CAS 762-72-1; 烯丙基三甲基硅烷; allytrimethylsilane

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货号

品牌

产品名称

规格

包装、参考价格

A800570

MACKLIN

烯丙基三甲基硅烷

97%

69元/5ml; 235元/25ml; 610元/100ml;

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储存：2~8 ℃
状态：无色液体
折射率：n20/D 1.407(lit.)

A0729

TCI

Allyltrimethylsilane

>98.0%(GC)

545元/25ML; 2790元/250ML;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₆H₁₄Si = 114.26
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
Reaxys-RN	906755
PubChem物质ID	87562275
SDBS (AIST Spectral DB)	5609
MDL编号	MFCD00008635

技术规格

Appearance	Colorless to Almost colorless clear liquid
Purity(GC)	min. 98.0 %

物性(参考值)

沸点	83 ℃
闪点	7 ℃
比重	0.72
折射率	1.41

安全信息

图形或危害标志
信号词	危险
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H225 : 高度易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。 P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号	UN1993
类别	3
包装类别	II
监管条件代码(*)

217264

J&K

Allyltrimethylsilane

97%

110元/10ml;

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基本信息

分子式	C₆H₁₄Si
分子量	114.26
沸点	84-88
闪点	16
密度	0.719
折光率(n20D)	1.4070
MDL编码	MFCD00008635
Beilstein	906755
EINECS 编号	212-104-5
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H225 H315 H319 H335
防范说明	P210 P261 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	II
WGK	3
TSCA	是

531623

J&K

Allyltrimethylsilane

98%

207元/10G; 702元/50G;

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基本信息

分子式	C₆H₁₄Si
分子量	114.26
沸点	84-88
闪点	16
密度	0.719
折光率(n20D)	1.4070
MDL编码	MFCD00008635
Beilstein	906755
EINECS 编号	212-104-5
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H225 H315 H319 H335
防范说明	P210 P261 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	II
WGK	3
TSCA	是

A14662

Alfa Aesar

Allyltrimethylsilane

98+%

801元/10g; 2284元/50g; 9512元/250g;

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应用
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.

备注
Store in cool place. Incompatible with strong oxidizing agents and acids.

基本信息

MDL
MFCD00008635

EINECS
212-104-5

分子式
CH₂=CHCH₂Si(CH₃)₃

分子量
114.27

沸点
85-86°

闪点
-10°(14°F)

密度
0.717

折射率
1.4080

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with organic solvents. Immiscible with water.

Beilstein
906755

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H315-H319-H335
Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
II

危险类别
11-36/37/38
Highly flammable.Irritating to eyes, respiratory system and skin.

安全等级
9-16-23-26-33-37
Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.

欧盟危险品标志

TSCA
是

C19699

Alfa Aesar

Allyltrimethylsilane

99%

1249元/10ml; 3538元/50ml; 13732元/250ml;

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基本信息

Ref#
19699

MDL
8635

分子式
C6 H14 Si

分子量
114.27

闪点
7

密度
0.719

形态
Liquid

安全信息

危险等级
3

包装组
II

C34999

Alfa Aesar

Allyltrimethylsilane

97%

1001元/10ml; 2829元/50ml;

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基本信息

Ref#
34999

MDL
8635

分子式
C6 H14 Si

分子量
114.27

闪点
7

密度
0.719

安全信息

危险等级
3

包装组
II

931298

Amethyst

Allyltrimethylsilane

97%, 用于合成

80元/5ML; 275元/25ML; 835元/100ML;

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基本信息

分子式	C₆H₁₄Si
分子量	114.26
沸点	84-88
闪点	16
密度	0.719
折光率(n20D)	1.406 to 1.408
MDL编码	MFCD00008635
Beilstein	906755
EINECS 编号	212-104-5
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H225 H315 H319 H335
防范说明	P210 P261 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	II
WGK	3
TSCA	是

S00450

Fluorochem

Allyltrimethylsilane

98%

264元/10g; 440元/25g; 1056元/100g;

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基本信息

CAS Number	762-72-1
MDL Number	MFCD00008635
Boiling Point	83℃
Density	0.72

安全信息

图形或危害标志
危险性说明	H225: Highly flammable liquid and vapour. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H411: Toxic to aquatic life with long lasting effects.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P235: Keep cool. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use CO2, powder or sand for extinction. P391: Collect spillage. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.