| è´§å· | å“牌 | 产å“å称 | è§„æ ¼ | 包装ã€å‚è€ƒä»·æ ¼ | |
| E742745 | MACKLIN | 4-氟苯乙炔 | Standard for GC, ≥99.8%(GC) | 350元/1g; | 咨询 |
储å˜ï¼š2-8°C 状æ€ï¼šæ¶²ä½“ |
| E809168 | MACKLIN | 4-氟苯乙炔 | 98% | 35元/1g; 85元/5g; 355元/25g; 1198元/100g; | 咨询 |
储å˜ï¼š2~8°C 折射率：n20/D 1.516(lit.) |
| F0470 | TCI | 1-Ethynyl-4-fluorobenzene | >98.0%(GC) | 290元/1G; 1360元/5G; | 咨询 |
åŸºæœ¬ä¿¡æ¯ | 纯度/分æžæ–¹æ³• | >98.0%(GC) | | 分åå¼/分åé‡ | C8H5F = 120.13 | | 外观与形状(20℃) | 固体 | | 储å˜æ¸©åº¦ | 0-10℃ | | 储å˜åœ¨æƒ°æ€§æ°”体下 | å˜æ”¾äºŽæƒ°æ€§æ°”ä½“ä¹‹ä¸ | | 应é¿å…的情况 | 空气,åŠ çƒ | | Reaxys-RN | 1099285 | | PubChem物质ID | 87570227 | | MDLç¼–å· | MFCD00168823 |
æŠ€æœ¯è§„æ ¼ | Appearance | White to Orange to Green powder to lump | | Purity(GC) | min. 98.0 % |
物性(å‚考值) | 熔点 | 24 ℃ | | 沸点 | 56 ℃/40 mmHg | | 闪点 | 29 ℃ | | 折射率 | 1.52 |
å®‰å…¨ä¿¡æ¯ | 图形或å±å®³æ ‡å¿— |   | | ä¿¡å·è¯ | è¦å‘Š | | å±é™©æ€§è¯´æ˜Ž | H315 : é€ æˆçš®è‚¤åˆºæ¿€ã€‚
H319 : é€ æˆä¸¥é‡çœ¼åˆºæ¿€ã€‚
H228 : 易燃固体。
| | 防范说明 | P240 : 容器和装载设备接地/ç‰åŠ¿è”接。
P210 : 远离çƒæº/ç«èŠ±/明ç«/çƒè¡¨é¢ã€‚ç¦æ¢å¸çƒŸã€‚
P241 : 使用防爆的电气/通风/照明设备。
P264 : 作业åŽå½»åº•æ¸…洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护é¢å…·ã€‚
P302 + P352 : 如皮肤沾染：用水充分清洗。
P370 + P378 : ç«ç¾æ—¶ï¼šä½¿ç”¨å¹²ç ‚ã€å¹²ç²‰æˆ–抗醇泡沫çç«ã€‚
P337 + P313 : 如ä»è§‰çœ¼åˆºæ¿€ï¼šæ±‚医/就诊。
P305 + P351 + P338 : 如进入眼ç›ï¼šç”¨æ°´å°å¿ƒå†²æ´—å‡ åˆ†é’Ÿã€‚å¦‚æˆ´éšå½¢çœ¼é•œå¹¶å¯æ–¹ä¾¿åœ°å–出，å–出éšå½¢çœ¼é•œã€‚继ç»å†²æ´—。
P362+P364 : 脱掉沾污的衣æœï¼Œæ¸…æ´—åŽæ–¹å¯é‡æ–°ä½¿ç”¨ã€‚
P332 + P313 : 如å‘生皮肤刺激：求医/就诊。
|
è¿è¾“ä¿¡æ¯ | UNç¼–å· | UN1325 | | 类别 | 4.1 | | 包装类别 | III | | 监管æ¡ä»¶ä»£ç (*) | |
|
| 350781 | J&K | 1-Ethynyl-4-fluorobenzene | 99% | 262元/1G; 1109元/5G; | 咨询 |
åŸºæœ¬ä¿¡æ¯ | 分åå¼ | C8H5F | | 分åé‡ | 120.12 | | 熔点 | 27-28 | | 沸点 | 55-56 | | 闪点 | 29 | | 密度 | 1.048 | | 折光率(n20D) | 1.5160 | | MDLç¼–ç | MFCD00168823 |
å®‰å…¨ä¿¡æ¯ | 图形或å±å®³æ ‡å¿— | | | æç¤ºè¯ | Danger | | å±é™©è¯´æ˜Ž | H228
H315
H319
H335 | | 防范说明 | P210
P261
P305+P351+P338 | | UNå·ç | 1325 | | å±é™©åˆ†ç±» | 4.1 | | 包装ç‰çº§ | II | | WGK | 3 | | TSCA | å¦ |
|
| H26269 | Alfa Aesar | 4-Fluorophenylacetylene | 99% | 883元/1g; 3554元/5g; 11758元/25g; | 咨询 |
应用
Intermediates of liquid Crystals. As pharmaceutical intermediates. As organic synthesis intermediates. For vacuum deposition. 备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heavy metal powders. åŸºæœ¬ä¿¡æ¯ MDL
MFCD00168823 分åå¼
C8H5F 分åé‡
120.12 熔点
27-28° 沸点
55-56°/40mm 闪点
29°(85°F) 密度
1.048 折射率
1.5170 çµæ•åº¦
Ambient temperatures. å½¢æ€
Low melting solid 溶解性
Soluble in chloroform, diethyl ether, acetone, dichloromethane, hexane and ethanol. Highly soluble in toluene. Insoluble in water. Beilstein
1099285 GHSå±å®³å’Œé˜²èŒƒè¯´æ˜Ž GHS符å·
Hazard Statements
H228-H319-H335
Flammable solid.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P210-P305+P351+P338
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. å®‰å…¨ä¿¡æ¯ å±é™©ç‰çº§
4.1 包装组
III å±é™©ç±»åˆ«
11-36/37
Highly flammable.Irritating to eyes and respiratory system. 安全ç‰çº§
16-26
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 欧盟å±é™©å“æ ‡å¿—
 TSCA
å¦ |
| C37137 | Alfa Aesar | 1-Ethynyl-4-fluorobenzene | 98% | 1069元/1g; 3506元/5g; | 咨询 |
åŸºæœ¬ä¿¡æ¯ Ref#
37137 MDL
168823 分åå¼
C8 H5 F 分åé‡
120.13 闪点
29 密度
1048 å½¢æ€
Colorless to pale yellow liquid as melt å®‰å…¨ä¿¡æ¯ å±é™©ç‰çº§
4.1 包装组
II |
| 404330 | Sigma-Aldrich | 1-Ethynyl-4-fluorobenzene | 99% | 481.43元/1 G; 824.49元/5 G; | 咨询 |
产å“说明 一般æè¿° 1-乙炔基-4-氟苯 (pFAB) 是一ç§æ°Ÿè‹¯è¡ç”Ÿç‰©ã€‚本文报é“了三阴离å钳型烷基苯å¤åˆç‰©å‚¬åŒ–çš„ 1-乙炔基-4-氟苯èšåˆã€‚碘苯基端有机å•å±‚的表é¢é€šè¿‡ pFAB 与表é¢ä¸Šå‘现的碘苯基的薗头å¶åˆå进行修饰。由 Y [N (TMS) 2 3 å’Œ 4-氯苯胺催化的二èšåŒ–å应以æžå¥½çš„产率得到三ç§å¯èƒ½çš„烯二炔ä¸çš„一ç§ã€‚ 应用 1-乙炔基-4-氟苯是一ç§å–代的苯乙炔，它å¯ä¸Žå¤šç§å¤ä»£èŠ³çƒƒé€šè¿‡è–—头å¶åˆååº”ï¼Œåœ¨åŒ (μ~ +)ã€åŒ (μ~ +)ã€å• (μ~ +)ã€åŒ (μ~ +)ã€å• (μ~ +)ã€åŒ (μ~ +)ã€å• (μ~ +)ã€åŒ (μ~ +)ã€åŒ (μ~ +)-碘)åŒ((-)-å¸å·´ä¸)åŒ (I) 催化剂。
1-乙炔基-4-氟苯å¯ç”¨äºŽä»¥ä¸‹åˆæˆï¼š - 在铜催化剂å˜åœ¨ä¸‹ï¼Œ3-(4-氟苯基)-1 H -异色-1-酮与 2-碘苯甲酸å应。
- 4-溴-3,5-二氟-2,6-åŒ-(4-æ°Ÿ-苯乙炔基)-å¡å•¶é€šè¿‡é’¯å‚¬åŒ–的薗头å¶åˆå应与 2,4,6-三溴-3,5-二氟å¡å•¶å应。
- 1-(4-氟苯基)-3-甲氧基-3-(4-甲氧基苯基)丙-1-酮与 p -茴香醛å应。
- 在å æ°®åŒ–é’ å˜åœ¨ä¸‹ï¼Œ5-(4-氟苯基)-1-(2-ç¡åŸºè‹„基)-1 H -1,2,3-三唑与 1-(溴甲基)-2-ç¡åŸºè‹¯å应。
包装 1, 5 g in glass bottle åŸºæœ¬ä¿¡æ¯ | 线性分åå¼ | FC6H4C≡CH | | 分åé‡ | 120.12 | | Beilstein | 1099285 | | MDLç¼–å· | MFCD00168823 | | PubChem化å¦ç‰©è´¨ç¼–å· | 24865238 | | NACRES | NA.22 |
产å“性质 | è´¨é‡æ°´å¹³ | 200 | | 测定 | 99% | | 折射率 | n20/D 1.516 (lit.) | | bp | 55-56 ℃/40 mmHg (lit.) | | mp | 26-27 ℃ (lit.) | | 密度 | 1.048 g/mL at 25 ℃ (lit.) | | 储å˜æ¸©åº¦ | 2-8℃ | | SMILES string | Fc1ccc(cc1)C#C | | InChI | 1S/C8H5F/c1-2-7-3-5-8(9)6-4-7/h1,3-6H | | InChI key | QXSWHQGIEKUBAS-UHFFFAOYSA-N |
å®‰å…¨ä¿¡æ¯ | 象形图 | | | è¦ç¤ºç”¨è¯ï¼š | Danger | | å±é™©å£°æ˜Ž | H228 - H315 - H319 - H335 | | 预防措施声明 | P210 - P240 - P241 - P261 - P302 + P352 - P305 + P351 + P338 | | å±é™©åˆ†ç±» | Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 | | é¶å™¨å®˜ | Respiratory system | | 储å˜åˆ†ç±»ä»£ç | 4.1B - Flammable solid hazardous materials | | WGK | WGK 3 | | 闪点(F) | 84.2 °F - closed cup | | 闪点(C) | 29 ℃ - closed cup | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
|
| 916051 | Amethyst | 1-Ethynyl-4-fluorobenzene | 98%, 用于åˆæˆ | 140å…ƒ/1G; 510å…ƒ/5G; 709å…ƒ/25G; 2709å…ƒ/100G; | 咨询 |
åŸºæœ¬ä¿¡æ¯ | 分åå¼ | C8H5F | | 分åé‡ | 120.12 | | 熔点 | 27-28 | | 沸点 | 55-56 | | 闪点 | 29 | | 密度 | 1.048 | | 折光率(n20D) | 1.5160 | | MDLç¼–ç | MFCD00168823 |
å®‰å…¨ä¿¡æ¯ | 图形或å±å®³æ ‡å¿— | | | æç¤ºè¯ | Danger | | å±é™©è¯´æ˜Ž | H228
H315
H319
H335 | | 防范说明 | P210
P261
P305+P351+P338 | | UNå·ç | 1325 | | å±é™©åˆ†ç±» | 4.1 | | 包装ç‰çº§ | II | | WGK | 3 | | TSCA | å¦ |
|
| 008808 | Fluorochem | 4-Fluorophenylacetylene | 99% | 440元/1g; 1232元/5g; | 咨询 |
åŸºæœ¬ä¿¡æ¯ | CAS Number | 766-98-3 | | MDL Number | MFCD00168823 | | Boiling Point | 42-44℃/20mm | | Melting Point | 26-28℃ | | Density | 1.048 |
å®‰å…¨ä¿¡æ¯ | 图形或å±å®³æ ‡å¿— | | | å±é™©æ€§è¯´æ˜Ž | H228: Flammable solid.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof / equipment.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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