.07元/100 G;

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产品说明

应用

用于制备磷酸二酯。

包装

25, 100 g in glass bottle

基本信息

线性分子式	C₆H₅OP(O)Cl₂
分子量	210.98
Beilstein	511863
EC 号	212-220-6
MDL编号	MFCD00002067
PubChem化学物质编号	24898297
NACRES	NA.22

产品性质

质量水平	200
测定	≥95%
折射率	n20/D 1.523 (lit.)
bp	241-243 ℃ (lit.)
密度	1.412 g/mL at 25 ℃ (lit.)
SMILES string	ClP(Cl)(=O)Oc1ccccc1
InChI	1S/C6H5Cl2O2P/c7-11(8,9)10-6-4-2-1-3-5-6/h1-5H
InChI key	TXFOLHZMICYNRM-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P305 + P351 + P338 - P310
危险分类	Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	235.4 °F - closed cup
闪点(C)	113 ℃ - closed cup
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

095121

Fluorochem

Phenyl Phosphorodichloridate

98%

220元/1g; 264元/25g; 484元/100g; 2068元/500g;

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基本信息

CAS Number	770-12-7
MDL Number	MFCD00002067
Boiling Point	241 - 243 ℃
Density	1.412

安全信息

图形或危害标志
危险性说明	H314: Causes severe skin burns and eye damage.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P280: Wear . P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see . on this label). P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.