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CAS: 609-09-6
分子式: C7H10O5
分子量: 174.15
沸点: 208-210℃
中文名称: 
二乙基双乙烯酯
酮基丙二酸二乙酯
英文名称: 
Diethyl mesoxalate
Diethyl oxomalonate
Ketomalonic Acid Diethyl Ester
Mesoxalic Acid Diethyl Ester
oxo-propanedioic aci diethyl ester
diethyl ketomalonate
性质描述: 黄色液体。沸点208-210℃,相对密度1.142,折光率1.4150。不溶于水,溶于醇、醚。
生产方法: 将三氧化二氮气体通入冷却的丙二酸二乙酯中,反应物转为绿色,通气完毕,使反应液渐渐升温,至室温后保持2d以上。减压蒸馏,收集103-108℃(2.0kPa)馏分,得酮基丙二酸二乙酯。收率74%-76%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
D831237MACKLIN酮基丙二酸二乙酯97%39元/5g;   113元/25g;   375元/100g;   1800元/500g;   咨询
储存:室温,密封
状态:黄色到黄绿色液体
M0866TCIDiethyl Mesoxalate>94.0%(GC)520元/5G;   1540元/25G;   咨询

基本信息

纯度/分析方法>94.0%(GC)
分子式/分子量C7H10O5 = 174.15
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN971873
PubChem物质ID87572859
SDBS (AIST Spectral DB)18309
Merck Index (14)5913
MDL编号MFCD00009121

技术规格

AppearanceWhite to Yellow to Green clear liquid
Purity(GC)min. 94.0 %

物性(参考值)

沸点210 ℃
比重1.14
折射率1.42
A12771Alfa AesarDiethyl Ketomalonate95%801元/5g;   3394元/25g;   11034元/100g;   咨询

应用
Diethyl ketomalonate, reagent employed in Wittig and Aza-Wittig reactions for synthesis of triazoles, and 2-azadienes, respectively.

备注
Moisture Sensitive. Store in cool dry place in tightly closed container. With good ventilation. Store away from oxidizing agent and water/moisture.

基本信息

MDL
MFCD00009121

EINECS
210-176-2

分子式
C7H10O5

分子量
174.15

熔点
ca -70°

沸点
208-210°

闪点
>110°(230°F)

密度
1.142

折射率
1.4150

灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Fully miscible with water.

Beilstein
971873

Merck
14,5913

安全信息

TSCA

C11443Alfa AesarDiethyl Ketomalonate95%1017元/5g;   3390元/25g;   咨询

基本信息

Ref#
11443

MDL
9121

分子式
C7 H10 O5

分子量
174.15

闪点
>112

密度
1142

形态
Yellow liquid

D97401Sigma-AldrichDiethyl Ketomalonate95%605.8元/5 G;   1777.56元/25 G;   咨询

产品说明

应用

用于经 Wittig 和 Aza-Wittig 反应分别合成三唑类和 2-氮杂二烯的试剂。

包装

5, 25 g in glass bottle

基本信息

线性分子式CO(CO2C2H5)2
分子量174.15
Beilstein971873
EC 号210-176-2
MDL编号MFCD00009121
PubChem化学物质编号24894323
NACRESNA.22

产品性质

质量水平100
测定95%
折射率n20/D 1.415 (lit.)
bp208-210 ℃ (lit.)
密度1.142 g/mL at 25 ℃ (lit.)
SMILES stringCCOC(=O)C(=O)C(=O)OCC
InChI1S/C7H10O5/c1-3-11-6(9)5(8)7(10)12-4-2/h3-4H2,1-2H3
InChI keyDBKKFIIYQGGHJO-UHFFFAOYSA-N

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
005421FluorochemDiethyl Ketomalonate94%352元/5g;   726元/25g;   2024元/100g;   咨询

基本信息

CAS Number609-09-6
MDL NumberMFCD00009121
Boiling Point208-210℃
Density1.142

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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