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CAS: 5683-31-8
分子式: C6H10O2Si
分子量: 142.23
沸点: 97℃(7 to
熔点: 47-9℃
英文名称: 
3-(Trimethylsilyl)propynoic acid
3-(trimethylsilyl)propiolic acid
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T819250MACKLIN3-(三甲基硅基)丙炔酸95%32元/100mg;   34元/250mg;   咨询
储存:室温
状态:无色或白色到黄色固体或液体
T3040TCI3-(Trimethylsilyl)propiolic Acid>97.0%(GC)(T)1300元/1G;   5690元/5G;   咨询

基本信息

纯度/分析方法>97.0%(GC)(T)
分子式/分子量C6H10O2Si = 142.23
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,湿气 (分解),加热
Reaxys-RN1755674
PubChem物质ID253661720
MDL编号MFCD00190216

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 97.0 %
Purity(Neutralization titration)min. 97.0 %
Melting point46.0 to 50.0 ℃

物性(参考值)

熔点48 ℃
沸点110 ℃/10 mmHg
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
940187J&K3-(Trimethylsilyl)propiolic Acid97%628元/1G;   咨询

基本信息

分子式C6H10O2Si
分子量142.23
熔点47-49
沸点105-110
闪点96
MDL编码MFCD00190216
Beilstein1755674

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
TSCA
H53380Alfa Aesar3-(Trimethylsilyl)propiolic Acid97%1750元/1g;   6602元/5g;   26409元/25g;   咨询

应用
3-(Trimethylsilyl)propiolic acid may be used in the regioselective preparation of 1,5-trisubstituted 1H-1,2,3-triazoles. It is also used as pharmaceutical intermediate.

备注
Stable under recommended storage conditions. Store away from oxidizing agents.

基本信息

MDL
MFCD00190216

分子式
C6H10O2Si

分子量
142.23

熔点
47-49°

沸点
105-110°/10mm

闪点
96°(205°F)

灵敏度
Ambient temperatures.

形态
Solid

溶解性
Soluble in methanol.

Beilstein
1755674

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

403482Sigma-Aldrich3-(Trimethylsilyl)propynoic acid98%401.73元/1 G;   1670.99元/5 G;   咨询

产品说明

应用

3-(Trimethylsilyl)propynoic acid (3-(Trimethylsilyl)propiolic acid) may be used as starting reagent for the synthesis of 3-trimethylsilylpropynamides.
3-(Trimethylsilyl)propynoic acid may be used in the regioselective preparation of 1,5-trisubstituted 1H-1,2,3-triazoles.

包装

1, 5 g in glass bottle

基本信息

线性分子式(CH3)3SiC≡CCO2H
分子量142.23
Beilstein1755674
MDL编号MFCD00190216
PubChem化学物质编号24865196
NACRESNA.22

产品性质

质量水平100
测定98%
bp105-110 ℃/10 mmHg (lit.)
mp47-49 ℃ (lit.)
SMILES stringC[Si](C)(C)C#CC(O)=O
InChI1S/C6H10O2Si/c1-9(2,3)5-4-6(7)8/h1-3H3,(H,7,8)
InChI keyIPEATTYBFBRNEB-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
S20140Fluorochem3-(Trimethylsilyl) propiolic acid95%1320元/1g;   5588元/5g;   咨询

基本信息

CAS Number5683-31-8
MDL NumberMFCD00190216
Boiling Point105-109
Melting Point47-49℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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