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CAS: 573-17-1
分子式: C14H9Br
分子量: 257.14
沸点: 180-190℃
熔点: 60-65℃
中文名称: 
9-溴苯蒽烯
9-溴菲
9-溴苯蒽
英文名称: 
9-bromo-phenanthren
9-bromophenanthrene
9-phenathryl bromide
9-bromo phenanthrene
性质描述: 白色结晶。熔点65-66℃,沸点190℃(0.16kPa,升华),相对密度1.409。溶于乙酸、二硫化碳。
生产方法: 将菲溶于干燥的四氯化碳,加热回流,滴加溴素,继续回流逸尽生成的溴化氢。反应液减压蒸除溶剂,继续减压蒸馏,收集177-190℃(0.16kPa)馏分,即为9-溴菲,产率90%-94%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
B803496MACKLIN9-溴菲98%29元/5g;   112元/25g;   399元/100g;   咨询
储存:室温
状态:白色到浅黄色粉末
B787352MACKLIN9-溴菲≥99.5%84元/5g;   346元/25g;   907元/100g;   3150元/500g;   咨询
储存:室温
B0838TCI9-Bromophenanthrene>98.0%(GC)705元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C14H9Br = 257.13
外观与形状(20℃)固体
Reaxys-RN1869927
PubChem物质ID87563821
SDBS (AIST Spectral DB)7274
MDL编号MFCD00001174

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 98.0 %
Melting point62.0 to 67.0 ℃
Solubility in Toluenealmost transparency

物性(参考值)

熔点63 ℃
沸点225 ℃/15 mmHg

相关法规

RTECS#SF7197000
376816J&K9-Bromophenanthrene96%167元/25G;   咨询

基本信息

分子式C14H9Br
分子量257.13
熔点60-64
沸点180-190
闪点113
MDL编码MFCD00001174
Beilstein1869927
EINECS 编号209-351-6

安全信息

防范说明P260
P262
WGK3
RTECSSF7197000
TSCA
933857J&K9-Bromophenanthrene98%453元/25G;   1792元/100G;   咨询

基本信息

分子式C14H9Br
分子量257.13
熔点60-64
沸点180-190
闪点113
MDL编码MFCD00001174
Beilstein1869927
EINECS 编号209-351-6

安全信息

防范说明P260
P262
WGK3
RTECSSF7197000
TSCA
L09033Alfa Aesar9-Bromophenanthrene98%465元/5g;   1221元/25g;   咨询

应用
9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission.

备注
Incompatible with strong oxidizing agents. Store away from oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

基本信息

MDL
MFCD00001174

EINECS
209-351-6

分子式
C14H9Br

分子量
257.14

熔点
62-66°

沸点
190°/1.2mm

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in toluene, and chloroform (50 mg/ml).

Beilstein
1869927

安全信息

RTECS
SF7197000

TSCA

C10724Alfa Aesar9-Bromophenanthrene96%844元/10g;   1546元/25g;   5777元/100g;   咨询

基本信息

Ref#
10724

MDL
1174

分子式
C14 H9 Br

分子量
257.13

闪点
>110

B75409Sigma-Aldrich9-Bromophenanthrene96%534.48元/10 G;   698.37元/25 G;   咨询

基本信息

经验(实验)分子式C14H9Br
分子量257.13
Beilstein1869927
EC 号209-351-6
MDL编号MFCD00001174
PubChem化学物质编号24892005
NACRESNA.22

产品性质

质量水平100
测定96%
形式powder
bp180-190 ℃/2 mmHg (lit.)
mp60-64 ℃ (lit.)
SMILES stringBrc1cc2ccccc2c3ccccc13
InChI1S/C14H9Br/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H
InChI keyRSQXKVWKJVUZDG-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
237121Fluorochem9-Bromophenanthrene95%220元/1g;   374元/10g;   506元/25g;   1584元/100g;   咨询

基本信息

CAS Number573-17-1
MDL NumberMFCD00001174

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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