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CAS: 613-54-7
分子式: C12H9BrO
分子量: 249.10
熔点: 82-84 °C(lit.)
中文名称: 
溴甲基-2-萘酮
2-(溴乙酰基)萘
2-溴乙酰基萘
英文名称: 
2-Bromo-2'-acetonaphthone
Bromomethyl 2-naphthyl ketone
2-(Bromoacetyl)naphthalene
à-Bromo-2-acetonaphthone
2-Bromoacetylnaphthalene
alpha-bromo-2'-acetonaphthone
推荐供应商
货号品牌产品名称规格包装、参考价格
B801832MACKLIN2-萘基溴甲基酮98%36元/1g;   109元/5g;   427元/25g;   1656元/100g;   咨询
储存:2~8°C
状态:白色到黄色或紫色到暗棕色粉末
B1259TCI2-Bromoacetylnaphthalene>98.0%(GC)330元/5G;   950元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C12H9BrO = 249.11
外观与形状(20℃)固体
应避免的情况
Reaxys-RN639153
PubChem物质ID87564193
SDBS (AIST Spectral DB)21083
MDL编号MFCD00004109

技术规格

AppearanceLight yellow to Brown powder to crystal
Purity(GC)min. 98.0 %
Melting point82.0 to 85.0 ℃

物性(参考值)

熔点84 ℃
水溶性不溶

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3261
类别8
包装类别 II
监管条件代码(*)
365600J&K2-Bromo-2'-acetonaphthone95%208元/5G;   679元/25G;   咨询

基本信息

分子式C12H9BrO
分子量249.10
熔点82-84
MDL编码MFCD00004109
Beilstein639153
EINECS 编号210-348-7

安全信息

图形或危害标志
提示语Danger
危险说明H314
H335
防范说明P261
P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
TSCA
B23960Alfa Aesar2-(Bromoacetyl)naphthalene98%1026元/10g;   3065元/50g;   7202元/250g;   咨询

基本信息

MDL
MFCD00004109

EINECS
210-348-7

分子式
C12H9BrO

分子量
249.11

熔点
80-85°

形态
Crystalline solid

Beilstein
639153

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

C14748Alfa Aesaralpha-Bromo-2'-acetonaphthone98%1928元/10g;   8972元/50g;   咨询

基本信息

Ref#
14748

MDL
4109

分子式
C12 H9 Br O

分子量
249.11

安全信息

危险等级
8

包装组
II

105120Sigma-Aldrich2-Bromo-2′-acetonaphthone99%514.99元/5 G;   咨询

产品说明

一般描述

2-Bromo-2′-acetonaphthone is used for derivatization of captopril to develop a fast and sensitive high-performance liquid chromatographic method for the determination of captopril in plasma.2-Bromo-2′-acetonaphthone converts tetra-acids extracted from calcium naphthenate deposits to 2-naphthacyl derivatives.

应用

2-Bromo-2′-acetonaphthone was used to determine the concentration of tetra-acids in calcium naphthenate deposits. 2-Bromo-2′-acetonaphthone was used as derivation reagent for determination of fatty acids extracted from Botryococcus braunii by HPLC.

包装

5 g in glass bottle

基本信息

线性分子式C10H7COCH2Br
分子量249.10
EC 号210-348-7
MDL编号MFCD00004109
PubChem化学物质编号24846689
NACRESNA.22

产品性质

质量水平100
测定99%
mp82-84 ℃ (lit.)
溶解性acetonitrile: soluble
SMILES stringBrCC(=O)c1ccc2ccccc2c1
InChI1S/C12H9BrO/c13-8-12(14)11-6-5-9-3-1-2-4-10(9)7-11/h1-7H,8H2
InChI keyYHXHHGDUANVQHE-UHFFFAOYSA-N
Gene Informationhuman ... PTPN6(5777)

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H314 - H335
预防措施声明P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
358274Fluorochem2-bromo-1-(naphthalen-2-yl)ethan-1-one95+%396元/5g;   1100元/25g;   咨询

基本信息

CAS Number613-54-7
MDL NumberMFCD00004109
Melting Point82-84℃
Density1.4188

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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