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CAS: 77-92-9
分子式: C6H8O7
分子量: 192.12
熔点: 154℃
中文名称: 
2-羟基丙烷-1,2,3-三羧酸
柠檬酸标准品
柠檬酸酐
柠檬酸
柠檬酸、无水
柠檬酸(一水)
一水合枸椽酸
一水合柠檬酸
柠檬酸(无水)
无水柠檬酸
无水枸椽酸
枸椽酸
2-羟基丙三羧酸
β-羟基丙三羧酸
3-羟基-3-羧基戊二酸
展开更多中文名
英文名称: 
citric acid ester
Citric acid(anhydrous form)
Citronensαure
1,2,3-Tricarboxy-2-hydroxypropane
-Hydroxytri-carballylic acid
-Hydroxy propanetricarboxylic acid
Citric acid anhydrous
Citiric acid
2-Hydroxy-1,2,3-propanetricarboxylic acid
2-hydroxypropanetricarboxylic acid
2-hydroxytricarballylic acid
acide citrique
aciletten
anhydrous citric acid
beta-hydroxy-tricarboxylic acid
beta-hydroxytricarballylic acid
citretten
citric acid, anhydrous
citro
fema number 2306
kyselina 2-hydroxy-1,2,3-propantrikarbonova
kyselina citronova
kyselina citronova (czech)
nsc 30279
Citric acid,anhydrous
Citric acid
Citric acid,anhydrous,ACS
Citrate standard for IC
Citric acid solution
citrfc acid,anhydrous
citricacid,anhydrous
展开更多英文名
性质描述: 白色半透明晶体或粉末。相对密度1.665(无水物)。1.542(一水物),熔点153℃(无水物),折射率1.493-1.509,摩尔燃烧热(25℃):一水物1.952MJ/mol,无水物1.96MJ/mol。无气味,味酸,从冷的溶液中结晶出来的柠檬酸含有1分子水,在干燥空气中或加热至40-50℃成无水物。在潮湿空气中微有潮解性。75℃时变软,100℃时熔融,易溶于水和乙醇,溶于乙醚。可燃。
生产方法: 本品主要采用发酵法生产,其原料可用糖蜜、蔗糖、甘薯和石油烃等碳水化合物。一般采用真菌为菌种发酵生产,按发酵方式可分为表面发酵和深层发酵两大类,表面发酵是早期的生产方法,用某些青霉菌或黑曲霉菌为菌种;深层发酵法亦以黑曲霉菌为菌种,发酵过程中生成小球形的丝菌聚集体,应避免生成长而薄的丝菌体,发酵条件为pH值1.5-2.8,同时需通入无菌空气并伴随搅拌,发酵完毕过滤除去丝菌体及残存的固体渣滓,滤液用碳酸钙中和获得柠檬酸钙,然后用浓硫酸中和得柠檬酸粗品,再经离子交换树脂精制、浓缩和结晶得到成品。以深层发酵法为主,约占发酵法产量的80%。
用途: 广泛用作食品、饮料的酸味剂和药物添加剂。亦可用作化妆品、金属清洗剂、媒染剂、无毒增塑剂和锅炉防垢剂的原料和添加剂。其主要盐类产品有柠檬酸钠、钙和铵盐等,柠檬酸钠是血液抗凝剂,柠檬酸铁铵可作补血药品。
推荐供应商
货号品牌产品名称规格包装、参考价格
C805022MACKLIN无水柠檬酸分析对照品39元/20mg;   咨询
储存:室温
状态:白色到灰白色粉末或晶体
折射率:1.493~1.509
C805021MACKLIN无水柠檬酸细胞培养专用,97.0%(GC)62元/100g;   93元/500g;   356元/2.5kg;   1092元/10kg;   1069元/12X500g;   咨询
储存:室温
状态:白色到灰白色粉末或晶体
折射率:1.493~1.509
C805019MACKLIN柠檬酸≥99.5%(T)36元/100g;   52元/500g;   88元/1kg;   354元/5kg;   1420元/25kg;   605元/12X500g;   咨询
储存:室温
状态:白色到灰白色粉末或晶体
折射率:1.493~1.509
C1949TCICitric Acid>98.0%(T)295元/500G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C6H8O7 = 192.12
外观与形状(20℃)固体
Reaxys-RN782061
PubChem物质ID87558243
Merck Index (14)2326

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Neutralization titration)min. 98.0 %
Solubility in Methanolalmost transparency

物性(参考值)

熔点154 ℃
水溶性完全溶解
在水中的溶解度590 g/l   20 ℃
溶解性(易溶于)
溶解性(可溶于)乙醚,氯仿
溶解性(不溶于)

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H316 : 造成轻微皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护眼罩/戴防护面具。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#GE7350000
947677J&KCitric Acid98%, 无水62元/100G;   75元/500G;   301元/2.5KG;   咨询

基本信息

分子式C6H8O7
分子量192.12
熔点153-159
MDL编码MFCD00011669
EINECS 编号201-069-1

安全信息

图形或危害标志
提示语Warning
危险说明H319
防范说明P305+P351+P338
WGK1
RTECSGE7350000
TSCA
958140J&KCitric Acid99.5%, 无水, ACS级207元/100G;   417元/500G;   1470元/2.5KG;   咨询

基本信息

分子式C6H8O7
分子量192.12
熔点153-159
MDL编码MFCD00011669
EINECS 编号201-069-1

安全信息

图形或危害标志
提示语Warning
危险说明H319
防范说明P305+P351+P338
WGK1
RTECSGE7350000
TSCA
A10395Alfa AesarCitric Acid99+%247元/250g;   536元/1000g;   2168元/5000g;   咨询

应用
Citric acid is the most widely used organic acid and pH-control agent in foods, beverages, pharmaceuticals and technical applications. Used in pharmaceutical preparations, especially in effervescent tablets. It is used as a natural preservative.

备注
Hygroscopic. Incompatible with alkalies, bases, metal nitrates and oxidizing agents.

基本信息

MDL
MFCD00011669

EINECS
201-069-1

分子式
C6H8O7

分子量
192.13

熔点
153-154°

密度
1.665

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water, alcohol, ether, dimethylsufoxide and ethylacetate.

Beilstein
782061

Merck
14,2326

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H318-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
37/38-41
Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
26-37/39-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.This material and its container must be disposed of as hazardous waste

RTECS
GE7350000

TSCA

036664Alfa AesarCitric Acidanhydrous, ACS, 99.5+%343元/100g;   692元/500g;   3063元/2kg;   咨询

应用
Citric acid is the most widely used organic acid and pH-control agent in foods, beverages, pharmaceuticals and technical applications. Used in pharmaceutical preparations, especially in effervescent tablets. It is used as a natural preservative.

Grade Specifications
Maximum level of impurities: Insoluble matter 0.005%, Residue after ignition 0.02%, Cl 0.001%, C2O4 P.T. (limit about 0.05%), PO4 0.001%, SO4 0.002%, Fe 3ppm, Pb 2ppm, Substances carbonizable by hot sulfuric acid (tartrates, etc.) P.T.

备注
Citric acid anhydrous is non-toxic. It is chemically stable if stored at ambient temperatures. Stability tests have shown that citric acid anhydrous is chemically stable for at least five years in tightly closed containers under proper storage conditions. Hygroscopic.

基本信息

MDL
MFCD00011669

EINECS
201-069-1

分子式
C6H8O7

分子量
192.13

熔点
153-154°

密度
1.665

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline

溶解性
It is very soluble in water, freely soluble in ethanol (96 %) and sparingly soluble in ether.

Beilstein
782061

Merck
14,2326

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H318-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
37/38-41
Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
26-37/39-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.This material and its container must be disposed of as hazardous waste

RTECS
GE7350000

TSCA

J13729Alfa AesarCitric Acidanhydrous, 99.5-100.5% (dry basis), Thermo Scientific767元/500g;   1095元/1kg;   咨询

基本信息

MDL
MFCD00011669

EINECS
201-069-1

分子量
192.12

熔点
153-154°

密度
1.665

灵敏度
Ambient temperatures.

形态
Crystalline powder

Beilstein
782061

Merck
14,2326

安全信息

危险类别
37/38-41
Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
26-37/39-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.This material and its container must be disposed of as hazardous waste

RTECS
GE7350000

TSCA

C22034Alfa AesarCitric Acid99.5%, for analysis, anhydrous666元/100g;   853元/500g;   2732元/2.5kg;   咨询

基本信息

Ref#
22034

MDL
11669

分子式
C6 H8 O7

分子量
192.13

闪点
100

形态
Crystalline

C11045Alfa AesarCitric Acid99%, pure, anhydrous1035元/1kg;   4116元/5kg;   4917元/25kg;   咨询

基本信息

Ref#
11045

MDL
11669

分子式
C6 H8 O7

分子量
192.13

闪点
100

形态
Crystalline

C32986Alfa AesarCitric Acidfor molecular biology, anhydrous, Rnase and Protease free1738元/1kg;   咨询

基本信息

Ref#
32986

MDL
11669

分子式
C6 H8 O7

分子量
192.13

闪点
100

A940-500Alfa AesarCITRIC ACID ANHYD CRT ACS 500G396元/500g;   咨询

基本信息

Ref#
F50235

MDL
MFCD00011669

分子式
HOCOCH{2}C(OH)(COOH)CH{2}COOH

分子量
192.13

形态
Solid

T_702C624053Alfa AesarCitric Acidanhydrous, extra pure, SLR, Eur.Ph., BP,USP 500331元/500g;   咨询

基本信息

Ref#
F50618

MDL
MFCD00011669

分子式
HOCOCH{2}C(OH)(COOH)CH{2}COOH

分子量
192.13

形态
Solid

A940-1Alfa AesarCITRIC ACID ANHYD CERT ACS 1KG560元/1kg;   咨询

基本信息

Ref#
F50756

MDL
MFCD00011669

分子式
HOCOCH{2}C(OH)(COOH)CH{2}COOH

分子量
192.13

形态
Solid

A940-250LBAlfa AesarCITRIC ACID ANHY ACS 250LB28129元/250lb;   咨询

基本信息

Ref#
F51863

A95-250LBAlfa AesarCITRIC ACID ANHY USP 250LB29952元/250lb;   咨询

基本信息

Ref#
F52231

A95-3Alfa AesarCITRIC ACID ANH USP/FCC 3KG1445元/3kg;   咨询

基本信息

Ref#
F52232

BP339-500Alfa AesarCITRIC ACID 500G360元/500g;   咨询

基本信息

Ref#
F52627

R11150Alfa AesarCitric acid Standard solution100ppm210元/1ml;   咨询
PHR1071SupelcoCitric acid, AnhydrousPharmaceutical Secondary Standard; Certified Reference Material1359.83元/1 G;   咨询

产品说明

一般描述

用于质量控制的药物二级标准品,为制药实验室和制造商制备内部工作标准品提供了一种方便、高性价比的替代方案。
柠檬酸是药物制剂中的一种常见成分。由于它与碳酸盐或碳酸氢盐结合产生的起泡作用,它可用于抗酸剂和洁齿剂中。柠檬酸也可用作缓冲剂,它有助于悬浮液的分散,从而确保活性成分的稳定性并增强抗氧化剂的功效。

应用

无水柠檬酸可以用作参考标准品,通过分光光度法对生物流体中存在的柠檬酸浓度进行测定。
无水柠檬酸可用作药物参考标准品,用于通过各种色谱技术测定药物制剂和牛奶样品中的分析物。
这些二级标准品是经过检验的认证标准物质(CRM)。它们适用于多种分析应用,包括但不限于药物释放测试、药物的定性和定量分析方法开发、食品和饮料质量控制检测以及其他标定应用。

分析说明

这些二级标准品可追溯至USP、EP(PhEur)和BP一级标准品。

其他说明

该认证标准物质(CRM)根据ISO 17034ISO/IEC 17025进行生产和认证。有关此CRM使用的所有信息均可在分析证书上找到。

附注

要查看该材料的分析证书示例,请在下面的栏位中输入LRAB7603。这只是一个示例证书,可能不是您收到的批次。

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
eCl@ss39021801
PubChem化学物质编号329823094
NACRESNA.24

产品性质

质量水平300
等级certified reference material
pharmaceutical secondary standard
CofAcurrent certificate can be downloaded
expl. lim.8 %, 65 °F
technique(s)HPLC: suitable
gas chromatography (GC): suitable
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
药典可追溯性traceable to PhEur A1202000
traceable to USP 1134368
储存温度2-30℃
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
251275Sigma-AldrichCitric AcidACS reagent, ≥99.5%558.34元/5 G;   615.84元/100 G;   995.65元/500 G;   1831.65元/1 KG;   3442.82元/2.5 KG;   8082.7元/12 KG;   咨询

产品说明

一般描述

柠檬酸是一种常用作螯合剂、缓冲剂的有机酸,用于pH的调整和衍生化。

应用

柠檬酸已用于制备:

  • 柠檬酸磷酸盐缓冲液用于酶联免疫吸附测定。
  • 柠檬酸盐稳定的二氧化铈水溶胶,其可用于合成氧化铈纳米颗粒。
  • 柠檬酸-Na2HPO4缓冲储备溶液用于粪便脲酶活性的测定。
  • 抗凝血柠檬酸葡萄糖溶液A(ACD-A),可用于分离血液来源的内皮祖细胞。

柠檬酸还可用于:
  • 在一种新方法中,它可实现在合成钯立方八面体时对粒子的大小进行控制。
  • 通过自下而上碳化法制备柠檬酸衍生的碳纳米点(CND)。
  • 作为一种双组分螯合剂,通过一种新型的溶胶-凝胶法合成Li4Ti5O12(钛酸锂)。

包装

5, 100, 500 g in poly bottle
1, 2.5 kg in poly bottle
12 kg in fiber drum

其他说明

访问Redi-Dri产品列表 791725

法律信息

Redi-Dri is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
eCl@ss39021801
PubChem化学物质编号24855122

产品性质

质量水平200
等级ACS reagent
测定≥99.5%
形式crystals
expl. lim.8 %, 65 °F
杂质 Substances carbonizable by hot sulfuric acid, passes test
灼烧残渣≤0.02%
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
痕量阴离子chloride (Cl-): ≤0.001%
oxalate (C2O42-): passes test (limit about 0.003%)
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤0.002%
痕量阳离子Fe: ≤3 ppm
Pb: ≤2 ppm
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N
Gene Informationhuman ... SRC(6714)

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
C0759Sigma-AldrichCitric Acid99%273.45元/100 G;   606.74元/500 G;   1049.95元/1 KG;   4448.91元/5 KG;   咨询

产品说明

一般描述

柠檬酸是一种广泛用于食品和制药工业的有机酸。在工业规模上,通常通过使用真菌黑曲霉(Aspergillus niger)对糖蜜进行深层发酵来生产。对精制甘油酯油和脂肪中的柠檬酸进行电解测定已有研究。一种使用柠檬酸从组织中除去钙而不改变其抗原性质的方法已有报道。

包装

1 kg in poly bottle
100, 500 g in poly bottle
5 kg in poly drum

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
eCl@ss39021801
PubChem化学物质编号329774820
NACRESNA.21

产品性质

质量水平200
测定99%
expl. lim.8 %, 65 °F
pKa (25 ℃)(1) 3.13, (2) 4.76, (3) 6.40
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
溶解性water: soluble 383 g/L at 25 ℃
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
791725Sigma-AldrichCitric Acidanhydrous, free-flowing, Redi-Dri, ACS reagent, ≥99.5%867元/100 G;   1085.08元/500 G;   1462.41元/1 KG;   3473.25元/2.5 KG;   4906.53元/6 X 1 KG;   9322.4元/12 KG;   咨询

产品说明

一般描述

柠檬酸也称为2-羟基-丙烷-1,2,3-三羧酸,是所有生物体中三羧酸循环的组分之一。柠檬酸的工业生产使用真菌、酵母和柑橘类水果作为主要来源。黑曲霉(Aspergillus niger) 主要用于通过发酵生产柠檬酸 锰可抑制柠檬酸的发酵生成 口服补充柠檬酸可促进线粒体中的三羧酸循环和氧化磷酸化,以减轻身体疲劳。

应用

柠檬酸已被用作柠檬酸盐缓冲液 和无铁Suton培养基的组分。它已被用在杂交链反应缓冲液中,用于睾丸切片的盖玻片的预平衡。

包装

1 kg in poly bottle
2.5, 12 kg in poly drum
100, 500 g in poly bottle

法律信息

Redi-Dry是sigma-aldrich公司的商标
Redi-Dri is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
PubChem化学物质编号329768287
NACRESNA.21

产品性质

质量水平200
等级ACS reagent
anhydrous
产品线Redi-Dri
测定≥99.5%
形式crystals
质量free-flowing
expl. lim.8 %, 65 °F
杂质 Substances carbonizable by hot sulfuric acid, passes test
灼烧残渣≤0.02%
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
痕量阴离子chloride (Cl-): ≤0.001%
oxalate (C2O42-): passes test (limit about 0.003%)
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤0.002%
痕量阳离子Fe: ≤3 ppm
Pb: ≤2 ppm
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
27109Sigma-AldrichCitric Acidmeets analytical specification of Ph. Eur., BP, USP, E330, anhydrous, 99.5-100.5% (based on anhydrous substance)602.67元/100 G;   2170.65元/1 KG;   2946.69元/2.5 KG;   6206.93元/6 X 1 KG;   10522元/6 X 2.5 KG;   13017.8元/25 KG;   咨询

产品说明

应用

以柠檬酸为测试试剂,研究新型哒嗪基哌嗪类似物 TPRV-1 抑制剂能否减轻柠檬酸和辣椒素诱发的豚鼠咳嗽反射。

包装

1, 6×1 kg in poly bottle

生化/生理作用

膳食形式的柠檬酸可促进抗酸剂中铝的吸收。它还能促进重金属污染土壤的植物修复,并能将镉转化为更易迁移的形式。

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
eCl@ss39021801
PubChem化学物质编号329752978
NACRESNA.21

产品性质

质量水平200
测定99.5-100.5% (based on anhydrous substance)
形式grit
质量anhydrous
meets analytical specification of Ph. Eur., BP, USP, E330
expl. lim.8 %, 65 °F
杂质 residual solvents, complies
≤0.0005% heavy metals (as Pb)
≤0.5% water (Karl Fischer)
灼烧残渣≤0.05% (as SO4)
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
溶解性water: 383 g/L at 25 ℃
痕量阴离子chloride (Cl-): ≤50 ppm
oxalate (as oxalic acid): ≤100 ppm
sulfate (SO42-): ≤100 ppm
痕量阳离子As: ≤1 ppm
Ca: ≤200 ppm
Cu: ≤10 ppm
Fe: ≤10 ppm
Hg: ≤1 ppm
Pb: ≤0.5 ppm
Zn: ≤10 ppm
适用性complies for appearance of solution
complies for reaction against H2SO4
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N
Gene Informationhuman ... SRC(6714)
C2404Sigma-AldrichCitric Acidanhydrous, suitable for cell culture, suitable for plant cell culture424.9元/100 G;   739.54元/500 G;   咨询

产品说明

包装

100, 500 g in poly bottle

应用

除了用作铁螯合剂外,在细胞培养应用中柠檬酸盐还可支持胆固醇/甾醇、泛醌和类异戊二烯的生物合成。

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
eCl@ss39021801
PubChem化学物质编号24892327

产品性质

质量水平200
测定≥97% (GC)
形式powder
expl. lim.8 %, 65 °F
technique(s)cell culture | mammalian: suitable
cell culture | plant: suitable
pH值(酸碱度)1.8 (25 ℃, 50 g/L)
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
溶解性water: 50 mg/mL, clear to very slightly hazy, colorless
密度1.67 g/cm3 at 20 ℃
web metadata keyword.defaultMetal chelator, iron delivery, cholesterol/sterol biosynthesis
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N
Gene Informationhuman ... SRC(6714)

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P305 + P351 + P338
危险分类Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
27487Sigma-AldrichCitric AcidBioUltra, anhydrous, ≥99.5% (T)471.13元/50 G;   534.34元/250 G;   1520.89元/1 KG;   咨询

产品说明

一般描述

柠檬酸是三柱氨基酸分析的缓冲成分。是放射性碘化抗体从活的鼠肿瘤细胞中解离的最佳缓冲液。

其他说明

斯克里普斯代谢组学和质谱技术中心独立生成的串联质谱数据可在PDF 27487.pdf 中查看或下载。斯克里普斯代谢物组学和质谱技术中心的METLIN代谢物数据库中有测试代谢物。要了解更多信息,请访问sigma.com/metlin。

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
eCl@ss39021801
PubChem化学物质编号57648248
NACRESNA.25

产品性质

质量水平200
产品线BioUltra
测定≥99.5% (T)
形式powder or crystals
expl. lim.8 %, 65 °F
technique(s)cell culture | hybridoma: suitable
杂质 insoluble matter, passes filter test
灼烧残渣≤0.05% (as SO4)
缺失≤0.5% loss on drying, 110 ℃
pH值(酸碱度)1.0-2.0 (25 ℃, 1 M in H2O)
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
溶解性H2O: 1 M at 20 ℃, clear, colorless
痕量阴离子chloride (Cl-): ≤5 mg/kg
oxalate (C2O42-): ≤500 mg/kg
phosphate (PO43-): ≤5 mg/kg
sulfate (SO42-): ≤20 mg/kg
tartrate (C4H4O62-): ≤2000 mg/kg
痕量阳离子Al: ≤5 mg/kg
As: ≤0.1 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤50 mg/kg
Li: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Zn: ≤5 mg/kg
λmax260 nm (Amax: ≤0.20)
280 nm (Amax: ≤0.10)
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
λ1 M in H2O
紫外吸收λ: 260 nm Amax: 0.20
λ: 280 nm Amax: 0.10
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N
Gene Informationhuman ... SRC(6714)

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
W230618Sigma-AldrichCitric Acid≥99.5%, FCC, FG404.65元/;   1116.64元/1 KG;   1634.07元/10 KG;   2194.35元/25 KG;   咨询

产品说明

一般描述

柠檬酸是一种重要的有机酸,广泛用于食品工业,作为pH调节剂、调味剂、抗菌剂、膨松剂和抗氧化剂。 用低浓度的柠檬酸和甘氨酸混合物处理马铃薯类食品,可以减少丙烯酰胺的形成,并且对风味的影响极小。 柠檬酸也是食品和饮料的有效抗褐变剂,因为它能够抑制引起褐变的多酚氧化酶(PPO)的活性。

包装

10, 25 kg in fiber drum
1 kg in poly bottle

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
FEMA编号2306
Beilstein782061
EC 号201-069-1
欧洲委员会编号20c
MDL编号MFCD00011669
PubChem化学物质编号24900992
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
reg. complianceEU Regulation 1334/2008 & 178/2002
FCC
FDA 21 CFR 117
FDA 21 CFR 184.1033
测定≥99.5%
形式powder or granules
expl. lim.8 %, 65 °F
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
溶解性water: 383 g/L at 25 ℃
痕量阳离子As: ≤3.0 ppm
Cd: ≤1.0 ppm
Hg: ≤1.0 ppm
Pb: ≤0.5 ppm
文件see Safety & Documentation for available documents
性状检查odorless
application(s)flavors and fragrances
食品过敏原no known allergens
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N
Gene Informationhuman ... SRC(6714)

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
W230633Sigma-AldrichCitric Acidnatural, ≥99.5%, FCC, FG489元/;   1727.11元/1 KG;   3062.33元/10 KG;   咨询

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
FEMA编号2306
Beilstein782061
MDL编号MFCD00011669
E编号E 330

产品性质

质量水平400
生物来源botanical
等级FG
Halal
Kosher
natural
agencyfollows IFRA guidelines
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 178/2002
FCC
FDA 21 CFR 117
测定≥99.5%
形式crystals, granules or powder
expl. lim.8 %, 65 °F
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
密度1.67 g/cm3 at 20 ℃
痕量阳离子As: ≤3.0 ppm
Cd: ≤1.0 ppm
Hg: ≤1.0 ppm
Pb: ≤0.5 ppm
文件see Safety & Documentation for available documents
性状检查odorless
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物no known allergens
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
1134368USPCitric AcidUnited States Pharmacopeia (USP) Reference Standard3633.89元/200 MG;   咨询

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

分析说明

These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind.  ​

其他说明

USP issued SDS can be found here.
Sales restrictions may apply.

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
MDL编号MFCD00011669
PubChem化学物质编号329749410
NACRESNA.24

产品性质

等级pharmaceutical primary standard (unable to validate for USP)
expl. lim.8 %, 65 °F
manufacturer/tradenameUSP
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
溶解性water: 383 g/L at 25 ℃
application(s)pharmaceutical (small molecule)
格式neat
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
A1202000Citric Acidanhydrous, European Pharmacopoeia (EP) Reference Standard1572.27元/ ;   咨询

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

包装

Unit quantity: 50 mg. Subject to change. The product is delivered as supplied by the issuing Pharmacopoeia. For the current unit quantity, please visit the EDQM reference substance catalogue.

注意

Please find SDS provided by EDQM here..

其他说明

Sales restrictions may apply.

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
MDL编号MFCD00011669
PubChem化学物质编号329770684
NACRESNA.24

产品性质

等级pharmaceutical primary standard
agencyEP reference standard
质量anhydrous
expl. lim.8 %, 65 °F
manufacturer/tradenameEDQM
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
储存温度2-8℃
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
V900019Sigma-AldrichCitric AcidVetec, reagent grade, 99%195.21元/500 G;   咨询

产品说明

包装

500, 6×500 g in poly bottle

法律信息

Vetec is a trademark of sigma-aldrich International GmbH

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
PubChem化学物质编号329829451

产品性质

等级reagent grade
产品线Vetec
测定99%
形式crystals or granules
expl. lim.8 %, 65 °F
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
溶解性water: 50 mg/mL, clear to very slightly hazy, colorless
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
8.18707Sigma-AldrichCitric Acidanhydrous for synthesis752.92元/1 KG;   1799.12元/5 KG;   咨询

产品说明

分析说明

Assay (alkalimetric): ≥ 99 %
Identity (IR-spectrum): passes test

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
MDL编号MFCD00011669
EC索引号201-069-1

产品性质

质量水平200
蒸汽压<0.1 hPa ( 20 ℃)
测定≥99% (alkalimetric)
形式solid
效能3000 mg/kg LD50, oral (Rat)
expl. lim.8 %, 65 °F
pH值(酸碱度)1.7 (20 ℃, 100 g/L in H2O)
pKa (1) 3.13, (2) 4.76, (3) 6.4
bp200 ℃/1013 hPa (decomposition)
mp153-159 ℃ (lit.)
溶解性 1330 g/L
密度1.665 g/cm3 at 18 ℃
堆积密度560 kg/m3
储存温度15-25℃
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
94676SupelcoCitric Acidcertified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland1750.6元/100 mg;   咨询

产品说明

一般描述

该认证标准物质(CRM)根据ISO/IEC 17025ISO 17034进行生产和认证。该CRM可追溯来自NMI的原始材料,如NIST或NMIJ。
NMR定量信息已包括在认证内容中。证书上已给出不确定性和失效日期。
请访问http://www.sigma-aldrich.com下载您的证书。

应用

有关合适仪器技术的更多信息,请参考产品分析证书。如需进一步支持,请联系技术服务。

包装

无底玻璃瓶。内含物在插入的融合锥体内。

法律信息

TraceCERT is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式HOC(COOH)(CH2COOH)2
分子量192.12
Beilstein782061
EC 号201-069-1
MDL编号MFCD00011669
eCl@ss39021801
PubChem化学物质编号329770375
E编号E330
NACRESNA.24

产品性质

质量水平300
等级certified reference material
TraceCERT®
保质期limited shelf life, expiry date on the label
expl. lim.8 %, 65 °F
technique(s)HPLC: suitable
gas chromatography (GC): suitable
pKa (1) 3.13, (2) 4.76, (3) 6.4
mp153-159 ℃ (lit.)
application(s)cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
格式neat
SMILES stringOC(=O)CC(O)(CC(O)=O)C(O)=O
InChI1S/C6H8O7/c7-3(8)1-6(13,5(11)12)2-4(9)10/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12)
InChI keyKRKNYBCHXYNGOX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H319
预防措施声明P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
BIOC-010N-25MGAccuStandardCitric Acid232元/25mg;   咨询
Citric acid柠檬酸77-92-9
044712FluorochemCitric acid, Anhydrous99%220元/100g;   374元/1kg;   1628元/5kg;   咨询

基本信息

CAS Number77-92-9
MDL NumberMFCD00149972
Melting Point153℃
Density1.665

安全信息

图形或危害标志
危险性说明 H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to .
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