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CAS: 584-13-4
分子式: C2H4N4
分子量: 84.08
沸点: 255 °C(lit.)
熔点: 84-88℃
中文名称: 
4-氨基-1,2,4-三唑
4-氨基-1,2,4-三氮唑
英文名称: 
4-Amino-1,2,4-triazole
1-Amino-1,3,4-triazole
[1,2,4]Triazol-4-ylamine
4-Amino-4H-1,2,4-triazole
4H-1,2,4-Triazol-4-amine
4-triazole, 4-amino-4h-2
性质描述: 该品为针状结晶。熔点为82-83℃。能溶于水、乙醇,微溶于三氯甲烷和石油醚。易吸潮。
生产方法: 由甲酰肼加热制得。将甲酰肼在常压下加热3h,浴温由50℃升至200℃,再冷至100℃左右,并将糖浆状物溶于95%乙醇中,再加活性炭脱色,然后将滤液用乙醚稀释,冷却结晶,过滤。用1:2乙醇-乙醚混合溶剂洗涤并干燥得粗品,再用95%热乙醇和乙醚重结晶而得纯品。甲酰肼可由甲酸乙酯和水合肼反应得到。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
A800540MACKLIN4-氨基-4H-1,2,4-三唑98%28元/5g;   32元/25g;   95元/100g;   468元/500g;   2316元/2.5kg;   9182元/10kg;   咨询
储存:室温
状态:白色到棕褐色粉末,晶体和/或块状
A1137TCI4-Amino-1,2,4-triazole>98.0%(T)(HPLC)490元/25G;   2100元/250G;   咨询

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C2H4N4 = 84.08
外观与形状(20℃)固体
应避免的情况
Reaxys-RN107563
PubChem物质ID87562620
SDBS (AIST Spectral DB)22112
MDL编号MFCD00003099

技术规格

AppearanceWhite to Gray to Brown powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 98.0 %
Melting point84.0 to 88.0 ℃

物性(参考值)

熔点86 ℃
溶解性(可溶于)甲醇
溶解度(极微溶)氯仿

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#XZ3850200
220009J&K4-Amino-4H-1,2,4-triazole99%83元/5G;   138元/25G;   365元/100G;   咨询

基本信息

分子式C2H4N4
分子量84.08
熔点84-86
MDL编码MFCD00003099
Beilstein107563
EINECS 编号209-533-5

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK2
RTECSXZ3850200
TSCA
A17716Alfa Aesar4-Amino-1,2,4-triazole99%670元/5g;   1380元/25g;   4764元/100g;   咨询

应用
4-Amino-1,2,4-triazole is used as an intermediate for the preparation of antifungal agent like fluconazole.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00003099

EINECS
209-533-5

分子式
C2H4N4

分子量
84.08

熔点
83-88°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water and methanol.

Beilstein
107563

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
XZ3850200

TSCA

A81803Sigma-Aldrich4-Amino-4H-1,2,4-triazoleReagentPlus®, 99%331.53元/5 G;   1574.76元/25 G;   2767.56元/100 G;   咨询

产品说明

包装

5, 25, 100 g in glass bottle

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

经验(实验)分子式C2H4N4
分子量84.08
Beilstein107563
EC 号209-533-5
MDL编号MFCD00003099
PubChem化学物质编号24891209
NACRESNA.22

产品性质

质量水平200
产品线ReagentPlus®
测定99%
mp84-86 ℃ (lit.)
SMILES stringNn1cnnc1
InChI1S/C2H4N4/c3-6-1-4-5-2-6/h1-2H,3H2
InChI keyFMCUPJKTGNBGEC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
8.01309Sigma-Aldrich4-Amino-1,2,4-triazolefor synthesis316.06元/25 G;   咨询

产品说明

分析说明

Assay (HClO₄): ≥ 98.0 %
Melting range (lower value): ≥ 83 °C
Melting range (upper value): ≤ 86 °C
Identity (IR): passes test

基本信息

经验(实验)分子式C2H4N4
分子量84.08
MDL编号MFCD00003099
EC索引号209-533-5

产品性质

质量水平200
pH值(酸碱度)<7 (20 ℃ in H2O)
mp83-86 ℃
储存温度2-30℃
InChI1S/C2H4N4/c3-6-1-4-5-2-6/h1-2H,3H2
InChI keyFMCUPJKTGNBGEC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
V900701Sigma-Aldrich4-Amino-4H-1,2,4-triazoleVetec, reagent grade, 98%737.31元/25 G;   咨询

产品说明

包装

5, 25 g in glass bottle

法律信息

Vetec is a trademark of sigma-aldrich International GmbH

基本信息

经验(实验)分子式C2H4N4
分子量84.08
Beilstein107563
EC 号209-533-5
MDL编号MFCD00003099
PubChem化学物质编号329830073

产品性质

等级reagent grade
产品线Vetec
测定98%
mp84-86 ℃ (lit.)
SMILES stringNn1cnnc1
InChI1S/C2H4N4/c3-6-1-4-5-2-6/h1-2H,3H2
InChI keyFMCUPJKTGNBGEC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
122778Amethyst4-Amino-4H-1,2,4-triazole99%, 用于合成51元/5G;   80元/25G;   208元/100G;   677元/500G;   咨询

基本信息

分子式C2H4N4
分子量84.08
熔点84-86
MDL编码MFCD00003099
Beilstein107563
EINECS 编号209-533-5

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK2
RTECSXZ3850200
TSCA
013753Fluorochem4-Amino-1,2,4-triazole97%220元/1g;   308元/25g;   814元/100g;   咨询

基本信息

CAS Number584-13-4
MDL NumberMFCD00003099
Melting Point83-88℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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