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CAS: 603-11-2
分子式: C8H5NO6
分子量: 211.13
熔点: 213-216℃
中文名称: 
3-硝基-1,2-苯二羧酸
3-硝基酞酸
间硝基苯二甲酸
3-硝基邻苯二甲酸
英文名称: 
3-Nitro-1,2-benzenedicarboxylic acid
3-nitro-2-benzenedicarboxylic acid
3-nitrophthalic acid
3-nitrophthalic
3-nitrophthalicacid
性质描述: 淡黄色结晶。熔点213-216℃(分解)。溶于热水、甲醇、乙醇,微溶于醚,不溶于氯仿、四氯化碳、二硫化碳、苯。
生产方法: 将苯酐加入浓硫酸中,搅拌下通入水蒸气加热至80℃,滴加发烟硝酸,反应温度维持100-110℃,加毕,在110℃以上加热2h,放置过夜后倾入水中,过滤。滤饼用水重结晶,得3-硝基邻苯二甲酸。收率约30%。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
N814665MACKLIN3-硝基邻苯二甲酸99%35元/25g;   62元/100g;   192元/500g;   642元/2.5kg;   咨询
储存:室温,阴凉
状态:白色粉末或晶体
N814664MACKLIN3-硝基邻苯二甲酸96%49元/100g;   154元/500g;   511元/2.5kg;   咨询
储存:室温,阴凉
状态:白色到灰白色粉末或晶体
N0243TCI3-Nitrophthalic Acid>98.0%(T)(HPLC)120元/25G;   290元/500G;   咨询

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C8H5NO6 = 211.13
外观与形状(20℃)固体
Reaxys-RN2054269
PubChem物质ID87573604
SDBS (AIST Spectral DB)1399
MDL编号MFCD00007138

技术规格

AppearanceWhite to Almost white powder to crystaline
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %
Solubility in Methanolalmost transparency

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
390196J&K3-Nitrophthalic Acid98%81元/25G;   125元/100G;   466元/500G;   咨询

基本信息

分子式C8H5NO6
分子量211.13
熔点210
MDL编码MFCD00007138
Beilstein2054269
EINECS 编号210-030-8

安全信息

图形或危害标志
提示语Danger
危险说明H315
H318
H335
防范说明P261
P280
P305+P351+P338
WGK3
TSCA
A14281Alfa Aesar3-Nitrophthalic Acid95%775元/100g;   1559元/250g;   2632元/500g;   11178元/2500g;   咨询

应用
3-Nitrophthalic acid can be used as starting reagent in the synthesis of modified 2-iodoxybenzoic acid derivatives. It may be used in the synthesis of brucinium 2-carboxy-6-nitrophthalate dihydrate (systematic name: 2,3-dimethoxy-10-oxostrychnidinium 2-carboxy-6-nitrophthalate dihydrate), via heating with brucine. Clyatt E

备注
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

基本信息

MDL
MFCD00007138

EINECS
210-030-8

分子式
C8H5NO6

分子量
211.13

熔点
ca 214° dec.

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Solubility in methanol is almost transparent. Soluble in 5% water.

Beilstein
2054269

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C16016Alfa Aesar3-Nitrophthalic Acid95%766元/100g;   3179元/500g;   13093元/2.5kg;   咨询

基本信息

Ref#
16016

MDL
7138

分子式
C8 H5 N O6

分子量
211.13

137820Sigma-Aldrich3-Nitrophthalic Acid99%1163.52元/100 G;   咨询

产品说明

一般描述

3-硝基邻苯二甲酸是异恶草胺的降解产物 。它作为配体与稀土形成络合物 。

应用

以 3-硝基邻苯二甲酸为起始试剂,合成了改性 2-碘苯甲酸衍生物 。

包装

100 g in poly bottle

基本信息

线性分子式O2NC6H3-1,2-(CO2H)2
分子量211.13
Beilstein2054269
EC 号210-030-8
MDL编号MFCD00007138
PubChem化学物质编号24848350
NACRESNA.22

产品性质

质量水平100
测定99%
形式powder
mp210 ℃ (dec.) (lit.)
溶解性water: soluble 5%, clear to slightly hazy, colorless to faint yellow or tan
SMILES stringOC(=O)c1cccc(c1C(O)=O)[N+]([O-])=O
InChI1S/C8H5NO6/c10-7(11)4-2-1-3-5(9(14)15)6(4)8(12)13/h1-3H,(H,10,11)(H,12,13)
InChI keyKFIRODWJCYBBHY-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H315 - H318 - H335
预防措施声明P261 - P280 - P305 + P351 + P338
危险分类Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
369306Sigma-Aldrich3-Nitrophthalic Acid95%516.64元/100 G;   咨询

产品说明

一般描述

3-硝基邻苯二甲酸是一种异恶唑除草剂的降解产物。它作为配体可与La、Nd、Eu、Tb、Er和Y形成稀土络合物。3-硝基邻苯二甲酸的制备已被报道。

应用

3-硝基邻苯二甲酸可被用作合成改性的2-碘代苯甲酸衍生物的起始试剂。它可通过与亮氨酸加热合成2-羧基-6-硝基邻苯二甲酸溴化物二水合物(系统名称:2,3-二甲氧基-10-氧代噻吩-2-羰基-6-硝基邻苯二甲酸酯二水合物)。

包装

100 g in poly bottle

基本信息

线性分子式O2NC6H3-1,2-(CO2H)2
分子量211.13
Beilstein2054269
EC 号210-030-8
MDL编号MFCD00007138
PubChem化学物质编号24862954
NACRESNA.22

产品性质

质量水平200
测定95%
mp210 ℃ (dec.) (lit.)
溶解性water: soluble 5%, clear to slightly hazy, colorless to faintly yellow
SMILES stringOC(=O)c1cccc(c1C(O)=O)[N+]([O-])=O
InChI1S/C8H5NO6/c10-7(11)4-2-1-3-5(9(14)15)6(4)8(12)13/h1-3H,(H,10,11)(H,12,13)
InChI keyKFIRODWJCYBBHY-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H315 - H318 - H335
预防措施声明P261 - P280 - P305 + P351 + P338
危险分类Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
210761Fluorochem3-Nitrophthalic Acid95%308元/100g;   咨询

基本信息

CAS Number603-11-2
MDL NumberMFCD00007138

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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