基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	危险
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H341 : 怀疑可造成遗传性缺陷。 H225 : 高度易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P202 : 在阅读并明了所有安全措施前切勿搬动。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P201 : 使用前取得专用说明。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P308 + P313 : 如接触到或有疑虑：求医/就诊。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P403 + P235 : 存放在通风良好的地方。保持低温。 P405 : 存放处须加锁。

运输信息

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H225 H315 H319 H335
防范说明	P210 P261 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	II
WGK	3
TSCA	否

应用
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents, bases and heat.

基本信息

MDL
MFCD00001307

EINECS
227-632-1

分子式
C₄H₇Cl

分子量
90.55

熔点
-91°

沸点
87-89°

闪点
-1°(30°F)

密度
0.980

折射率
1.4360

灵敏度
Keep Cold.

形态
Liquid

溶解性
Not miscible in water.

Beilstein
635697

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H302-H315-H319-H335
Highly flammable liquid and vapour.Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P280h-P243-P305+P351+P338
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/clothing.Take precautionary measures against static discharge.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险等级
3

包装组
II

危险类别
11-22-36/37/38
Highly flammable.Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
16-23-26-33-36/37
Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA
否

产品说明

一般描述

(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

应用

(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.

包装

10, 50 g in ampule

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H225 - H315 - H319 - H335
预防措施声明	P210 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	28.4 °F - closed cup
闪点(C)	-2 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

基本信息

安全信息

图形或危害标志
危险性说明	H225: Highly flammable liquid and vapour. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P235: Keep cool. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use CO2, powder or sand for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.