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CAS: 769-68-6
分子式: C10H11N
分子量: 145.21
沸点: 102℃(7 t
中文名称: 
2-苯基丁烷腈
2-苯基丁腈
A-乙基苯乙腈
α-苯基丁腈
α-乙基苯乙腈
英文名称: 
α-Ethylphenylacetonitrile
Benzeneacetonitrile,alpha.-ethyl-
-Phenylbutyronitrile
2-Phenylbutanenitrile
.alpha.-ethyl-Benzeneacetonitrile
alpha-ethyl-benzeneacetonitril
2-phenylbutyronitrile
Benzeneacetonitrile,.alpha.-ethyl-
性质描述: 无色液体。沸点238-240℃,141-143℃(1.06kPa),114-115℃(0.2kPa)。溶于苯、乙醚、乙醇。
生产方法: 由苯乙腈与溴乙烷经缩合反应而制得。将氨钠的苯溶液温度控制在15-20℃,加入苯乙腈,维持同一温度区间滴加溴乙烷。加毕,升温回流4h。加水静置,分取苯层,回收苯后进行减压蒸馏,收集120-150℃(0.2kPa)馏分,即为2-苯基丁腈。收率约90%。
用途: 用作医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
P914339MACKLIN2-苯基丁腈95%45元/1g;   95元/5g;   412元/25g;   1642元/100g;   咨询
储存:室温
状态:澄清无色液体
A17093Alfa Aesar2-Phenylbutyronitrile95%500元/10g;   1765元/50g;   咨询

基本信息

MDL
MFCD00001876

EINECS
212-213-8

分子式
C10H11N

分子量
145.20

沸点
102-104°/7mm

闪点
105°(221°F)

密度
0.975

折射率
1.5086

形态
Liquid

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-36/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.

安全等级
9-23-26-36/37
Keep container in a well-ventilated place.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

222739Sigma-Aldrich2-Phenylbutyronitrile95%285.02元/10 G;   咨询

产品说明

应用

2-Phenylbutyronitrile was used in the preparation of Michael-adducts. It was also used in the preparation of S-amides by nitrile hydratase.

包装

10 g in glass bottle

基本信息

线性分子式C6H5CH(CH2CH3)CN
分子量145.20
EC 号212-213-8
MDL编号MFCD00001876
PubChem化学物质编号24853353

产品性质

质量水平100
测定95%
折射率n20/D 1.5086 (lit.)
bp114-115 ℃/15 mmHg (lit.)
密度0.974 g/mL at 25 ℃ (lit.)
SMILES stringCCC(C#N)c1ccccc1
InChI1S/C10H11N/c1-2-9(8-11)10-6-4-3-5-7-10/h3-7,9H,2H2,1H3
InChI keyIZPUPXNVRNBDSW-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 + H312 + H332
预防措施声明P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312
危险分类Acute Tox. 4 Oral
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)221.0 °F - closed cup
闪点(C)105 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
099619Fluorochem2-Phenylbutyronitrile2-Phenylbutyronitrile95%330元/1g;   咨询

基本信息

CAS Number769-68-6
MDL NumberMFCD00001876
Boiling Point114-115℃
Density0.974

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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