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CAS: 555-31-7
分子式: C9H21AlO3
分子量: 204.24
沸点: 125-130 °C/51 hPa
熔点: 128-133 °C(lit.)
中文名称: 
三异丙醇铝
异丙基氧化铝
2-丙醇铝
异丙醇铝
三异丙氧基铝
英文名称: 
aluminum tris-(isopropoxide)
aluminumtriisopropylate
2-Propanol, aluminum salt
Aluminium isopropoxide
aluminum(ii) isopropylate
aliso
aluminum isopropanolate
aluminum isopropoxide
aluminum isopropylate
aluminum sec-propanolate
aluminum triisopropoxide
aluminum triisopropylate
aluminum tris(sec-propoxide)
isopropanol aluminum salt
isopropyl alcohol, aluminum salt
triisopropoxyaluminum
triisopropyloxyaluminum
tris(isopropoxy)aluminum
Aluminium-iso-propoxide
AIP
Aluminium isopropxide
Aluminum iso-Propoxide
2-Propanol,aluminum salt
Aiuminumisopropoxide
展开更多英文名
性质描述: 吸湿性白色固体。熔点128-132℃,沸点138-148℃(1.33kPa),相对密度(20/4℃)1.035。溶于乙醇、异丙醇、苯、甲苯、氯仿、四氯化碳和石油烃。遇水分解。
生产方法: 由异丙醇和铝在氧化铝催化下反应而得。原料消耗定额:异丙醇1255kg/t、铝166kg/t。
用途: 用作脱水剂、催化剂和防水剂的原料。
推荐供应商
货号品牌产品名称规格包装、参考价格
A800381MACKLIN异丙醇铝99.99% metals basis58元/25g;   123元/100g;   409元/500g;   1250元/2.5kg;   3849元/10kg;   咨询
储存:室温, 干燥, 易燃物区域, 惰性气体保存
状态:白色粉末和/或块状物
折射率:1.0346
A800380MACKLIN异丙醇铝≥99.8%42元/100g;   98元/500g;   388元/2.5kg;   1195元/10kg;   2436元/25kg;   1165元/12X500g;   咨询
储存:室温, 干燥, 易燃物区域, 惰性气体保存
状态:白色粉末和/或块状物
折射率:1.0346
A800379MACKLIN异丙醇铝试剂级, 94%34元/100g;   79元/500g;   281元/2.5kg;   910元/10kg;   926元/12X500g;   咨询
储存:室温, 干燥, 易燃物区域, 惰性气体保存
状态:白色粉末和/或块状物
折射率:1.0346
A0246TCIAluminum Isopropoxide>98.0%(T)160元/100G;   270元/500G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C9H21AlO3 = 204.25
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,湿气 (分解)
Reaxys-RN3910275
PubChem物质ID87561903
SDBS (AIST Spectral DB)3144
Merck Index (14)347
MDL编号MFCD00008870

技术规格

AppearanceWhite to Almost white powder to lump
Purity(Chelometric Titration)min. 98.0 %
Melting point132.0 to 140.0 ℃

物性(参考值)

熔点136 ℃
溶解性(可溶于)乙醇,苯,甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H319 : 造成严重眼刺激。
H335 : 可能造成呼吸道刺激。
H228 : 易燃固体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P241 : 使用防爆的电气/通风/照明设备。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#BD0975000

运输信息

UN编号UN1325
类别4.1
包装类别 II
监管条件代码(*)
969496J&KAluminum Isopropoxide98%69元/100G;   118元/250G;   214元/500G;   388元/1KG;   咨询

基本信息

分子式C9H21AlO3
分子量204.25
熔点129-136
沸点125-130
闪点46
MDL编码MFCD00008870
Beilstein3910275
Merck14,347
EINECS 编号209-090-8

安全信息

图形或危害标志
提示语Danger
危险说明H228
防范说明P210
UN号码3181
危险分类4.1
包装等级II
WGK1
RTECSBD0975000
TSCA
93-1345StremAluminum i-propoxide98+%300元/250g;   842元/1kg;   咨询
97-0139StremAluminum i-propoxide(99.99+%-Al) PURATREM2057元/25g;   6187元/100g;   咨询
014007Alfa AesarAluminum Isopropoxide98+%8385元/2500g;   4628元/1kg;   13908元/5kg;   咨询

应用
Reagent for the reduction of carbonyl compounds. Used in alcoholysis and ester exchange reactions. Also used in synthesis of higher alkoxides, chelates, and acrylates. Aluminum isopropoxide is a useful reagent in the synthesis of alkoxides, chelates and acrylates. It acts as an intermediate of pharmaceutical products like isophytol, testosterone, progesterone and ethisterone. Also used as the material of aluminate coupling agent. It is also used in alcoholysis and ester exchange reactions. In Meerwein-Ponndorf-Verley (MPV) reduction, it is used as a catalyst for the reduction of ketones and aldehydes to their corresponding alcohols.

备注
Moisture sensitive. Incompatible with strong oxidizing agents, strong acids and halogens.

基本信息

MDL
MFCD00008870

EINECS
209-090-8

分子式
Al[OCH(CH3)2]3

分子量
204.25

熔点
131-135°

沸点
135°/10mm

密度
1.035

折射率
1.0346

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Granular

溶解性
Soluble in alcohol, benzene, and toluene. Decomposes in water.Soluble in ethanol, isopropanol, benzene, toluene, chloroform, carbon tetrachloride and petroleum hydrocarbons.

Merck
14,347

GHS危害和防范说明

GHS符号

Hazard Statements
H228
Flammable solid.

Precautionary Statements
P210-P280-P240-P241-P370+P378a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves/protective clothing/eye protection/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.In case of fire: Use for extinction: CO2, powder or water spray.

安全信息

危险等级
4.1

包装组
II

危险类别
11
Highly flammable.

安全等级
8-16
Keep container dry.Keep away from sources of ignition - No smoking.

欧盟危险品标志

RTECS
BD0975000

TSCA

022982Alfa AesarAluminum Isopropoxide99.99+% (metals basis)4012元/25g;   7992元/100g;   咨询

应用
Aluminum isopropoxide is a useful reagent in the synthesis of alkoxides, chelates and acrylates. It acts as an intermediate of pharmaceutical products like isophytol, testosterone, progesterone and ethisterone. Also used as the material of aluminate coupling agent. It is also used in alcoholysis and ester exchange reactions. In Meerwein-Ponndorf-Verley (MPV) reduction, it is used as a catalyst for the reduction of ketones and aldehydes to their corresponding alcohols. It acts as a precursor to prepare alumina.

备注
Moisture sensitive. Incompatible with strong oxidizing agents, strong acids and halogens.

基本信息

MDL
MFCD00008870

EINECS
209-090-8

分子式
Al[OCH(CH3)2]3

分子量
204.25

熔点
131-135°

沸点
135°/10mm

密度
1.035

折射率
1.0346

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Powder

溶解性
Soluble in ethanol, isopropanol, benzene, toluene, chloroform, carbon tetrachloride and petroleum hydrocarbons.

Merck
14,347

GHS危害和防范说明

GHS符号

Hazard Statements
H228
Flammable solid.

Precautionary Statements
P210-P280-P240-P241-P370+P378a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves/protective clothing/eye protection/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.In case of fire: Use for extinction: CO2, powder or water spray.

安全信息

危险等级
4.1

包装组
II

危险类别
11
Highly flammable.

安全等级
8-16
Keep container dry.Keep away from sources of ignition - No smoking.

欧盟危险品标志

RTECS
BD0975000

TSCA

C21223Alfa AesarAluminium isopropoxide99.99%, (trace metal basis)899元/10g;   3091元/50g;   14764元/250g;   咨询

基本信息

Ref#
21223

MDL
8870

分子式
C9 H21 Al O3

分子量
204.25

形态
Granular

安全信息

危险等级
4.1

包装组
II

C20517Alfa AesarAluminium isopropoxide98%821元/500g;   1282元/1kg;   4889元/5kg;   咨询

基本信息

Ref#
20517

MDL
8870

分子式
C9 H21 Al O3

分子量
204.25

形态
Granular

安全信息

危险等级
4.1

包装组
II

220418Sigma-AldrichAluminum Isopropoxide≥98%771.29元/100 G;   1197.75元/1 KG;   咨询

基本信息

线性分子式Al[OCH(CH3)2]3
分子量204.24
Beilstein3910275
EC 号209-090-8
MDL编号MFCD00008870
PubChem化学物质编号24852958
NACRESNA.23

产品性质

质量水平200
测定≥98%
形式solid
reaction suitabilitycore: aluminum
reagent type: catalyst
mp128-133 ℃ (lit.)
密度1.035 g/mL at 25 ℃ (lit.)
SMILES stringCC(C)O[Al](OC(C)C)OC(C)C
InChI1S/3C3H7O.Al/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
InChI keySMZOGRDCAXLAAR-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Danger
危险声明H228
预防措施声明P210 - P240 - P241 - P280 - P370 + P378
危险分类Flam. Sol. 1
储存分类代码4.1B - Flammable solid hazardous materials
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
229407Sigma-AldrichAluminum Isopropoxide≥99.99% trace metals basis906.35元/10 g;   3043.44元/50 G;   6685.58元/250 G;   咨询

产品说明

包装

10, 50, 250 g in poly bottle

应用

常用作制备氧化铝的前体

基本信息

线性分子式Al[OCH(CH3)2]3
分子量204.24
Beilstein3910275
EC 号209-090-8
MDL编号MFCD00008870
PubChem化学物质编号24853273
NACRESNA.23

产品性质

质量水平200
测定≥99.99% trace metals basis
形式powder and chunks
solid
reaction suitabilitycore: aluminum
reagent type: catalyst
mp128-133 ℃ (lit.)
密度1.035 g/mL at 25 ℃ (lit.)
SMILES stringCC(C)O[Al](OC(C)C)OC(C)C
InChI1S/3C3H7O.Al/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
InChI keySMZOGRDCAXLAAR-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Danger
危险声明H228
预防措施声明P210
危险分类Flam. Sol. 1
储存分类代码4.1B - Flammable solid hazardous materials
WGKWGK 1
闪点(F)60.8 °F - closed cup
闪点(C)16 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
8.01079Sigma-AldrichAluminium triisopropylatefor synthesis345.35元/250 G;   441.27元/1 KG;   6073.11元/20 KG;   11132.2元/50 KG;   咨询

产品说明

分析说明

Assay (complexometric): ≥ 98.0 %
Melting range (lower value): ≥ 127 °C
Melting range (upper value): ≤ 135 °C
Identity (IR): passes test

基本信息

线性分子式Al[OCH(CH3)2]3
分子量204.24
MDL编号MFCD00008870
EC索引号209-090-8

产品性质

质量水平200
蒸汽压0.13 hPa ( 21 ℃)
形式powder
效能11300 mg/kg LD50, oral (Rat)
expl. lim.2 % (v/v)
reaction suitabilityreagent type: reductant
bp135 ℃/13 hPa
mp130-134 ℃
转变温度flash point 16 ℃
密度1.035 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/3C3H7O.Al/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
InChI keySMZOGRDCAXLAAR-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Danger
危险声明H228
预防措施声明P210 - P240 - P241 - P280 - P370 + P378
危险分类Flam. Sol. 1
储存分类代码4.1B - Flammable solid hazardous materials
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
936758AmethystAluminum Isopropoxide99.8%, 用于合成82元/100G;   239元/500G;   608元/2.5KG;   咨询

基本信息

分子式C9H21AlO3
分子量204.25
熔点129-136
沸点125-130
闪点46
MDL编码MFCD00008870
Beilstein3910275
Merck14,347
EINECS 编号209-090-8

安全信息

图形或危害标志
提示语Danger
危险说明H228
防范说明P210
UN号码3181
危险分类4.1
包装等级II
WGK1
RTECSBD0975000
TSCA
099441FluorochemAluminium isopropoxide95%220元/25g;   616元/100g;   1848元/1kg;   咨询

基本信息

CAS Number555-31-7
MDL NumberMFCD00008870
Melting Point128-133℃
Density1.035

安全信息

图形或危害标志
危险性说明 H228: Flammable solid.
防范说明 P210: Keep away from – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof / equipment.
P280: Wear .
P370 + P378: In case of fire: Use for extinction.
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