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CAS: 759-65-9
分子式: C9H14O5
分子量: 202.21
沸点: 133°C|23mmHg(lit.)
中文名称: 
草酰丙酸二乙酯
英文名称: 
Diethyl 2-methyl-3-oxosuccinate
2-Ethoxalylpropionic Acid Ethyl Ester
Diethyl Methyloxalacetate
Ethyl 2-Ethoxalylpropionate
methyloxo-butanedioic aci diethyl ester
diethyl oxalpropionate
性质描述: 无色油状液体。沸点198-202℃,138℃(3.07kPa),相对密度(20/4℃)1.098,折光率(nD20)1.434。
生产方法: 由丙酸乙酯和草酸二乙酯反应得到。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
D862749MACKLIN草酰丙酸二乙酯96%(GC)62元/5g;   295元/25g;   1175元/100g;   咨询
储存:室温,干燥
状态:无色到微黄绿色到橙色到绿色液体
D797227MACKLIN草酰丙酸二乙酯10mM in DMSO168元/1ml;   咨询
储存:-20°C
M0381TCIDiethyl Methyloxalacetate>96.0%(GC)685元/25G;   咨询

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C9H14O5 = 202.21
外观与形状(20℃)液体
Reaxys-RN1783697
PubChem物质ID87572446
SDBS (AIST Spectral DB)89
MDL编号MFCD00009163

技术规格

AppearanceColorless to Orange to Green clear liquid
Purity(GC)min. 96.0 %

物性(参考值)

沸点133 ℃/23 mmHg
闪点97 ℃
比重1.09
折射率1.43
137766Sigma-AldrichDiethyl oxalpropionate≥95%575.08元/25 G;   1588.37元/100 G;   咨询

产品说明

应用

Reactant involved in:

  • Synthesis of anticancer and antiviral agents
  • Oxidation by organohypervalent iodine reagent
  • Synthesis of monomers for preparation of functional polyesters
  • Synthesis of calpain inhibitors
  • Preparation of human A2A receptor antagonists
  • Structural studies of dihydropteroate synthase inhibitors

Diethyl oxalpropionate was used in the synthesis of 2-hydroxy-3-methylsuccinic acid. It was used as starting reagent in the synthesis of racemic 4-alkyloxycarbonyl-3,3-dimethyl-2-oxetanones and 4-quinolinone 2-carboxylic acid.

包装

25, 100 g in glass bottle

基本信息

线性分子式C2H5OCOCH(CH3)COCOOC2H5
分子量202.20
Beilstein1783697
EC 号212-071-7
MDL编号MFCD00009163
PubChem化学物质编号24848348
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式liquid
折射率n20/D 1.432 (lit.)
bp138 ℃/23 mmHg (lit.)
密度1.073 g/mL at 25 ℃ (lit.)
SMILES stringCCOC(=O)C(C)C(=O)C(=O)OCC
InChI1S/C9H14O5/c1-4-13-8(11)6(3)7(10)9(12)14-5-2/h6H,4-5H2,1-3H3
InChI keyOQOCQBJWOCRPQY-UHFFFAOYSA-N

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)206.6 °F - closed cup
闪点(C)97 ℃ - closed cup
个人防护装备Eyeshields, Gloves
498996FluorochemDiethyl 2-methyl-3-oxosuccinate95+%242元/5g;   440元/10g;   836元/25g;   2266元/100g;   咨询

基本信息

CAS Number759-65-9
MDL NumberMFCD00009163
Boiling Point133℃
Density1.09

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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