CAS 56210-72-1; (-)-bis-((S)-1-phenylethyl)amine hydrochloride

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货号

品牌

产品名称

规格

包装、参考价格

B914694

MACKLIN

双[(S)-1-苯基乙基]胺

≥98%

39元/250mg; 105元/1g; 374元/5g; 1700元/25g;

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储存：室温
状态：无色到浅黄色液体

H27106

Alfa Aesar

(-)-Bis[(S)-1-phenylethyl]amine

ChiPros庐, 99%, ee 98+%

858元/1g; 2674元/5g; 9968元/25g;

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应用
(-)-Bis[(S)-1-phenylethyl]amine is used as a chiral resolution reagent in organic synthesis.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00243087

分子式
C₁₆H₁₉N

分子量
225.34

沸点
98°/0.3mm

灵敏度
Air Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Immiscible with water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

433810

Sigma-Aldrich

(-)-Bis[(S)-1-phenylethyl]amine

99%

412.03元/1 G; 1889.71元/10 G;

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产品说明

应用

(−)-双[(S)-1-苯基乙基]胺可用作：

亚磷酰胺 (Feringa) 配体合成的关键中间产物。
新型大环内酯化合物lasonolide A的C(18)-C(24)单元制备的反应剂。
他克林−石杉碱甲A杂合体合成的起始材料。

包装

1, 10 g in glass bottle

基本信息

线性分子式	[C₆H₅CH(CH₃)]₂NH
分子量	225.33
MDL编号	MFCD00243087
PubChem化学物质编号	24866982
NACRES	NA.22

产品性质

测定	99%
旋光性	[α]/D −159°, c = 2 in ethanol
光学纯度	ee: ≥99% (GLC)
折射率	n20/D 1.5525 (lit.)
bp	86 ℃/0.05 mmHg (lit.)
密度	0.987 g/mL at 25 ℃ (lit.)
SMILES string	C[C@H](N[C@@H](C)c1ccccc1)c2ccccc2
InChI	1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m0/s1
InChI key	NXLACVVNHYIYJN-KBPBESRZSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	12 - Non Combustible Liquids
WGK	WGK 3
闪点(F)	235.4 °F - closed cup
闪点(C)	> 113 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter