CAS 6165-68-0; 2-噻吩硼酸; 2-THIOPHENEBORONIC ACID

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货号

品牌

产品名称

规格

包装、参考价格

T819151

MACKLIN

2-噻吩硼酸

98%

22元/1g; 44元/5g; 188元/25g; 748元/100g;

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储存：2~8°C
状态：白色到黄色到棕色粉末或晶体

T1772

TCI

2-Thiopheneboronic Acid (contains varying amounts of Anhydride)

210元/1G; 435元/5G; 1860元/25G;

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基本信息

分子式/分子量	C₄H₅BO₂S = 127.95
外观与形状(20℃)	固体
储存温度	0-10℃
应避免的情况	加热
Reaxys-RN	112375
PubChem物质ID	87577505
MDL编号	MFCD00151850

技术规格

Appearance	White to Orange to Green powder to crystal
Purity(Neutralization titration)	96.0 to 116.0 %

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

199801

J&K

Thiophene-2-boronic acid

98%

75元/1G; 222元/5G; 573元/25G;

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基本信息

分子式	C₄H₅BO₂S
分子量	127.96
熔点	138-140
MDL编码	MFCD00151850
Beilstein	112375
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

05-1040

Strem

2-Thiopheneboronic acid

min. 97%

1002元/5g; 4003元/25g;

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B23071

Alfa Aesar

Thiophene-2-boronic acid

97%

475元/1g; 1562元/5g; 6792元/25g;

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应用
Thiophene-2-boronic acid is a reagent used for Palladium-catalyzed Suzuki-Miyaura cross-couplings, Copper-catalyzed nitration reactions, Chain-growth catalyst transfer polycondensation of conjugated alternating copolymer, Ferric perchlorate-promoted reaction of fullerene to give fullerenyl boronic esters. It is also used in the preparation of Amino pyridine-based inhibitors of mitotic kinase Nek2 with potential antipoliferative effects in cancer tumors.

备注
Store in a cool, dry conditions, in well sealed conditions. Store away from oxidizing agents.

基本信息

MDL
MFCD00151850

EINECS
000-000-0

分子式
C₄H₅BO₂S

分子量
127.96

熔点
128-131°

灵敏度
Keep Cold.

形态
Powder

溶解性
Soluble in methanol.

Beilstein
112375

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

436836

Sigma-Aldrich

2-Thienylboronic Acid

≥95.0%

429.08元/1 G; 704.89元/5 G;

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产品说明

应用

用作以下反应的试剂

钯催化的Suzuki-Miyaura交叉偶联
烷基化、硼酸化、偶联反应、Suzuki偶联和芴基溴化物的卤化
耦合交替共聚物的链增长催化剂转移缩聚反应
生成富勒烯基硼酸酯的高氯酸铁催化富勒烯反应
无配体的Suzuki、Sonogashira和Heck交叉偶联反应
铜催化的硝化反应
几何松弛引起的在红色发光硼二甲基甲烷(BODIPY)中的大斯托克位移及其在荧光硫醇探针中的应用

用作以下制备反应的试剂

含氧多环芳基三联苯的光物理属性
通过N-烷基化、Suzuki偶联和溴化的供体-受体型聚合物的供体单元
基于氨基吡啶的有丝分裂激酶Nek2抑制剂，在癌症肿瘤中具有潜在的抗增殖作用

包装

1, 5 g in glass bottle

其他说明

含有不定量的酸酐

基本信息

经验(实验)分子式	C₄H₅BO₂S
分子量	127.96
Beilstein	112375
MDL编号	MFCD00151850
PubChem化学物质编号	24867305
NACRES	NA.22

产品性质

质量水平	200
测定	≥95.0%
mp	138-140 ℃ (lit.)
储存温度	2-8℃
SMILES string	OB(O)c1cccs1
InChI	1S/C4H5BO2S/c6-5(7)4-2-1-3-8-4/h1-3,6-7H
InChI key	ARYHTUPFQTUBBG-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302 - H315 - H319 - H335
预防措施声明	P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
危险分类	Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

992144

Amethyst

Thiophene-2-boronic acid

98%, 用于合成

60元/1G; 113元/5G; 310元/25G; 1024元/100G;

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基本信息

分子式	C₄H₅BO₂S
分子量	127.96
熔点	138-140
MDL编码	MFCD00151850
Beilstein	112375
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

011009

Fluorochem

Thiophene-2-boronic acid

98%

220元/5g; 220元/1g; 638元/25g; 1848元/100g;

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基本信息

CAS Number	6165-68-0
MDL Number	MFCD00151850
Boiling Point	287.9℃
Melting Point	138-140℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .