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CAS: 6283-74-5
分子式: C8H8O7
分子量: 216.14
熔点: 130-135℃
中文名称: 
二-O-乙酰基-L-酒石酸酐
英文名称: 
(+)-Di-O-acetyl-L-tartaric anhydride
Di-O-acetyl-L-tartaric anhydride
(+)-diacetyl-l-tartaric anhydride
推荐供应商
货号品牌产品名称规格包装、参考价格
D831379MACKLIN二-O-乙酰基-L-酒石酸酐97%30元/1g;   59元/5g;   158元/25g;   568元/100g;   咨询
储存:2~8℃
状态:白色到灰白色固体
D1911TCI(+)-Diacetyl-L-tartaric Anhydride>97.0%(T)520元/25G;   咨询

基本信息

纯度/分析方法>97.0%(T)
分子式/分子量C8H8O7 = 216.15
外观与形状(20℃)固体
储存温度<0℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解),加热
Reaxys-RN87315
PubChem物质ID87568371
MDL编号MFCD00037918

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Methanolysis Method)min. 97.0 %
Melting point131.0 to 135.0 ℃
Specific rotation [a]20/D+91.0 to +97.0 deg(C=0.5, CHCl3)

物性(参考值)

熔点134 ℃
比旋光度 [α]D95° (C=0.5,CHCl3)
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
358924Sigma-Aldrich(+)-O,O′-Diacetyl-L-tartaric anhydride97%1825.03元/50 G;   咨询

产品说明

一般描述

(+)-O,O′-二乙酰基L-酒石酸酐是用于紫外/可见光检测的HPLC衍生化试剂。它主要用作氨基醇的手性衍生化试剂。它还可在含三氯乙酸的质子惰性介质中与链烷胺反应,生成酒石酸单酯。

应用

(+)-O,O′-二乙酰基-L-酒石酸酐可用作以下应用中的手性衍生化剂:

  • 通过超高效液相色谱-四极杆飞行时间质谱 (UHPLC-Q-TOF-M) 测定小鼠血清样品中的氨己烯酸对映体        
  • 通过高效液相色谱-电喷雾电离质谱(UPLC-MS / MS)测定大鼠血浆中的川丁特罗(trantinterol)

包装

50 g in glass bottle

基本信息

经验(实验)分子式C8H8O7
分子量216.14
Beilstein87315
EC 号228-502-7
MDL编号MFCD00037918
PubChem化学物质编号24862037
NACRESNA.22

产品性质

质量水平100
测定97%
旋光性[α]20/D +59°, c = 6 in acetone
mp130-135 ℃ (lit.)
储存温度2-8℃
SMILES stringCC(=O)O[C@@H]1[C@@H](OC(C)=O)C(=O)OC1=O
InChI1S/C8H8O7/c1-3(9)13-5-6(14-4(2)10)8(12)15-7(5)11/h5-6H,1-2H3/t5-,6-/m1/s1
InChI keyXAKITKDHDMPGPW-PHDIDXHHSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
322051Fluorochem(3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate95%990元/25g;   咨询

基本信息

CAS Number6283-74-5
MDL NumberMFCD00037918
Melting Point134℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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