CAS 626-55-1; 3-溴吡啶; 3-bromo-pyridine

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货号

品牌

产品名称

规格

包装、参考价格

B802438

MACKLIN

3-溴吡啶

98%

29元/5g; 45元/25g; 125元/100g; 598元/500g; 2555元/2.5kg;

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储存：室温,易燃物区域
状态：无色到浅黄色液体
折射率：n20/D 1.571(lit.)

B0651

TCI

3-Bromopyridine (stabilized with Copper chip)

>98.0%(GC)

430元/25G; 1325元/100G;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₅H₄BrN = 158.00
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	光,空气
Reaxys-RN	105880
PubChem物质ID	87563658
SDBS (AIST Spectral DB)	4139
MDL编号	MFCD00006373

技术规格

Appearance	Colorless to Light yellow to Light orange clear liquid
Purity(GC)	min. 98.0 %

物性(参考值)

熔点	-27 ℃
沸点	178 ℃
闪点	52 ℃
比重	1.62
折射率	1.57
水溶性	微溶
在水中的溶解度	31 g/l 25 ℃

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H226 : 易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。 P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号	UN1993
类别	3
包装类别	III
监管条件代码(*)

169848

J&K

3-Bromopyridine

98%

66元/5G; 132元/25G; 275元/100G;

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基本信息

分子式	C₅H₄BrN
分子量	158.00
沸点	173
闪点	52
密度	1.640
折光率(n20D)	1.5710
MDL编码	MFCD00006373
Beilstein	105880
EINECS 编号	210-952-0

安全信息

图形或危害标志
提示语	Warning
危险说明	H226 H302 H315 H319 H335
防范说明	P261 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	III
WGK	3
TSCA	是

A12894

Alfa Aesar

3-Bromopyridine

98+%

685元/25g; 1724元/100g; 9698元/500g;

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应用
3-Bromopyridine undergoes lithiation with LDA at low temperatures in the 4-position: Heterocycles, involved in formation of the Grignard by Mg exchange with i-PrMgCl and in transmetallation of the lithiated derivative with zinc chloride followed by treatment with an electrophile as a route to 4-substituted 3-bromopyridines.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong acids.

基本信息

MDL
MFCD00006373

EINECS
210-952-0

分子式
C₅H₄BrN

分子量
158.00

熔点
-27°

沸点
172-174°

闪点
72°(181°F)

密度
1.617

折射率
1.5700

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Soluble in water (31 g/L at 20°C).

Beilstein
105880

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H311-H332-H315-H319-H335
Combustible liquid.Harmful if swallowed.Toxic in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280h-P305+P351+P338-P309-P310a
Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:

安全信息

危险等级
6.1

包装组
II

危险类别
20/21/22-36/37/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA
是

C10741

Alfa Aesar

3-Bromopyridine

99%

956元/25ml; 2835元/100ml;

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基本信息

Ref#
10741

MDL
6373

分子式
C5 H4 Br N

分子量
158

闪点
51

密度
1.64

形态
Liquid

安全信息

危险等级
6.1

包装组
II

602088

Amethyst

3-Bromopyridine

98%, 用于合成

54元/5G; 82元/25G; 190元/100G; 736元/500G;

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基本信息

分子式	C₅H₄BrN
分子量	158.00
沸点	173
闪点	52
密度	1.640
折光率(n20D)	1.5710
MDL编码	MFCD00006373
Beilstein	105880
EINECS 编号	210-952-0

安全信息

图形或危害标志
提示语	Warning
危险说明	H226 H302 H315 H319 H335
防范说明	P261 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	III
WGK	3
TSCA	是

008797

Fluorochem

3-Bromopyridine

99%

220元/25g; 418元/100g; 1716元/500g;

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基本信息

CAS Number	626-55-1
MDL Number	MFCD00006373
Boiling Point	172-174
Melting Point	-27℃
Density	1.617

安全信息

图形或危害标志
危险性说明	H226: Flammable liquid and vapour. H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use CO2 for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.