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CAS: 603-32-7
分子式: C18H15As
分子量: 306.23
沸点: 360℃
熔点: 57-62℃
中文名称: 
三苯基胂
英文名称: 
triphenyl-arsine
Triphenyl-arsane
Arsine,triphenyl-
Triphenylarsen
triphenyl-arsin
triphenylarsane
triphenylarsine
推荐供应商
货号品牌产品名称规格包装、参考价格
T823396MACKLIN三苯基胂98%46元/250mg;   158元/1g;   710元/5g;   3350元/25g;   咨询
储存:2~8℃
状态:白色-略淡红黄色晶体-粉末
T0508TCITriphenylarsine>98.0%(GC)(T)550元/5G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C18H15As = 306.24
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN1842037
PubChem物质ID87576437
SDBS (AIST Spectral DB)10942
MDL编号MFCD00002994

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(GC)min. 98.0 %
Purity(Iodometric Titration)min. 98.0 %
Melting point60.0 to 62.0 ℃
Solubility in Methanolwithin almost transparency

物性(参考值)

熔点61 ℃
沸点175 ℃/1.5 mmHg
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H331 : 吞咽或吸入可致中毒。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P391 : 收集溢出物。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#CH8942500

运输信息

UN编号UN3465
类别6.1
包装类别 III
监管条件代码(*)
33-4000StremTriphenylarsinemin. 97%849元/5g;   3336元/25g;   咨询
L03616Alfa AesarTriphenylarsine97%857元/5g;   2844元/25g;   咨询

应用
Triphenylarsine is used in certain metal-catalyzed coupling reactions. It is a precursor to tetraphenylarsonium chloride a popular precipitating agent.

备注
Handle and store under inert gas. Incompatible materials are Strong oxidizing agents.

基本信息

MDL
MFCD00002994

EINECS
210-032-9

分子式
C18H15As

分子量
306.24

熔点
58-62°

沸点
360°

闪点
265°(509°F)

灵敏度
Ambient temperatures.

形态
Lump/powder

溶解性
Soluble in methanol. Insoluble in water.

Beilstein
1842037

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H331-H400-H410
Toxic if swallowed.Toxic if inhaled.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P301+P310a-P304+P340-P311a-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Avoid breathing dust/fume/gas/mist/vapours/spray.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
23/25-50/53
Toxic by inhalation and if swallowed.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
20/21-28-45-60-61
When using do not eat, drink or smoke.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
CH7942500

TSCA

T81906Sigma-AldrichTriphenylarsine97%531.15元/5 G;   1093.47元/25 G;   6024.2元/100 G;   咨询

基本信息

线性分子式(C6H5)3As
分子量306.23
EC 号210-032-9
MDL编号MFCD00002994
PubChem化学物质编号24900510
NACRESNA.23

产品性质

质量水平100
测定97%
形式solid
reaction suitabilityreagent type: catalyst
mp58-61 ℃ (lit.)
SMILES stringc1ccc(cc1)[As](c2ccccc2)c3ccccc3
InChI1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI keyBPLUKJNHPBNVQL-UHFFFAOYSA-N

安全信息

象形图GHS06GHS09
警示用语:Danger
危险声明H301 + H331 - H410
预防措施声明P273 - P301 + P310 + P330 - P304 + P340 + P311
危险分类Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
8.08653Sigma-AldrichTriphenylarsinefor synthesis1563.58元/25 G;   咨询

产品说明

分析说明

Assay (HPLC, area%): ≥ 98.0 % (a/a)
Melting range (lower value): ≥ 57 °C
Melting range (upper value): ≤ 61 °C
Identity (IR): passes test

基本信息

线性分子式(C6H5)3As
分子量306.23
MDL编号MFCD00002994
EC索引号210-032-9

产品性质

质量水平200
测定≥98.0% (HPLC)
bp>360 ℃/1013 hPa (decomposition)
mp59-61 ℃
转变温度flash point 265 ℃
密度1.22 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI keyBPLUKJNHPBNVQL-UHFFFAOYSA-N

安全信息

象形图GHS06GHS09
警示用语:Danger
危险声明H301 + H331 - H410
预防措施声明P261 - P264 - P270 - P273 - P301 + P310 - P304 + P340 + P311
危险分类Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9
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