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CAS: 762-42-5
分子式: C6H6O4
分子量: 142.11
沸点: 95-98℃(1
熔点: -18 °C
中文名称: 
丁炔二酸二甲酯
英文名称: 
1,2-bis(methoxycarbonyl)ethyne
2-butynedioic acid, dimethyl ester
acetylenedicarboxylic acid dimethyl ester
acetylenedicarboxylic acid, dimethyl ester
di(carbomethoxy)acetylene
dimethyl acetylenedicarboxylic acid
dimethyl ethynedicarboxylate
methyl acetylenedicarboxylate
dimethyl acetylenedicarboxylate
but-2-ynedioic acid dimethyl ester
Butynedioic acid dimethyl ester
Dimethyl 2-butynedioate
展开更多英文名
性质描述: 无色液体。沸点95-98℃(2.53kPa)。
生产方法: 丁炔二甲酸钾与甲醇在浓硫酸存在下室温反应4d,以72-88%的收率生成丁炔二酸二甲酯。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
D823847MACKLIN丁炔二酸二甲酯≥98%(GC)30元/5g;   72元/25g;   215元/100g;   858元/500g;   咨询
储存:室温,避光
状态:无色到浅黄色液体
折射率:n20/D 1.447(lit.)
A0090TCIDimethyl Acetylenedicarboxylate>96.0%(GC)485元/25ML;   1380元/100ML;   咨询

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C6H6O4 = 142.11
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气,加热
Reaxys-RN607063
PubChem物质ID87561787
SDBS (AIST Spectral DB)10447
MDL编号MFCD00008456

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 96.0 %

物性(参考值)

沸点198 ℃
闪点86 ℃
比重1.16
折射率1.45

安全信息

图形或危害标志
信号词危险
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

相关法规

RTECS#ES0175000

运输信息

UN编号UN1760
类别8
包装类别 III
监管条件代码(*)
353191J&KDimethyl Acetylenedicarboxylate98%78元/5G;   102元/25G;   354元/100G;   咨询

基本信息

分子式C6H6O4
分子量142.11
沸点95-98
闪点86
密度1.156
折光率(n20D)1.4470
MDL编码MFCD00008456
Beilstein607063
EINECS 编号212-098-4

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
防范说明P280
P305+P351+P338
P310
UN号码3265
危险分类8
包装等级II
WGK3
RTECSES0175000
045131Alfa AesarDimethyl Acetylenedicarboxylate95%1655元/25g;   4999元/100g;   24716元/500g;   咨询

应用
Dimethyl acetylenedicarboxylate as a versatile dienophile used in Diels-Alder reactions.

备注
Light Sensitive. Store away from strong oxidizing agents. keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00008456

EINECS
212-098-4

分子式
C6H6O4

分子量
142.11

熔点
-18°

沸点
95-98°/19mm

闪点
86°(186°F)

密度
1.156

折射率
1.4470

灵敏度
Light Sensitive. Ambient temperatures.

形态
Colorless to pale yellow liquid

溶解性
Soluble in most organic solvents. Insoluble in water.

Beilstein
607063

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H314-H318
Combustible liquid.Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34
Harmful if swallowed.Causes burns.

安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
ES0175000

TSCA

A11437Alfa AesarDimethyl Acetylenedicarboxylate98%1676元/25g;   2956元/100g;   12824元/500g;   咨询

应用
It acts as an inhibitor of oxidative phosphorylation. It is also used in Pharmaceutical and electronic industry. It is used in organic synthesis. It also acts as an intermediate in chemical research. It is also used in Diels-Alder Reaction.

备注
Stable under normal conditions. Incompatabile to strong oxidizing agents, strong acids, strong bases, Strong reducing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

基本信息

MDL
MFCD00008456

EINECS
212-098-4

分子式
C6H6O4

分子量
142.11

熔点
-18°

沸点
95-98°/19mm

闪点
86°(186°F)

密度
1.156

折射率
1.4480

灵敏度
Light Sensitive. Ambient temperatures.

形态
Liquid

溶解性
It is insoluble in water but soluble in ethanol, ethyl ether, CCl4, miscible with organic solvents.

Beilstein
607063

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H314-H318
Combustible liquid.Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34
Harmful if swallowed.Causes burns.

安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
ES0175000

TSCA

C11571Alfa AesarDimethyl Acetylenedicarboxylate98%551元/5g;   1709元/25g;   4987元/100g;   23041元/500g;   咨询

基本信息

Ref#
11571

MDL
8456

分子式
C6 H6 O4

分子量
142.11

闪点
86

密度
1.16

形态
Colorless to pale yellow liquid

安全信息

危险等级
8

包装组
II

D138401Sigma-AldrichDimethyl Acetylenedicarboxylate95%319.45元/5 g;   779.52元/25 g;   咨询

产品说明

应用

用于 Diels-Alder 反应的多功能亲二烯体。

包装

5, 25 g in glass bottle

基本信息

线性分子式CH3OCOC≡CCO2CH3
分子量142.11
Beilstein607063
EC 号212-098-4
MDL编号MFCD00008456
PubChem化学物质编号24893421
NACRESNA.22

产品性质

质量水平200
测定99%
折射率n20/D 1.447 (lit.)
bp95-98 ℃/19 mmHg (lit.)
密度1.156 g/mL at 25 ℃ (lit.)
SMILES stringCOC(=O)C#CC(=O)OC
InChI1S/C6H6O4/c1-9-5(7)3-4-6(8)10-2/h1-2H3
InChI keyVHILMKFSCRWWIJ-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 - H314
预防措施声明P270 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)186.8 °F - closed cup
闪点(C)86 ℃ - closed cup
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
978083AmethystDimethyl Acetylenedicarboxylate98%, 用于合成57元/5G;   96元/25G;   242元/100G;   824元/500G;   咨询

基本信息

分子式C6H6O4
分子量142.11
沸点95-98
闪点86
密度1.156
折光率(n20D)1.4470
MDL编码MFCD00008456
Beilstein607063
EINECS 编号212-098-4

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
防范说明P280
P305+P351+P338
P310
UN号码3265
危险分类8
包装等级II
WGK3
RTECSES0175000
049730FluorochemDimethyl Acetylenedicarboxylate98%330元/25g;   1056元/100g;   2090元/250g;   咨询

基本信息

CAS Number762-42-5
MDL NumberMFCD00008456
Density1.16

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations..
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