[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 59-88-1
关键词:       仅模糊查询
CAS: 59-88-1
分子式: C6H9ClN2
分子量: 144.6035
熔点: 250-254℃
中文名称: 
苯肼盐酸盐
苯肼单盐酸盐
盐酸苯肼
苯肼,盐酸盐
英文名称: 
Hydrazine,phenyl-,monohydrochloride
phenylhydrazine,hydrochloride
phenylhydrazinehydrochloride1
Phenylhydrazine hydrochloride
Hydrazine, phenyl-, monohydrochloride
phenyl-hydrazin hydrochloride
phenyl-hydrazin monohydrochloride
phenylhydrazin hydrochlorid
phenylhydrazine monohydrochloride
phenylhydrazinium chloride
用途: 用作医药、农药中间体及染料中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
P0184TCIPhenylhydrazine Hydrochloride>98.5%(T)210元/25G;   535元/100G;   咨询

基本信息

纯度/分析方法>98.5%(T)
分子式/分子量C6H8N2・HCl = 144.60
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN3594958
PubChem物质ID87574433
Merck Index (14)7293
MDL编号MFCD00012924

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(HPLC)min. 98.0 area%
Purity( Potassium iodate Method)min. 98.5 %

物性(参考值)

熔点254 ℃(dec.)
水溶性完全溶解
溶解性(可溶于)
溶解性(不溶于)乙醚

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H317 : 可能造成皮肤过敏反应。
H341 : 怀疑可造成遗传性缺陷。
H350 : 可能致癌。
H400 : 对水生生物毒性极大。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P273 : 避免释放到环境中。
P272 : 受沾染的工作服不得带出工作场地。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P391 : 收集溢出物。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#MV9000000

运输信息

UN编号UN2811
类别6.1
包装类别 III
监管条件代码(*)
A14645Alfa AesarPhenylhydrazine Hydrochloride99%1742元/100g;   3644元/500g;   咨询

应用
Phenylhydrazine hydrochloride is used as a selective mannosidase inhibitor. It is used in the study of tyrosine phosphorylation of janus protein tyrosine kinase in the EPO-responsive normal erythroblastoid cells of anemic mice. It is used in steroid assays and as an N-protecting reagent. Its free base, phenylhydrazine is used to prepare indoles, which find application as intermediates in the synthesis of various dyes and pharmaceuticals.

备注
Air and light sensitive. Hygroscopic. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and bases.

基本信息

MDL
MFCD00012924

EINECS
200-444-7

分子式
C6H8N2?HCl

分子量
144.61

熔点
ca 252° dec.

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water and alcohol.

Beilstein
3594958

Merck
14,7293

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H311-H331-H315-H319-H317-H341-H350-H372-H400
Toxic if swallowed.Toxic in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction.Suspected of causing genetic defects.May cause cancer.Causes damage to organs through prolonged or repeated exposure.Very toxic to aquatic life.

Precautionary Statements
P260-P201-P301+P310a-P305+P351+P338-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray.Obtain special instructions before use.Obtain special instructions before use.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
45-23/24/25-36/38-43-48/23/24/25-68-50
May cause cancer.Toxic by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.May cause sensitization by skin contact.Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.Possible risk of irreversible effects.Very toxic to aquatic organisms.

安全等级
53-45-61
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
MV9000000

TSCA

C15155Alfa AesarPhenylhydrazine Hydrochloride99+%1084元/100g;   7681元/500g;   咨询

基本信息

Ref#
15155

MDL
12924

分子式
C6 H8 N2 . H Cl

分子量
144.61

形态
White to cream crystalline powder

安全信息

危险等级
6.1

包装组
II

1.07253SupelcoPhenylhydrazinium Chloridefor analysis1128.45元/100 G;   2579.33元/250 G;   咨询

产品说明

分析说明

Assay (argentometric): ≥ 99.0 %
Identity (IR): passes test
Solubility in ethanol: passes test
Solubility in water: passes test
Sulfate (SO₄): ≤ 0.01 %
Iron (Fe): ≤ 0.001 %
Sulfated ash: ≤ 0.1 %
Loss on drying (105 °C): ≤ 0.5 %

基本信息

经验(实验)分子式C6H9ClN2
分子量144.60
MDL编号MFCD00012924
EC索引号200-444-7

产品性质

质量水平200
agencyreag. Ph. Eur.
测定≥99.0% (silver nitrate titration)
形式solid
pH值(酸碱度)2.6-2.9 (50 g/L in H2O)
mp245 ℃ (decomposition)
溶解性 50 g/L
堆积密度330 kg/m3
痕量阴离子sulfate (SO42-): ≤0.01%
痕量阳离子Fe: ≤ 0.001%
储存温度2-30℃
InChI1S/C6H8N2.ClH/c7-8-6-4-2-1-3-5-6;/h1-5,8H,7H2;1H
InChI keyJOVOSQBPPZZESK-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08GHS09
警示用语:Danger
危险声明H301 + H311 + H331 - H315 - H317 - H319 - H341 - H350 - H372 - H400
预防措施声明P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1
储存分类代码6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
114715Sigma-AldrichPhenylhydrazine Hydrochloride≥99%331.62元/5 G;   1033.24元/100 G;   4444.15元/500 G;   咨询

产品说明

应用

盐酸苯肼用于检测贫血小鼠 EPO 反应性正常成红细胞样细胞中 Janus 蛋白酪氨酸激酶 (JAK) 的酪氨酸磷酸化 。

包装

5, 100, 500 g in poly bottle

生化/生理作用

将盐酸苯肼腹腔注射到野生型和 Hp、Hx 单缺失小鼠体内时,会引起急性溶血 ,从而会抑制动物组织切片中辣根过氧化物 (HRP) 残留活性 。

制备说明

50 g 盐酸苯肼溶于 1 mL 水中,得到澄清、淡黄色溶液。

基本信息

线性分子式C6H5NHNH2 · HCl
分子量144.60
Beilstein3594958
EC 号200-444-7
MDL编号MFCD00012924
PubChem化学物质编号24847191
NACRESNA.22

产品性质

质量水平200
测定≥99%
mp250-254 ℃ (dec.) (lit.)
溶解性H2O: soluble 50 mg/mL
SMILES stringCl[H].NNc1ccccc1
InChI1S/C6H8N2.ClH/c7-8-6-4-2-1-3-5-6;/h1-5,8H,7H2;1H
InChI keyJOVOSQBPPZZESK-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08GHS09
警示用语:Danger
危险声明H301 + H311 + H331 - H315 - H317 - H319 - H341 - H350 - H372 - H400
预防措施声明P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
079470FluorochemPhenylhydrazine Hydrochloride98%220元/25g;   660元/100g;   咨询

基本信息

CAS Number59-88-1
MDL NumberMFCD00012924
Boiling Point243 ℃ at 760 mmHg
Melting Point230-250℃

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H331: Toxic if inhaled.
H341: Suspected of causing genetic defects ..
H350: May cause cancer ..
H372: Causes damage to organs ..
H400: Very toxic to aquatic life.
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P361: Remove/Take off immediately all contaminated clothing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9
Baidu
map