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CAS: 6228-47-3
分子式: C21H22P
分子量: 305.37
熔点: 236-238℃
英文名称: 
propyltriphenylphosphonium bromide
推荐供应商
货号品牌产品名称规格包装、参考价格
T818529MACKLIN丙基三苯基溴化膦98%27元/5g;   36元/25g;   115元/100g;   565元/500g;   2610元/2.5kg;   咨询
储存:室温
状态:白色到灰白色粉末,晶体和/或块状
P1200TCITriphenylpropylphosphonium Bromide>98.0%(T)(HPLC)310元/25G;   2730元/500G;   咨询

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C21H22BrP = 385.28
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (吸湿)
Reaxys-RN3599726
PubChem物质ID87575299
SDBS (AIST Spectral DB)15647
MDL编号MFCD00011843

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Argentometric Titration)min. 98.0 %
Melting point237.0 to 241.0 ℃

物性(参考值)

熔点239 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 : 吞咽或皮肤接触有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
232030J&Kn-Propyltriphenylphosphonium bromide99%230元/25G;   507元/100G;   1826元/500g;   咨询

基本信息

分子式C21H22BrP
分子量385.27
熔点235-238
MDL编码MFCD00011843
EINECS 编号240-056-5

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
防范说明P280
WGK3
A12968Alfa Aesar(1-Propyl)triphenylphosphonium bromide99%1095元/50g;   3029元/250g;   10250元/1000g;   咨询

应用
It is employed as a catalyst for the carboxylation of styrene oxide and as a reactant involved in epoxidation of arylalkenes, boration of allylic epoxides, Wittig reactions, selective dimerization of α-olefins, and synthesis of indoles. It has also been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A.

备注
Hygroscopic. Store away from oxidizing agents, humidity and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

基本信息

MDL
MFCD00011843

EINECS
228-330-2

分子式
CH3(CH2)2P(C6H5)3Br

分子量
385.29

熔点
236-240°

灵敏度
Hygroscopic. Ambient temperatures.

形态
Powder

溶解性
Soluble in water.

Beilstein
3599726

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

131563Sigma-AldrichPropyltriphenylphosphonium Bromide98%536.89元/25 G;   咨询

产品说明

应用

用于氧化苯乙烯羧化的催化剂
反应物参与到:

  • 芳基烯烃的环氧化
  • 烯丙基环氧化物的硼化
  • Wittig反应
  • α-烯烃的选择性二聚化
  • 吲哚的合成

包装

25 g in poly bottle

基本信息

线性分子式CH3CH2CH2P(C6H5)3Br
分子量385.28
EC 号228-330-2
MDL编号MFCD00011843
PubChem化学物质编号24848023
NACRESNA.22

产品性质

测定98%
reaction suitabilityreaction type: C-C Bond Formation
mp235-238 ℃ (lit.)
SMILES string[Br-].CCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI1S/C21H22P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
InChI keyXMQSELBBYSAURN-UHFFFAOYSA-M

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 + H312
预防措施声明P280
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
222209FluorochemPropyltriphenylphosphonium Bromide95%220元/1g;   308元/25g;   814元/100g;   咨询

基本信息

CAS Number6228-47-3
MDL NumberMFCD00011843
Melting Point235 - 238 ℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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