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CAS: 5872-08-2
分子式: C10H16O4S
分子量: 232.29
熔点: 195-203℃
中文名称: 
(+/-)-樟脑-10-磺酸
樟脑-10-磺酸
英文名称: 
7-dimethyl-2-oxo- (+/-)-bicyclo[2.2.1]heptane-1-methanesulfonic aci
dl-10-camphorsulfonic acid
DL-Camphor sulfonic acid
(±)-Camphor-10-sulfonic acid
(±)-β-Camphorsulfonic acid
Camphor-10-sulfonic acid(β)
(n)-Camphor-10-sulfonic acid
(+/-)-CSA
(+/-)-10-Camphorsulfonic Acid
推荐供应商
货号品牌产品名称规格包装、参考价格
C805252MACKLIN(±)-樟脑-10-磺酸99%36元/25g;   79元/100g;   268元/500g;   1335元/2.5kg;   咨询
储存:室温
状态:白色到灰白色到浅米黄色粉末或结晶粉末
C0016TCI(±)-10-Camphorsulfonic Acid>98.0%(T)195元/25G;   490元/100G;   1370元/500G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C10H16O4S = 232.29
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN3205973
PubChem物质ID87565227
SDBS (AIST Spectral DB)10703
MDL编号MFCD00074827

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Neutralization titration)min. 98.0 %
Specific rotation [a]20/D-1.0 to +1.0 deg(C=5, H2O)
Solubility in Wateralmost transparency

物性(参考值)

熔点202 ℃(dec.)
水溶性可溶

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN3261
类别8
包装类别 II
监管条件代码(*)
502667J&K10-Camphorsulfonic acid98%86元/25G;   285元/100G;   911元/500G;   咨询

基本信息

分子式C10H16O4S
分子量232.30
熔点196
MDL编码MFCD00074827
Beilstein3205973
EINECS 编号227-527-0
存储条件Corrosives

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
RTECSDT5077100
TSCA
A12620Alfa Aesar(±)-Camphor-10-sulfonic acid98%847元/100g;   3364元/500g;   15266元/2500g;   咨询

应用
(+)-Camphor-10-sulfonic acid is used as a resolving agent for chiral amines and other cations. It is involved in the preparation of active pharmaceutical ingredient such as trimetaphan camsilate, which is used to reduce bleeding during neurosurgery. Further, it is involved in the transglucosidation of methyl and ethyl D-glucopyranosides by alcoholysis.

备注
Hygroscopic. Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00074827

EINECS
227-527-0

分子式
C10H16O4S

分子量
232.30

熔点
ca 200° dec.

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water.

Beilstein
3205973

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
DT5077100

TSCA

C18907Alfa AesarDL-10-Camphorsulfonic acid98%1140元/100g;   4268元/500g;   16731元/2.5kg;   咨询

基本信息

Ref#
18907

MDL
00074827

分子式
C10 H16 O4 S

分子量
232.29

形态
White to cream cryst powder

安全信息

危险等级
8

包装组
II

147923Sigma-AldrichCamphor-10-sulfonic acid (β)98%563.37元/100 G;   1687.36元/500 G;   咨询

产品说明

一般描述

樟脑磺酸是一种有机硫化合物。

应用

樟脑-10-磺酸(β)(CSA)被广泛用作酸催化剂。

  • 它能够用于保护羟基,如使用催化量的CSA和二氢吡喃可以生成四氢吡喃基(THP)醚。
  • 它还催化保护酮类,如缩酮。
  • 它是环氧化物分子内开环反应的有效催化剂。
  • CSA还可用于在两栖动物毒素 A的全合成中催化由亲核试剂促进的炔-亚氨基环化反应。

包装

100, 500 g in glass bottle

基本信息

经验(实验)分子式C10H16O4S
分子量232.30
Beilstein3205973
EC 号227-527-0
MDL编号MFCD00074827
PubChem化学物质编号24848866
NACRESNA.22

产品性质

质量水平200
测定98%
mp203-206 ℃ (dec.) (lit.)
SMILES string[H][C@@]12CC[C@@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
InChI1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
InChI keyMIOPJNTWMNEORI-GMSGAONNSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Y0001397Voriconazole impurity EEuropean Pharmacopoeia (EP) Reference Standard1259.15元/ ;   咨询

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

包装

Unit quantity: 50 mg. Subject to change. The product is delivered as supplied by the issuing Pharmacopoeia. For the current unit quantity, please visit the EDQM reference substance catalogue.

注意

Please find SDS provided by EDQM here..

其他说明

Sales restrictions may apply.

基本信息

经验(实验)分子式C10H16O4S
分子量232.30
Beilstein3205973
MDL编号MFCD00074827
PubChem化学物质编号329831402
NACRESNA.24

产品性质

等级pharmaceutical primary standard
manufacturer/tradenameEDQM
mp199-201 ℃ (dec.)
application(s)pharmaceutical (small molecule)
格式neat
储存温度2-8℃
SMILES stringCC1(C)[C@@H]2CC[C@@]1(CS(O)(=O)=O)C(=O)C2
InChI1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
InChI keyMIOPJNTWMNEORI-GMSGAONNSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
1718063USPVoriconazole Related Compound FUnited States Pharmacopeia (USP) Reference Standard10218.8元/50 MG;   咨询

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.
For further information and support please go to the website of the issuing Pharmacopoeia.

分析说明

These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind.  ​

其他说明

USP issued SDS can be found here.
Sales restrictions may apply.

基本信息

经验(实验)分子式C10H16O4S
分子量232.30
Beilstein3205973
MDL编号MFCD00074827
PubChem化学物质编号329751509
NACRESNA.24

产品性质

等级pharmaceutical primary standard
manufacturer/tradenameUSP
mp199-201 ℃ (dec.)
application(s)pharmaceutical (small molecule)
格式neat
SMILES stringCC1(C)[C@@H]2CC[C@@]1(CS(O)(=O)=O)C(=O)C2
InChI1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
InChI keyMIOPJNTWMNEORI-GMSGAONNSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
963388Amethyst10-Camphorsulfonic acid99%, 用于合成40元/25G;   88元/100G;   302元/500G;   1207元/2.5KG;   咨询

基本信息

分子式C10H16O4S
分子量232.30
熔点203-206
MDL编码MFCD00074827
Beilstein3205973
EINECS 编号227-527-0
存储条件Corrosives

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
RTECSDT5077100
TSCA
984795Amethyst10-Camphorsulfonic acid98%, 用于合成40元/25G;   88元/100G;   302元/500G;   1207元/2.5KG;   咨询

基本信息

分子式C10H16O4S
分子量232.30
熔点196
MDL编码MFCD00074827
Beilstein3205973
EINECS 编号227-527-0
存储条件Corrosives

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
RTECSDT5077100
TSCA
237819FluorochemCamphor-10-sulfonic acid95%220元/25g;   660元/100g;   1826元/500g;   咨询

基本信息

CAS Number5872-08-2
MDL NumberMFCD00074827
Boiling Point344.46℃
Melting Point193-204℃
Density1.2981

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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