Technical Notes:

1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.

2.Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids

3.Chiral ligands for rhodium-catalyzed arylation of a-ketoesters with arylboronic acids.

4.Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes .

5.Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-ß-arylenamides.

References:

1.Org. Lett. 2006, 8, 1479.

2.Org. Lett. 2006, 8, 2567 .

3.Angew. Chem. Int. Ed. 2008, 47, 4351.

4.Chem. Sci. 2011, 2, 1135.

5.Tetrahedron 2012, 68, 7685.