CAS 637-89-8; 4-羟基硫代苯酚; monothiohydroquinone

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货号

品牌

产品名称

规格

包装、参考价格

M812819

MACKLIN

4-羟基苯硫酚

97%

39元/1g; 112元/5g; 346元/25g; 1190元/100g; 3619元/500g;

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储存：室温
状态：白色到黄色固体,无色到黄色液体

H0662

TCI

4-Hydroxybenzenethiol

>97.0%(GC)(T)

490元/25G; 1950元/100G;

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基本信息

纯度/分析方法	>97.0%(GC)(T)
分子式/分子量	C₆H₆OS = 126.17
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,湿气 (吸湿)
Reaxys-RN	2039306
PubChem物质ID	87571035
SDBS (AIST Spectral DB)	22799
MDL编号	MFCD00004850

技术规格

Appearance	White to Light yellow powder to lump
Purity(GC)	min. 97.0 %
Purity(Iodometric Titration)	min. 97.0 %

物性(参考值)

熔点	34 ℃
水溶性	可溶

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

相关法规

RTECS#

MX7175000

282732

J&K

4-Hydroxythiophenol

98%

378元/5G; 1454元/25G;

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基本信息

分子式	C₆H₆OS
分子量	126.18
熔点	33-35
沸点	149-150
闪点	110
MDL编码	MFCD00004850
Beilstein	2039306
EINECS 编号	211-307-6

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
RTECS	MX7175000
TSCA	否

L04429

Alfa Aesar

4-Hydroxythiophenol

97%

632元/5g; 2278元/25g;

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应用
4-Hydroxythiophenol is used to improve charge separation in PbSe quantum dots (QDs) as sensitizers for TiO2. It helps in the activation of neocarzinostatin-chromophore. Also used as a resin monomer in the study of the different gold nanocrystal core-resin shell structures

备注
Air Sensitive. Store at 4?°C. Incompatible with air and oxidizing agents.

基本信息

MDL
MFCD00004850

EINECS
211-307-6

分子式
C₆H₆OS

分子量
126.18

熔点
33-37°

沸点
256°

闪点
110°(230°F)

密度
1.255

灵敏度
Air Sensitive. Store under Argon. Ambient temperatures.

形态
Solid

溶解性
Soluble in water.

Beilstein
2039306

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
8

包装组
II

危险类别
22-34
Harmful if swallowed.Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

RTECS
MX7175000

TSCA
否

C37063

Alfa Aesar

4-Mercaptophenol

99%

1108元/5g; 3552元/25g;

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基本信息

Ref#
37063

MDL
4850

分子式
C6 H6 O S

分子量
126.18

闪点
110

安全信息

危险等级
8

包装组
II

559938

Sigma-Aldrich

4-Mercaptophenol

97%

878.59元/5 G;

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产品说明

应用

4-巯基苯酚(MPH)已被用于通过时间依赖性表面增强拉曼散射(SERS)光谱法研究镀银聚苯乙烯纳米球上的MPH吸附。
4-巯基苯酚可用于制备甲硅烷基化单体，该产物可用于合成超支化聚(酯-酰亚胺)。4-巯基苯酚(H-4MP)与金属叔丁醇([M(OBu^t)₄])反应，得到以下第4类苯氧基-硫醇：

[(HOBu^t)(4MP)₃M(μ-4MP)]₂，其中M = Ti，Zr，Hf
[(py)₂M(4MP)], where M = Ti，Zr；py = 吡啶
[(py)(4MP)₃Hf(μ-4MP)]₂

4-巯基苯酚可用于合成以下物质：

通过甲硅烷基化反应，然后与2,6-二氯吡啶或3,6-二氯哒嗪发生缩聚反应，合成聚硫醚
在路易斯酸存在下，与叔丁基氯发生Friedel-Craft烷基化反应，得到2,6-二叔丁基-4-巯基苯酚

包装

5 g in glass bottle

基本信息

线性分子式	HSC₆H₄OH
分子量	126.18
Beilstein	2039306
EC 号	211-307-6
MDL编号	MFCD00004850
PubChem化学物质编号	24879829
NACRES	NA.22

产品性质

质量水平	100
测定	97%
bp	149-150 ℃/25 mmHg (lit.)
mp	33-35 ℃ (lit.)
SMILES string	Oc1ccc(S)cc1
InChI	1S/C6H6OS/c7-5-1-3-6(8)4-2-5/h1-4,7-8H
InChI key	BXAVKNRWVKUTLY-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	230.0 °F - closed cup
闪点(C)	110 ℃ - closed cup
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

275395

Sigma-Aldrich

4-Mercaptophenol

technical grade, 90%

602.96元/5 G; 2345.61元/25 G;

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产品说明

一般描述

The density function theory calculations were performed to infer the IR and Raman spectra for 4-mercaptophenol molecule.

应用

4-Mercaptophenol was used as a resin monomer in the study of the different gold nanocrystal core-resin shell structures.

包装

5, 25 g in glass bottle

基本信息

线性分子式	HSC₆H₄OH
分子量	126.18
Beilstein	2039306
EC 号	211-307-6
MDL编号	MFCD00004850
PubChem化学物质编号	24856646
NACRES	NA.22

产品性质

等级	technical grade
质量水平	100
测定	90%
bp	149-150 ℃/25 mmHg (lit.)
mp	33-35 ℃ (lit.)
SMILES string	Oc1ccc(S)cc1
InChI	1S/C6H6OS/c7-5-1-3-6(8)4-2-5/h1-4,7-8H
InChI key	BXAVKNRWVKUTLY-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	230.0 °F - closed cup
闪点(C)	110 ℃ - closed cup
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

353379

Fluorochem

4-Sulfanylphenol

90%

220元/1g; 462元/5g; 1056元/25g;

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基本信息

CAS Number	637-89-8
MDL Number	MFCD00004850
Melting Point	34℃

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .