| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| T819847 | MACKLIN | 三环己基膦四氟硼酸盐 | 98% | 26元/1g; 28元/5g; 79元/25g; 310元/100g; 1254元/500g; | 咨询 |
|
| T2585 | TCI | Tricyclohexylphosphonium Tetrafluoroborate | >98.0%(T) | 215元/1G; 860元/5G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(T) | | 分子式/分子量 | C18H34BF4P = 368.25 | | 外观与形状(20℃) | 固体 | | 包装和容器 | 1G-带有塑料内管的玻璃瓶 (查看图片) | | Reaxys-RN | 6789409 | | PubChem物质ID | 125307419 | | MDL编号 | MFCD03840580 |
技术规格 | Appearance | White to Almost white powder to crystal | | Purity(Iodometric Titration) | min. 98.0 % | | Melting point | 168.0 to 172.0 ℃ |
物性(参考值) 安全信息 | 图形或危害标志 |   | | 信号词 | 危险 | | 危险性说明 | H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。
|
运输信息 | UN编号 | UN1759 | | 类别 | 8 | | 包装类别 | III | | 监管条件代码(*) | |
|
| 419063 | J&K | Tricyclohexylphosphonium Tetrafluoroborate | 98% | 77元/1G; 199元/5G; 607元/25G; | 咨询 |
基本信息 | 分子式 | C18H34BF4P | | 分子量 | 368.24 | | 熔点 | 164 | | MDL编码 | MFCD03840580 |
安全信息 |
| 15-6160 | Strem | Tricyclohexylphosphonium Tetrafluoroborate | 99% | 319元/1g; 973元/5g; 4170元/25g; | 咨询 |
Technical Note: 1. Non-pyrophoric, air-stable derivative suitable as a replacement for the neat phosphine in a variety of stoichiometric and catalyticprocesses. |
| H27428 | Alfa Aesar | Tricyclohexylphosphonium Tetrafluoroborate | 99% | 362元/1g; 1380元/5g; 6902元/25g; | 咨询 |
应用
Tricyclohexylphosphonium tetrafluoroborate is used with ruthenium (1,5-cyclooctadiene)ruthenium dimer to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds. It is also used in suzuki reaction. 备注
Incompatible with strong oxidizing agents. 基本信息 MDL
MFCD03840580 分子式
C18H34P?BF4 分子量
368.25 熔点
166-170° 灵敏度
Ambient temperatures. 形态
Crystalline powder 溶解性
Soluble in water. GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
否 |
| C38683 | Alfa Aesar | Tricyclohexylphosphonium Tetrafluoroborate | 99% | 518元/1g; 1955元/5g; | 咨询 |
基本信息 Ref#
38683 MDL
03840580 分子式
C18 H34 B F4 P 分子量
368.24 形态
White crystalline powder |
| 631493 | Sigma-Aldrich | Tricyclohexylphosphine tetrafluoroborate | 97% | 296.26元/1 G; 938.16元/5 G; | 咨询 |
产品说明 一般描述 三环己基膦四氟硼酸盐(PCy3·HBF4) 是一种价廉、气稳的膦配体，常用于交叉偶联反应。 应用 与 Ru (cod) Cl 二聚体配合使用，催化醇与胺的脱氢偶联形成酰胺键。
三环己基膦四氟硼酸盐可用于以下工艺： - 作为通过微波辅助直接芳基化制备 C-高阿朴啡生物碱的配体。
- 聚-\ [9,9-双(3-丙酰胺-2-甲基丙磺酸)芴]- 钴 -(4,4′) 的合成-二苯基)(PFDBSO 3 H)，它能被用作模板和掺杂代理人为提高聚 (3,4-乙烯二氧噻吩) (PEDOT) 膜的电导率。
- 为了改善钯催化的 MIDA 硼酸酯与活性较低的烯基甲苯磺酸盐之间的 Suzuki-Miyaura 交叉偶联反应的反应性。
包装 1, 5 g in glass bottle 基本信息 | 线性分子式 | (C6H11)3P · HBF4 | | 分子量 | 368.24 | | MDL编号 | MFCD03840580 | | PubChem化学物质编号 | 24882425 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 97% | | reaction suitability | reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Stille Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling | | mp | 164 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | F[B-](F)(F)F.[H][P+](C1CCCCC1)(C2CCCCC2)C3CCCCC3 | | InChI | 1S/C18H33P.BF4/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1(3,4)5/h16-18H,1-15H2;/q;-1/p+1 | | InChI key | MYSMMEUXKHJYKH-UHFFFAOYSA-O |
安全信息 | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
|
| 985081 | Amethyst | Tricyclohexylphosphonium Tetrafluoroborate | 98%, 用于合成 | 51元/1G; 57元/5G; 207元/25G; 779元/100G; | 咨询 |
基本信息 | 分子式 | C18H34BF4P | | 分子量 | 368.24 | | 熔点 | 164 | | MDL编码 | MFCD03840580 |
安全信息 |
| 044347 | Fluorochem | Tricyclohexylphosphine tetrafluoroborate | 97% | 220元/1g; 264元/5g; 440元/10g; 638元/25g; 1958元/100g; | 咨询 |
基本信息 | CAS Number | 58656-04-5 | | MDL Number | MFCD03840580 | | Melting Point | 164-172℃ |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
| | 防范说明 | P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
|
|
m.cnreagent.com