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CAS: 75732-01-3
分子式: C9H11Cu
分子量: 182.73
英文名称: 
mesitylcopper
推荐供应商
货号品牌产品名称规格包装、参考价格
M918811MACKLIN荚基化铜(I)30.6-39.0%Cu431元/100mg;   927元/250mg;   咨询
储存:2-8°C,密闭,干燥
29-5550StremMesitylcopper(I)min. 95%2100元/1g;   8370元/5g;   咨询

Technical Note:

1.Starting material for a variety of copper(I) complexes.

736627Sigma-AldrichMesitylcopper(I)2624.29元/1 G;   9554.26元/5 G;   咨询

产品说明

一般描述

Mesitylcopper(I) is a thermally stable and highly soluble organocopper compound, which is commonly used as a metalation reagent in organic synthesis. In mixed lithium cuprate reagents, mesitylcopper serves as a useful ″holding group″. It is very sensitive to moisture and air therefore reactions must be carried out under anhydrous conditions.

应用

Mesitylcopper(I) is can be used to synthesize:

  • Homo and heteroleptic copper(I) complexes such as Cu(I) alkoxides, siloxides, phosphates, amides, and phosphides.
  • Biorelevant copper(I) complexes as biomimetic model compounds.
  • Copper nanoparticles from stabilizing primary amines.

It can also be used as a selective mesityl group transfer reagent in stoichiometric C−C and C−heteroatom bond-forming reactions.

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C9H11Cu
分子量182.73
MDL编号MFCD00015622
PubChem化学物质编号329765125
NACRESNA.22

产品性质

reaction suitabilitycore: copper
reagent type: catalyst
质量水平100
mp184-191 ℃
储存温度2-8℃
SMILES stringCc1cc(C)c([Cu])c(C)c1
InChI1S/C9H11.Cu/c1-7-4-8(2)6-9(3)5-7;/h4-5H,1-3H3;
InChI keyBBUKMFLZOHNUQU-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9
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