CAS 58109-40-3; 二苯基碘鎓六氟磷酸盐; Iodonium, diphenyl-, hexafluorophosphate(1-)

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品牌

产品名称

规格

包装、参考价格

D837233

MACKLIN

二苯基碘鎓六氟磷酸盐

98%

76元/1g; 258元/5g; 799元/25g; 2200元/100g;

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储存：室温，干燥，避光
状态：无色到白色到灰白色粉末或块状

D2238

TCI

Diphenyliodonium Hexafluorophosphate

>97.0%(T)

325元/1G; 885元/5G; 3205元/25G;

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基本信息

纯度/分析方法	>97.0%(T)
分子式/分子量	C₁₂H₁₀F₆IP = 426.08
外观与形状(20℃)	固体
应避免的情况	光
Reaxys-RN	4224192
PubChem物质ID	87568676
MDL编号	MFCD00061398

技术规格

Appearance	White to Almost white powder to crystal
Purity(Ion exchange titration)	min. 97.0 %
Solubility in Methanol	almost transparency

物性(参考值)

熔点	142 ℃(dec.)
溶解性(可溶于)	甲醇

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

523434

J&K

Diphenyliodonium Hexafluorophosphate

98%

227元/1G; 907元/5G; 1996元/25G; 3359元/50G;

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基本信息

分子式	C₁₂H₁₀F₆IP
分子量	426.08
熔点	138-140
MDL编码	MFCD00061398
Beilstein	4343861
EINECS 编号	261-134-5

安全信息

图形或危害标志
提示语	Danger
危险说明	H314
防范说明	P264 P271 P280
UN号码	1759
危险分类	8
包装等级	II
WGK	3
TSCA	是

A17934

Alfa Aesar

Diphenyliodonium Hexafluorophosphate

98%

1427元/10g; 5333元/50g; 20058元/250g;

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应用
Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

备注
Light sensitive and hygroscopic. Incompatible with strong acids.

基本信息

MDL
MFCD00061398

EINECS
261-134-5

分子式
C₁₂H₁₀F₆IP

分子量
426.08

熔点
139-144°

灵敏度
Light Sensitive. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA
是

548014

Sigma-Aldrich

Diphenyliodonium Hexafluorophosphate

≥98%

1096.77元/5 G; 4066.49元/25 G;

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产品说明

包装

5, 25 g in amber poly bottle
棕色聚乙烯瓶封装

应用

阳离子光引发剂。光酸产生剂。

基本信息

线性分子式	(C₆H₅)₂I(PF₆)
分子量	426.08
Beilstein	4343861
EC 号	261-134-5
MDL编号	MFCD00061398
PubChem化学物质编号	24879004
NACRES	NA.23

产品性质

质量水平	200
测定	≥98%
mp	140-144 ℃ (lit.)
SMILES string	F[P-](F)(F)(F)(F)F.[I+](c1ccccc1)c2ccccc2
InChI	1S/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-7(2,3,4,5)6/h1-10H;/q+1;-1
InChI key	DSSRLRJACJENEU-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Eye Dam. 1 - Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

009165

Fluorochem

Diphenyliodonium Hexafluorophosphate

97%

968元/1g; 2750元/5g; 7084元/25g;

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基本信息

CAS Number	58109-40-3
MDL Number	MFCD00061398
Melting Point	142℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .