CAS 70187-32-5; 氧化-4-甲基吗啉一水合物; 4-Methylmorpholine-4-oxide monohydrate

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货号

品牌

产品名称

规格

包装、参考价格

M814351

MACKLIN

4-甲基吗啡-|N|-氧化物,一水合物

98%

27元/5g; 35元/25g; 132元/100g; 630元/500g; 3140元/2.5kg;

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储存：2~8°C
状态：白色到奶油色粉末或晶体

166478

J&K

4-Methylmorpholine N-oxide monohydrate

97%

307元/25G; 855元/100G;

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基本信息

分子式	C₅H₁₁NO₂·H₂O
分子量	135.16
熔点	73-75
MDL编码	MFCD00149388
Beilstein	507437
EINECS 编号	231-391-8
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	1
TSCA	否

A15996

Alfa Aesar

4-Methylmorpholine N-oxide monohydrate

98+%

635元/10g; 1494元/25g; 2773元/50g; 5199元/100g;

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应用
4-Methylmorpholine N-oxide monohydrate is used as a solvent to prepare cellulose fibers. It is an oxidant and involved in the catalytic OsO₄ oxidation of olefins to cis-1,2-diols. It is also involved in ruthenium catalyzed oxidation of alcohols to aldehydes and ketones.

备注
Hygroscopic. Store in a cool place. Keep the container tightly closed. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00149388

EINECS
231-391-8

分子式
C₅H₁₁NO₂?H₂O

分子量
135.17 (117.15anhy)

熔点
73-76°

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystals or lumps

溶解性
Soluble in water.

Beilstein
5449441

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
是

67873

Sigma-Aldrich

4-Methylmorpholine N-oxide monohydrate

≥95.0% (N)

2144.39元/100 G;

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产品说明

应用

4-甲基吗啉N-氧化物(MNO)一水合物可用于：

在四氧化锇(OsO₄)催化下，作为烯烃二羟基化和氨羟基化反应的试剂。
在锰和铜与四齿配体的络合物存在下，将硫化物选择性的氧化成亚砜或砜。

包装

25, 100 g in poly bottle

其他说明

用于改进烯烃的催化 OsO₄ 氧化反应的试剂，该反应生成顺-1,2-二醇；综述；用于醇的钌催化氧化反应，生成醛和酮

基本信息

经验(实验)分子式	C₅H₁₁NO₂ · H₂O
分子量	135.16
Beilstein	507437
EC 号	231-391-8
MDL编号	MFCD00149388
PubChem化学物质编号	57652112
NACRES	NA.22

产品性质

质量水平	100
测定	≥95.0% (N)
mp	71-75 ℃
SMILES string	O.C[N+]1([O-])CCOCC1
InChI	1S/C5H11NO2.H2O/c1-6(7)2-4-8-5-3-6;/h2-5H2,1H3;1H2
InChI key	WAZPLXZGZWWXDQ-UHFFFAOYSA-N

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 1
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

228951

Fluorochem

4-Methylmorpholine 4-oxide monohydrate

95%

220元/10g; 440元/25g; 880元/100g;

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基本信息

CAS Number	70187-32-5
MDL Number	MFCD00005947
Melting Point	71-75℃
Density	1

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .