[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 7699-45-8
关键词:       仅模糊查询
CAS: 7699-45-8
分子式: Br2Zn
分子量: 225.22
沸点: 697 °C
熔点: 394 °C(lit.)
中文名称: 
溴化锌
英文名称: 
Zinc bromide
zinc bromide (znbr2)
zinc dibromide
zincbromide
推荐供应商
货号品牌产品名称规格包装、参考价格
Z820682MACKLIN溴化锌99.9% metals basis60元/25g;   194元/100g;   696元/500g;   2960元/2.5kg;   咨询
储存:室温
状态:白色到灰白色粉末或块状
折射率:1.5452
Z820681MACKLIN溴化锌试剂级, 98%50元/100g;   235元/500g;   920元/2.5kg;   3132元/10kg;   2808元/12X500g;   咨询
储存:室温
状态:白色到灰白色粉末,针状和/或块状
折射率:1.5452
Z0013TCIZinc Bromide>98.0%(T)455元/25G;   680元/300G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量ZnBr2 = 225.19
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
PubChem物质ID87560383
Merck Index (14)1029
MDL编号MFCD00011294

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Chelometric Titration)min. 98.0 %

物性(参考值)

熔点394 ℃
沸点697 ℃
折射率1.55
水溶性完全溶解
在水中的溶解度4,710 g/l   25 ℃
溶解性(易溶于)乙醇
溶解性(可溶于)乙醚

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H410 : 对水生生物毒性极大并具有长期持续影响。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P391 : 收集溢出物。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

相关法规

RTECS#ZH1150000

运输信息

UN编号UN3260
类别8
包装类别 III
监管条件代码(*)
923369J&KZinc Bromide99.5%, 无水417元/100G;   1349元/500G;   咨询

基本信息

分子式ZnBr2
分子量225.20
熔点394
沸点697
密度4.22
折光率(n20D)1.5452
MDL编码MFCD00011294
Merck14,10129
EINECS 编号231-718-4
存储条件Corrosives

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
H317
H411
防范说明P273
P280
P305+P351+P338
P310
P391
UN号码3260
危险分类8
包装等级II
WGK3
RTECSZH1150000
TSCA
30-3033StremZinc Bromide(99.999%-Zn) PURATREM390元/5g;   1590元/25g;   咨询
30-3032StremZinc Bromide(99.9%-Zn)675元/50g;   2655元/250g;   咨询
93-3032StremZinc Bromide98+%889元/100g;   3587元/500g;   咨询
B22510Alfa AesarZinc Bromideanhydrous, 98%485元/100g;   2494元/500g;   咨询

应用
Zinc bromide solution can be used as a transparent shield against radiation. It is used as an optimal catalyst for stereospecific and regioselective reaction of silacyclopropanes with carbonyl compounds. It finds an application as Lewis acid in organic reactions.

备注
Hygroscopic.

基本信息

MDL
MFCD00011294

EINECS
231-718-4

分子式
ZnBr2

分子量
225.19

熔点
394°

沸点
650°

密度
4.201

折射率
1.5452

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystals

溶解性
Soluble in alcohol, ether, acetone and tetrahydrofuran.

Merck
14,10129

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318-H317-H400-H410
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34-43-50/53
Harmful if swallowed.Causes burns.May cause sensitization by skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
20-26-36/37/39-45-57-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
ZH1150000

TSCA

040413Alfa AesarZinc Bromide99.9% (metals basis)2401元/50g;   8692元/250g;   25068元/1kg;   咨询

应用
In organic chemistry as a Lewis acid. It is the electrolyte in the zinc bromide battery. Zinc bromide solutions can be used as a transparent shield against radiation. In oil and natural gas wells, solutions containing zinc bromide are used to displace drilling mud.

备注
Hygroscopic. Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, strong acids and bases.

基本信息

MDL
MFCD00011294

EINECS
231-718-4

分子式
ZnBr2

分子量
225.19

熔点
394°

沸点
650°

密度
4.201

折射率
1.5452

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Very soluble in water, alcohol, ether, acetone, tetrahydrofuran.

Merck
14,10129

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318-H317-H400-H410
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34-43-50/53
Harmful if swallowed.Causes burns.May cause sensitization by skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
20-26-36/37/39-45-57-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
ZH1150000

TSCA

044223Alfa AesarZinc Bromideanhydrous, 99.999% (metals basis)938元/10g;   7140元/50g;   22973元/250g;   咨询

应用
Mainly used in ocean wells as complete liquid, stationary liquid, amending liquid. It is also an important material in medical industry.

备注
Hygroscopic. Store under inert gas. Protect from humidity and water. Keep away from incompatibles.

基本信息

MDL
MFCD00011294

EINECS
231-718-4

分子式
ZnBr2

分子量
225.19

熔点
394°

沸点
650°

密度
4.201

折射率
1.5452

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Powder, Packaged under argon

溶解性
Very soluble in ethanol and soluble in ethyl ether. Soluble in water (at 20°C 4470g/L).

Merck
14,10129

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318-H317-H400-H410
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34-43-50/53
Harmful if swallowed.Causes burns.May cause sensitization by skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
20-26-36/37/39-45-57-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
ZH1150000

TSCA

035725Alfa AesarZinc Bromideultra dry, 99.999% (metals basis)1137元/5g;   6482元/25g;   22255元/100g;   咨询

应用
Zinc bromide is an optimal catalyst for stereo specific and regioselective reaction of silacyclopropanes with carbonyl compounds. It is used as a transparent shield against radiation, as a fluid to displace drilling muds in transition phases, as a lewis acid in organic chemistry, colloidon emulsions for photography, a nutritional or functional ingredient in food and oral care products..

备注
Hygroscopic. Store under inert gas. Store in cool, dry conditions, in a well sealed containers. Incompatible with strong oxidizing agents, strong bases, water/ moisture.

基本信息

MDL
MFCD00011294

EINECS
231-718-4

分子式
ZnBr2

分子量
225.19

熔点
394°

沸点
650°

密度
4.201

折射率
1.5452

灵敏度
Hygroscopic. Ambient temperatures.

形态
-10 Mesh Beads, Ampouled under argon

溶解性
Soluble in water, ethanol, ether, 90% alcohol.

Merck
14,10129

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318-H317-H400-H410
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34-43-50/53
Harmful if swallowed.Causes burns.May cause sensitization by skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
20-26-36/37/39-45-57-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
ZH1150000

TSCA

C21277Alfa AesarZinc Bromide99.999%, (trace metal basis), extra pure840元/2.5g;   2641元/10g;   13622元/50g;   咨询

基本信息

Ref#
21277

安全信息

危险等级
8

包装组
II

C20210Alfa AesarZinc Bromide98%, extra pure, anhydrous1011元/100g;   2895元/500g;   12256元/2.5kg;   咨询

基本信息

Ref#
20210

MDL
11294

分子式
Br2 Zn

分子量
225.19

密度
4.22

安全信息

危险等级
8

包装组
II

Z27-500Alfa AesarZINC BROMIDE CRYSTAL CERT 500G1974元/500g;   咨询

基本信息

Ref#
F52908

安全信息

危险等级
8

包装组
II

230022Sigma-AldrichZinc Bromide99.999% trace metals basis1444.73元/10 G;   4673.71元/50 G;   咨询

产品说明

应用

硅杂环丙烷和羰基化合物的立体定向性和区域选择性反应的最佳催化剂。

包装

10, 50 g in poly bottle

基本信息

线性分子式ZnBr2
分子量225.20
EC 号231-718-4
MDL编号MFCD00011294
eCl@ss38150410
PubChem化学物质编号24853770
NACRESNA.23

产品性质

质量水平100
测定99.999% trace metals basis
形式powder and chunks
reaction suitabilityreagent type: catalyst
core: zinc
杂质≤15.0  ppm Trace Metal Analysis
bp~670 ℃/1 atm (lit.)
mp394 ℃ (lit.)
溶解性diethyl ether: slightly soluble(lit.)
ethanol: very soluble(lit.)
SMILES stringBr[Zn]Br
InChI1S/2BrH.Zn/h2*1H;/q;;+2/p-2
InChI keyVNDYJBBGRKZCSX-UHFFFAOYSA-L

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H317 - H411
预防措施声明P273 - P280 - P305 + P351 + P338 - P310
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Corr. 1B - Skin Sens. 1
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
451398Sigma-AldrichZinc BromideAnhydroBeads, −10 mesh, 99.999% trace metals basis755.95元/5 G;   2539.4元/25 G;   咨询

产品说明

包装

5, 25 g in ampule

应用

硅杂环丙烷和羰基化合物的立体定向性和区域选择性反应的最佳催化剂。

法律信息

AnhydroBeads is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式ZnBr2
分子量225.20
EC 号231-718-4
MDL编号MFCD00011294
eCl@ss38150410
PubChem化学物质编号24868627
NACRESNA.23

产品性质

质量水平100
产品线AnhydroBeads
测定99.999% trace metals basis
reaction suitabilityreagent type: catalyst
core: zinc
杂质≤ 15.0  ppm Trace Metal Analysis
粒径−10 mesh
bp~670 ℃/1 atm (lit.)
mp394 ℃ (lit.)
溶解性diethyl ether: slightly soluble(lit.)
ethanol: very soluble(lit.)
SMILES stringBr[Zn]Br
InChI1S/2BrH.Zn/h2*1H;/q;;+2/p-2
InChI keyVNDYJBBGRKZCSX-UHFFFAOYSA-L

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H317 - H411
预防措施声明P273 - P280 - P305 + P351 + P338 - P310
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Corr. 1B - Skin Sens. 1
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
8.18631Sigma-AldrichZinc Bromideanhydrous for synthesis319.82元/5 G;   669.78元/250 G;   2215.99元/1 KG;   咨询

产品说明

应用

Zinc bromide can be used as:

  • A catalyst to synthesize β-hydroxy ketones by stereoselective semipinacol rearrangement of α-hydroxy epoxides.
  • A safe brominating source for the oxidative bromination of alkenes and alkynes in combination with lead tetraacetate.

It can also be used to prepare silica-supported zinc bromide (ZnBr2/SiO2) composite, which is used as a catalyst to synthesize:
  • Ynone derivatives via cross-coupling reaction of acid chlorides with terminal alkynes.
  • 4,5-disubstituted-1,2,3-(NH)-triazole derivatives by one-pot cross-coupling and 1,3-dipolar cycloaddition reaction of acid chlorides, terminal alkynes, and sodium azide.

分析说明

Assay (argentometric): ≥ 98.0 %
Water (K. F.): ≤ 2.0 %

基本信息

经验(实验)分子式Br2Zn
分子量225.20
MDL编号MFCD00011294
EC索引号231-718-4

产品性质

质量水平200
形式crystals
pH值(酸碱度)4 (20 ℃ in H2O, saturated solution)
bp697 ℃/1013 mbar
mp394 ℃
溶解性 4470 g/L
密度4.2 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/2BrH.Zn/h2*1H;/q;;+2/p-2
InChI keyVNDYJBBGRKZCSX-UHFFFAOYSA-L

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H317 - H411
预防措施声明P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9
Baidu
map