CAS 74-94-2; 氢化硼(T-4)二甲基胺; dimethylamine borane(1:1)

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产品名称

规格

包装、参考价格

B802453

MACKLIN

二甲胺基甲硼烷

10%的水溶液

33元/100ml; 97元/500ml; 158元/1L; 375元/2.5L; 1380元/10L;

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储存：2~8°C
状态：液体

B802452

MACKLIN

二甲胺基甲硼烷

96%

30元/5g; 69元/25g; 199元/100g; 660元/500g; 3240元/2.5kg;

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储存：2~8°C
状态：白色晶体或颗粒

D1842

TCI

Dimethylamine Borane

>95.0%(T)

195元/25G; 690元/100G; 2490元/500G;

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基本信息

纯度/分析方法	>95.0%(T)
分子式/分子量	C₂H₇N・BH₃ = 58.92
外观与形状(20℃)	固体
储存温度	0-10℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,加热
Reaxys-RN	4132650
PubChem物质ID	87568308
MDL编号	MFCD00051068

技术规格

Appearance	White powder to crystal
Purity(Iodometric Titration)	min. 95.0 %
Melting point	35.0 to 38.0 ℃
Solubility in Methanol	almost transparency

物性(参考值)

熔点	37 ℃
闪点	43 ℃
溶解性(可溶于)	甲醇

安全信息

图形或危害标志
信号词	危险
危险性说明	H301 + H311 : 吞咽或皮肤接触可致中毒。 H314 : 造成严重皮肤灼伤和眼损伤。 H228 : 易燃固体。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P260 : 不要吸入粉尘或烟雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P241 : 使用防爆的电气/通风/照明设备。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P405 : 存放处须加锁。

相关法规

RTECS#

IP9450000

运输信息

UN编号	UN2926
类别	4.1 / 6.1
包装类别	II
监管条件代码(*)

279744

J&K

Dimethylamine Borane

98%

98元/5G; 358元/25G; 1098元/100G;

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基本信息

分子式	C₂H₁₀BN
分子量	58.92
熔点	35-37
闪点	43
密度	0.69
MDL编码	MFCD00051068
Beilstein	4132650
EINECS 编号	200-823-7
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H228 H301 H311
防范说明	P210 P280 P301+P310 P312
UN号码	2926
危险分类	4.1
次要危险性	6.1
包装等级	II
WGK	2
RTECS	IP9450000
TSCA	是

93-0554

Strem

Borane, dimethylamine complex

min. 97%

405元/10g; 1635元/50g;

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089149

Alfa Aesar

Borane-dimethylamine complex

97%

1014元/25g; 4087元/100g;

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应用
Borane-dimethylamine complex is used in a nickel-catalyzed reduction of electron-deficient aryl tosylates. It also serves as a reducing agent in electrolytic deposition of metals, alloys, semiconductors and insulators.

备注
Store in a cool place. Incompatible with acids, oxidizing agents, heavy metal salts and oxygen.

基本信息

MDL
MFCD00051068

EINECS
200-823-7

分子式
BH₃.NH(CH₃)₂

分子量
58.92

熔点
36°

沸点
59-65°/1-2mm

密度
0.69

灵敏度
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in methanol, water, ethanol, 2-propanol and terahydrofuran.

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H301-H311-H330-H314-H318
Flammable solid.Toxic if swallowed.Toxic in contact with skin.Fatal if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P301+P310a-P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment is urgent (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.1

包装组
II

危险类别
11-23/24/25-34
Highly flammable.Toxic by inhalation, in contact with skin and if swallowed.Causes burns.

安全等级
4-9-20-26-27-36/37/39-45
Keep away from living quarters.Keep container in a well-ventilated place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take off immediately all contaminated clothing.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

RTECS
IP9450000

TSCA
是

C17731

Alfa Aesar

Borane-dimethylamine complex

98+%

338元/5g; 886元/25g; 2902元/100g; 9876元/500g;

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基本信息

Ref#
17731

MDL
51068

分子式
C2 H10 B N

分子量
58.92

闪点
65

形态
Crystalline

安全信息

危险等级
4.1

包装组
II

180238

Sigma-Aldrich

Borane dimethylamine complex

97%

327.1元/5 G; 744.52元/25 G; 975.19元/100 G;

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产品说明

包装

5, 25, 100 g in glass bottle

应用

用于缺电子芳基甲苯磺酸酯的镍催化还原反应的试剂。该催化剂由市售 Ni(PPh₃)₂Cl₂(529621) 和 PCy₃(261971) 组成。

基本信息

线性分子式	(CH₃)₂NH · BH₃
分子量	58.92
EC 号	200-823-7
MDL编号	MFCD00051068
PubChem化学物质编号	24850856
NACRES	NA.22

产品性质

质量水平	200
测定	97%
reaction suitability	reagent type: reductant
mp	36 ℃ (lit.)
储存温度	2-8℃
SMILES string	[BH3-][NH+](C)C
InChI	1S/C2H10BN/c1-4(2)3/h4H,1-3H3
InChI key	RUOMFVPJBOADHA-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H228 - H301 + H311 - H317 - H318 - H332 - H411
预防措施声明	P210 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
危险分类	Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 1 - Skin Sens. 1
储存分类代码	4.1B - Flammable solid hazardous materials
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

043439

Fluorochem

Dimethylamine Borane

97%

220元/1g; 418元/10g; 792元/25g; 2904元/100g;

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基本信息

CAS Number	74-94-2
MDL Number	MFCD00051068

安全信息

图形或危害标志
危险性说明	H228: Flammable solid. H301: Toxic if swallowed. H311: Toxic in contact with skin. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof / equipment. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P361: Remove/Take off immediately all contaminated clothing. P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P370 + P378: In case of fire: Use for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.