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CAS: 563-41-7
分子式: CH6ClN3O
分子量: 111.53
沸点: (65 °C甲醇)
熔点: 171-177℃
中文名称: 
肼甲酰胺盐酸盐
氨基脲盐酸盐
氨基脲,盐酸盐
盐酸氨基脲
英文名称: 
Hydrazinecarboxamide, monohydrochloride
Semicarbazide hydrochloride
semicarbazide, monohydrochloride
amidourea hydrochloride
aminourea hydrochloride
carbamylhydrazine hydrochloride
hydrazinecarboxamide monohydrochloride
hydrazinecarboxamide, hydrochloride
semicarbazide chloride
hydrazinecarboxamide,monohydrochloride
semicarbazidehydrochloride1
Carbamyl hydrazine hydrochloride
展开更多英文名
性质描述: 无色透明或白色结晶。溶于水,不溶于无水乙醇和乙醚。熔点175-177℃(分解)。
生产方法: 以水合肼及尿素为原料,经缩合而得氨基脲液,然后加入盐酸进行酸化络合,经水冷结晶即得成品。在反应过程中生成的氨、用废酸(盐酸、硫酸混合液)中和后可用作肥料。
用途: 本品是医药工业的原料,用以制取硝基呋喃类等药物。也用作测定酮、醛的试剂、色谱分析试剂及分离激素和精油的溶剂。
推荐供应商
货号品牌产品名称规格包装、参考价格
A997320MACKLIN盐酸氨基脲试液25mg/ml140元/100ml;   咨询
储存:室温, 避光
A800404MACKLIN盐酸氨基脲98%28元/25g;   34元/100g;   98元/500g;   452元/2.5kg;   1802元/10kg;   咨询
储存:室温
状态:白色晶体粉末
S0032TCISemicarbazide Hydrochloride>99.0%(T)145元/25G;   640元/500G;   咨询

基本信息

纯度/分析方法>99.0%(T)
分子式/分子量CH5N3O・HCl = 111.53
外观与形状(20℃)固体
Reaxys-RN3593642
PubChem物质ID87575661
Merck Index (14)8444
MDL编号MFCD00013009

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Bromination Method)min. 99.0 %

物性(参考值)

水溶性完全溶解
溶解性(微溶于)
溶解性(不溶于)乙醚

安全信息

图形或危害标志
信号词危险
危险性说明H301 : 吞咽会中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H361 : 怀疑对生育能力或胎儿造成伤害。
H373 : 长期或反复接触可能损害器官。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#VT3500000

运输信息

UN编号UN2811
类别6.1
包装类别 III
监管条件代码(*)
246175J&KSemicarbazide Hydrochloride98%225元/100G;   551元/500G;   2199元/2.5KG;   咨询

基本信息

分子式CH5N3O·HCl
分子量111.53
熔点175-177
MDL编码MFCD00013009
Beilstein3593642
Merck14,8444
EINECS 编号209-247-0

安全信息

图形或危害标志
提示语Danger
危险说明H301
防范说明P301+P310
UN号码2811
危险分类6.1
包装等级III
WGK3
RTECSVT3500000
TSCA
A11668Alfa AesarSemicarbazide Hydrochloride99%384元/100g;   1270元/500g;   5333元/2500g;   咨询

应用
Semicarbazide hydrochloride is used as urease substrate and MAO inhibitor. Derivatizing agent for carbonyl compounds as their semicarbazones which produces crystalline compounds with characteristic melting points. Also used in heterocyclic synthesis. Semicarbazone formation has been used to separate carbonyl compounds from mixtures by adsorption onto silica gel from a hydrocarbon solution. Regeneration is by hydrolysis with oxalic acid.

备注
Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

基本信息

MDL
MFCD00013009

EINECS
209-247-0

分子式
CH4N3O•HCl

分子量
111.53

熔点
ca 176° dec.

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water (>100g/L).

Beilstein
3593642

Merck
14,8444

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
25-36/37/38
Toxic if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
20-26-36/37-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

RTECS
VT3500000

TSCA

C13264Alfa AesarSemicarbazide Hydrochloride99+%564元/100g;   1778元/500g;   6212元/2.5kg;   咨询

基本信息

Ref#
13264

MDL
13009

分子式
C H5 N3 O . H Cl

分子量
111.53

形态
Crystalline

安全信息

危险等级
6.1

包装组
III

R11951Alfa AesarSemicarbazide hydrochloride,1000ppm880元/1ml;   咨询

安全信息

危险等级
3

R10870Alfa AesarSemicarbazide hydrochloride Standard solution100ppm419元/1ml;   咨询

安全信息

危险等级
3

33656SupelcoSemicarbazide HydrochlorideVETRANAL®, analytical standard833.42元/100 MG;   咨询

产品说明

应用

氨基脲盐酸盐可用作稳定剂,用于通过稳定同位素稀释气相色谱-串联质谱法在负离子化学电离模式下测定血浆样品中的去甲肾上腺素。
有关合适仪器技术的更多信息,请参考产品分析证书。如需进一步支持,请联系技术服务部门。
盐酸氨基脲可用于 4-硝基苯甲醛缩氨基脲的合成。

法律信息

VETRANAL is a registered trademark of sigma-aldrich Chemie GmbH

基本信息

线性分子式NH2CONHNH2 · HCl
分子量111.53
Beilstein3593642
EC 号209-247-0
MDL编号MFCD00013009
PubChem化学物质编号329754605
NACRESNA.24

产品性质

等级analytical standard
质量水平100
产品线VETRANAL®
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp175-177 ℃ (dec.) (lit.)
application(s)forensics and toxicology
pharmaceutical (small molecule)
格式neat
SMILES stringCl.NNC(N)=O
InChI1S/CH5N3O.ClH/c2-1(5)4-3;/h3H2,(H3,2,4,5);1H
InChI keyXHQYBDSXTDXSHY-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语:Danger
危险声明H301 - H314 - H361fd - H373
预防措施声明P201 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Oral
靶器官Bone
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
S2201Sigma-AldrichSemicarbazide Hydrochloride≥99%195.41元/5 G;   291.39元/100 G;   946.02元/500 G;   咨询

产品说明

应用

氨基脲盐酸盐是用于从醛和酮合成缩氨基脲的通用试剂。可用于构建多种杂环化合物,其中一些是有效的抗菌剂和抗病毒剂。也可用于制备阻蚀剂。
醛和酮的衍生试剂,其可产生具有特征熔点的结晶化合物。

包装

5 g in glass bottle
100, 500 g in poly bottle

基本信息

线性分子式NH2CONHNH2 · HCl
分子量111.53
Beilstein3593642
EC 号209-247-0
MDL编号MFCD00013009
PubChem化学物质编号24278197
NACRESNA.22

产品性质

质量水平200
测定≥99%
mp175-177 ℃ (dec.) (lit.)
SMILES stringCl.NNC(N)=O
InChI1S/CH5N3O.ClH/c2-1(5)4-3;/h3H2,(H3,2,4,5);1H
InChI keyXHQYBDSXTDXSHY-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语:Danger
危险声明H301 - H314 - H361fd - H373
预防措施声明P201 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Oral
靶器官Bone
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
8.18369Sigma-AldrichSemicarbazide Hydrochloridefor synthesis367.02元/100 G;   咨询

产品说明

分析说明

Assay (argentometric): ≥ 98.0 %
Identity (IR): passes test

基本信息

经验(实验)分子式CH5N3O · xHCl
分子量75.07 (free base basis)
MDL编号MFCD00013009
EC索引号209-247-0

产品性质

质量水平200
效能123 mg/kg LD50, oral (Rat)
pH值(酸碱度)1.5 (20 ℃, 100 g/L in H2O)
mp175-177 ℃ (decomposition)
堆积密度740 kg/m3
储存温度15-25℃
InChI1S/CH5N3O.ClH/c2-1(5)4-3;/h3H2,(H3,2,4,5);1H
InChI keyXHQYBDSXTDXSHY-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语:Danger
危险声明H301 - H314 - H361fd - H373
预防措施声明P202 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Oral
靶器官Bone
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
242276FluorochemHydrazinecarboxamide hydrochloride95%220元/25g;   1232元/500g;   咨询

基本信息

CAS Number563-41-7
MDL NumberMFCD00013009

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H373: May cause damage to organs Bone.
H361fd: Reproductive toxicity
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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