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CAS: 613-50-3
分子式: C9H6N2O2
分子量: 174.16
熔点: 149-153℃
中文名称: 
6-硝基喹啉
英文名称: 
6-nitro-quinolin
6-nitroquinoline
6-Nitro-quinoline
Quinoline,6-nitro-
6-Nitrochinolin
性质描述: 浅黄色针状结晶。熔点153-154℃(150℃)。能升华。溶于热水及热乙醇,易溶于苯和稀无机酸,微溶于冷水。
生产方法: 以对硝基苯胺为原料,与丙烯醛缩合后再经环合而得,或与甘油环合制得。1.丙烯醛法将丙烯醛和对硝基苯胺加入反应锅,升温至75-80℃,保温1h,加入碘、碘化钾和硫酸。继续缓缓升温至110℃,保温20min,然后升温至120℃,保温半小时,再升温至136℃以上。反应结束后,加入大量水稀释。用活性炭脱色后,中和至pH=3-4。过滤,用水洗至pH为7,低温干燥,即得6-硝基喹啉。2.甘油法将对硝基苯胺、甘油、砷酸加入反应锅中加热,至70℃时开始滴加硫酸。加毕,在132-136℃下反应1h。加水稀释,用活性炭脱色后,以20%氢氧化钠溶液中和至pH2.5-3。甩滤,依次用水和饱和硫化钠溶液洗涤,干燥即得成品。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
N815075MACKLIN6-硝基喹啉98%27元/5g;   131元/25g;   514元/100g;   咨询
储存:室温
状态:浅黄色到棕色粉末或晶体或固体
N0252TCI6-Nitroquinoline>98.0%(GC)(T)290元/5G;   1330元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C9H6N2O2 = 174.16
外观与形状(20℃)固体
Reaxys-RN136138
PubChem物质ID87573613
SDBS (AIST Spectral DB)6278
MDL编号MFCD00006799

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point150.0 to 154.0 ℃

物性(参考值)

熔点151 ℃
水溶性微溶
溶解性(可溶于)乙醇,乙醚,苯,氯仿

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。

相关法规

RTECS#VC1900000
402657J&K6-Nitroquinoline98%190元/10G;   756元/50G;   咨询

基本信息

分子式C9H6N2O2
分子量174.16
熔点151-153
MDL编码MFCD00006799
Beilstein136138
EINECS 编号210-346-6

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
H332
H351
防范说明P280
WGK3
RTECSVC1900000
TSCA
N24005Sigma-Aldrich6-Nitroquinoline98%889.34元/25 G;   咨询

基本信息

经验(实验)分子式C9H6N2O2
分子量174.16
EC 号210-346-6
MDL编号MFCD00006799
PubChem化学物质编号24897572
NACRESNA.22

产品性质

质量水平100
测定98%
形式powder
mp151-153 ℃ (lit.)
SMILES string[O-][N+](=O)c1ccc2ncccc2c1
InChI1S/C9H6N2O2/c12-11(13)8-3-4-9-7(6-8)2-1-5-10-9/h1-6H
InChI keySMHPLBXIVNQFBA-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 + H312 + H332 - H351
预防措施声明P201 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P308 + P313
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
047735Fluorochem6-Nitroquinoline98%220元/5g;   220元/1g;   374元/10g;   792元/25g;   2332元/100g;   咨询

基本信息

CAS Number613-50-3
MDL NumberMFCD00006799

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H351: Suspected of causing cancer ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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