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CAS: 71989-18-9
分子式: C24H27NO6.H2O
分子量: 443.49
熔点: 89-93℃
中文名称: 
Fmoc-O-叔丁基-L-谷氨酸
芴甲氧羰基-O-叔丁基-L-谷氨酸
芴甲氧羰基-L-谷氨酸5-叔丁酯
芴甲氧羰基-谷氨酸侧链叔丁脂
FMOC-L-谷氨酸5-叔丁酯
英文名称: 
Fmoc-L-glutamic acid 5-tert-butyl ester
Fmoc-Glu(OtBu)-OH
fmoc-l-glutamic acid-o-t-butyl ester monohydrate
Fmoc-L-Glutamic acid γ-tert-butyl ester
推荐供应商
货号品牌产品名称规格包装、参考价格
F809405MACKLINFmoc-|O|-叔丁基-|L|-谷氨酸98%40元/5g;   130元/25g;   450元/100g;   2188元/500g;   8750元/2.5kg;   咨询
储存:2~8°C
折射率:-4 ° (C=1, 80% AcOH)
B3167TCI5-tert-Butyl N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-L-glutamate>98.0%(T)(HPLC)490元/5G;   1350元/25G;   咨询

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C24H27NO6 = 425.48
外观与形状(20℃)固体
Reaxys-RN3636375
PubChem物质ID87560119
SDBS (AIST Spectral DB)52147
MDL编号MFCD00037135

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %(calcd.on anh.substance)
Melting point87.0 to 93.0 ℃
Specific rotation [a]20/D-7.0 to -10.0 deg(C=1, MeOH)
Watermax. 6.0 %

物性(参考值)

熔点90 ℃
比旋光度 [α]D-8° (C=1,MeOH)
溶解性(可溶于)甲醇
237637J&KNα-Fmoc-L-glutamic-acid 5-tert-butyl ester98%78元/250MG;   117元/1G;   466元/5G;   1283元/25G;   咨询

基本信息

分子式C24H27NO6
分子量425.47
熔点83-90
比旋光度([α]20D)-10.5° to -6.5° (C=1, MeOH)
MDL编码MFCD00037135
Beilstein3636375
EINECS 编号276-253-8
存储条件Store at 2-8℃

安全信息

WGK3
TSCA
H59169Alfa AesarN-Fmoc-L-glutamic acid 5-tert-butyl ester98%1240元/5g;   4508元/25g;   咨询

基本信息

MDL
MFCD00037135

EINECS
276-253-8

分子式
C24H27NO6

分子量
425.48

熔点
83-90°

形态
Powder

Beilstein
3636375

安全信息

TSCA

47625Sigma-AldrichFmoc-Glu(OtBu)-OH≥98.0% (HPLC)1884.09元/10 G;   2227.41元/25 G;   3949.02元/100 G;   11393.9元/1 KG;   咨询

产品说明

应用

Fmoc-Glu(OtBu)-OH(氧羰基-L-谷氨酸 5--丁酯)可用于:

  • 配体,以使用Pd催化剂通过环丙烷酰胺C-H活化反应合成顺式取代环丙烷羧酸。
  • 多小分子共轭PTX(紫杉醇)衍生物制备中的连接剂。

还可用作基本构成要素制备钉状α-螺旋肽和肽C-端硫代酸酯。

包装

10, 25, 100 g in poly bottle
1 kg in poly bottle

基本信息

经验(实验)分子式C24H27NO6
分子量425.47
Beilstein3636375
EC 号276-253-8
MDL编号MFCD00037135
eCl@ss32160406
PubChem化学物质编号57651045
NACRESNA.26

产品性质

测定≥98.0% (HPLC)
旋光性[α]20/D −5.0±2.0°, c = 1% in acetic acid: water (4:1)
reaction suitabilityreaction type: Fmoc solid-phase peptide synthesis
杂质~4% water
application(s)peptide synthesis
官能团Fmoc
储存温度2-8℃
SMILES stringCC(C)(C)OC(=O)CC[C@H](NC(=O)OCC1c2ccccc2-c3ccccc13)C(O)=O
InChI1S/C24H27NO6/c1-24(2,3)31-21(26)13-12-20(22(27)28)25-23(29)30-14-19-17-10-6-4-8-15(17)16-9-5-7-11-18(16)19/h4-11,19-20H,12-14H2,1-3H3,(H,25,29)(H,27,28)/t20-/m0/s1
InChI keyOTKXCALUHMPIGM-FQEVSTJZSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
8.52009Sigma-AldrichFmoc-Glu(OtBu)-OHNovabiochem®636.66元/25 G;   1916.21元/100 G;   4084.74元/250 G;   7640元/500 G;   咨询

产品说明

一般描述

The product number for this product was previously 04-12-1020.

To obtain a certificate of analysis (CoA) of a lot that begins with the letter “A”, please select the option in the right hand menu “Request a COA for Lot#s starting with A”.

联系

Replaces: 04-12-1020

分析说明

Colour (visual): white to off white
Appearance of substance (visual): powder
Colour index (0,5 M in DMF): ≤ 150 Hazen
Identity (IR): passes test
Enantiomeric purity: ≥ 99.8 % (a/a)
Purity (HPLC): ≥ 99.0 % (a/a)
Fmoc-ß-Ala-OH (HPLC): ≤ 0.1 % (a/a)
Fmoc-ß-Ala-Glu(OtBu)-OH (HPLC): ≤ 0.1 % (a/a)
Fmoc-Glu(OtBu)-Glu(OtBu)-OH (HPLC): ≤ 0.1 % (a/a)
Fmoc-Glu-OH (HPLC): ≤ 0.1 % (a/a)
Assay free amino acid (GC): ≤ 0.2 %
Purity (TLC(0811)): ≥ 98 %
Purity (TLC(011A)): ≥ 98 %
Solubility (25 mmole in 50 ml DMF): clearly soluble
Assay (acidimetric): ≥ 95.0 %
Water (K. F.): ≤ 5.0 %
Ethyl acetate (HS-GC): ≤ 0.5 %
Acetate (IC): ≤ 0.02 %
For TLC-Systems see our General Catalog

法律信息

Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany

基本信息

经验(实验)分子式C24H27NO6
分子量425.47
MDL编号MFCD00037135
EC索引号276-253-8

产品性质

质量水平400
产品线Novabiochem®
测定≥95.0% (acidimetric)
≥98% (TLC)
≥99.0% (HPLC)
形式powder
reaction suitabilityreaction type: Fmoc solid-phase peptide synthesis
manufacturer/tradenameNovabiochem®
mp80-95 ℃
application(s)peptide synthesis
官能团Fmoc
储存温度2-30℃
InChI1S/C24H27NO6/c1-24(2,3)31-22(28)20(12-13-21(26)27)25-23(29)30-14-19-17-10-6-4-8-15(17)16-9-5-7-11-18(16)19/h4-11,19-20H,12-14H2,1-3H3,(H,25,29)(H,26,27)
InChI keyGOPWHXPXSPIIQZ-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
M03409FluorochemFmoc-Glu(OtBu)-OH99%550元/25g;   1672元/100g;   咨询

基本信息

CAS Number71989-18-9
MDL NumberMFCD00037135
Melting Point85-93℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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