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CAS: 596-43-0
分子式: C19H15Br
分子量: 323.23
沸点: 230℃(15
熔点: 151-155℃
中文名称: 
溴三苯基甲烷
英文名称: 
Benzene,1,1',1''-(bromomethylidyne)tris-
bromotriphenyl-methan
alpha-bromotriphenylmethane
1,1',1''-(bromomethylidyne)tris-benzen
bromotriphenylmethane
triphenylmethyl bromide
trityl bromide
Triphenylbromomethane
Triphenylmethylbromide
用途: 用于制备三苯甲基酯
推荐供应商
货号品牌产品名称规格包装、参考价格
B823254MACKLIN溴三苯基甲烷98%30元/1g;   54元/5g;   180元/25g;   702元/100g;   2888元/500g;   咨询
储存:2~8°C
状态:白色到黄色粉末
T0512TCITrityl Bromide>98.0%(T)590元/25G;   1785元/100G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C19H15Br = 323.23
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN1878494
PubChem物质ID87576440
SDBS (AIST Spectral DB)7455
MDL编号MFCD00000120

技术规格

AppearanceWhite to Yellow to Orange powder to crystal
Purity(Argentometric Titration)min. 98.0 %
Melting point153.0 to 157.0 ℃
Solubility in hot Acetic acidalmost transparency

物性(参考值)

熔点156 ℃

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

相关法规

RTECS#PA5550000

运输信息

UN编号UN3261
类别8
包装类别 III
监管条件代码(*)
208367J&KBromotriphenylmethane98%140元/5G;   533元/25G;   1416元/100G;   咨询

基本信息

分子式C19H15Br
分子量323.23
熔点152-154
沸点230
MDL编码MFCD00000120
Beilstein1878494
EINECS 编号209-884-4
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
RTECSPA5550000
TSCA
A12864Alfa AesarBromotriphenylmethane98%581元/10g;   2120元/50g;   14165元/500g;   咨询

应用
It is considered as a more reactive reagent than Chlorotriphenyl?-methane, for the preparation of trityl esters. It is also used in one-pot conversion of amino acids to their N-trityl derivatives involving N,O-ditritylation and selective methanolysis of the trityl ester.

备注
Moisture sensitive. Store away from oxidizing agents and bases. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

基本信息

MDL
MFCD00000120

EINECS
209-884-4

分子式
BrC(C6H5)3

分子量
323.24

熔点
152-156°

沸点
230°/15mm

密度
1.55

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Solubility in hot acetic acid is almost transparent.

Beilstein
1878494

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
PA5550000

TSCA

T83607Sigma-AldrichBromotriphenylmethane98%655.87元/25 G;   2492.31元/100 G;   咨询

产品说明

包装

25, 100 g in glass bottle

应用

用于制备三苯甲基酯的试剂。

基本信息

线性分子式(C6H5)3CBr
分子量323.23
Beilstein1878494
EC 号209-884-4
MDL编号MFCD00000120
PubChem化学物质编号24900521
NACRESNA.22

产品性质

质量水平100
测定98%
bp230 ℃/15 mmHg (lit.)
mp152-154 ℃ (lit.)
储存温度2-8℃
SMILES stringBrC(c1ccccc1)(c2ccccc2)c3ccccc3
InChI1S/C19H15Br/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI keyNZHXEWZGTQSYJM-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P280 - P305 + P351 + P338 - P310
危险分类Skin Corr. 1B
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
358304Fluorochem(bromodiphenylmethyl)benzene95%1650元/25g;   4158元/100g;   咨询

基本信息

CAS Number596-43-0
MDL NumberMFCD00000120
Melting Point156℃

安全信息

图形或危害标志
危险性说明 H290: May be corrosive to metals.
H314: Causes severe skin burns and eye damage.
防范说明 P234: Keep only in original container.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P390: Absorb spillage to prevent material damage.
P405: Store locked up.
P406: Store in corrosive resistant/ container with a resistant inner liner.
P501: Dispose of contents/container to local regulations.
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