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CAS: 565-53-7
分子式: C4H5Br2FO2
分子量: 263.9
沸点: 82℃(33 t
熔点: 157-161°C
中文名称: 
二溴氟乙酸乙酯
英文名称: 
ethyl dibromofluoroacetate
性质描述: 沸点82℃。密度1.894。
推荐供应商
货号品牌产品名称规格包装、参考价格
E808682MACKLIN二溴氟乙酸乙酯97%106元/5g;   502元/25g;   1869元/100g;   咨询
储存:室温
折射率:1.4633
D2530TCIEthyl Dibromofluoroacetate>97.0%(GC)490元/5G;   1715元/25G;   咨询

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C4H5Br2FO2 = 263.89
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1762048
PubChem物质ID87568954
SDBS (AIST Spectral DB)16354
MDL编号MFCD00042068

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点173 ℃
比重1.92
折射率1.46

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 : 吞咽或皮肤接触可致中毒。
H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN2927
类别6.1 / 8
包装类别 II
监管条件代码(*)
520443J&KEthyl Dibromofluoroacetate97%432元/5G;   1520元/25G;   咨询

基本信息

分子式C4H5Br2FO2
分子量263.89
沸点173
闪点>110
密度1.894
折光率(n20D)1.4635
MDL编码MFCD00042068
Beilstein1762048
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H301
H311
H314
防范说明P260
P301+P330+P331
P303+P361+P353
P305+P351+P338
P405
P501
UN号码2922
危险分类8
次要危险性6.1
包装等级III
TSCA
L16491Alfa AesarEthyl Dibromofluoroacetate97%1802元/5g;   6459元/25g;   咨询

应用
Ethyl dibromofluoroacetate is a reagent used in the preparation of fluorinated molecules in organic synthesis. It is involved in the Reformatsky-type reaction to prepare syn-alfa-bromo-alfa-fluoro-beta-lactams by using diethylzinc. It is also used to prepare 2-fluoroaziridine-2-carboxylates by reaction with imines.

备注
Incompatible with oxidizing agents and bases.

基本信息

MDL
MFCD00042068

分子式
Br2C4FH5O2

分子量
263.89

沸点
82°/33mm

闪点
>110°(230°F)

密度
1.894

折射率
1.4635

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with most organic solvents. Immiscible with water.

Beilstein
1762048

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H314-H318
Harmful if swallowed.Harmful in contact with skin.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
21/22-34
Harmful in contact with skin and if swallowed.Causes burns.

安全等级
23-26-36/37/39-45
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

003217FluorochemEthyl Dibromofluoroacetate97%330元/1g;   1254元/5g;   3894元/25g;   咨询

基本信息

CAS Number565-53-7
MDL NumberMFCD00042068
Boiling Point82℃/33mm
Density1.894

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H332: Harmful if inhaled.
防范说明 P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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